Journal ArticleDOI
Light‐Assisted CO <sub>2</sub> Hydrogenation over Pd <sub>3</sub> Cu@UiO‐66 Promoted by Active Sites in Close Proximity
Reads0
Chats0
TLDR
In this article , tiny Pd3 Cu nanoparticles are confined into a metal-organic framework (MOF), UiO-66, to afford a methanol production rate of 340 μmol g-1 h-1 at 200 °C and 1.25 MPa under light irradiation, far surpassing that in the dark.Abstract:
CO2 hydrogenation to methanol has attracted great interest while suffering from low conversion and high energy input. Herein, tiny Pd3 Cu nanoparticles are confined into a metal-organic framework (MOF), UiO-66, to afford Pd3 Cu@UiO-66 for CO2 hydrogenation. Remarkably, it achieves a methanol production rate of 340 μmol g-1 h-1 at 200 °C and 1.25 MPa under light irradiation, far surpassing that in the dark. The photo-generated electron transfer from the MOF to antibonding orbitals of CO2 * promotes CO2 activation and HCOO* formation. In addition, the Pd3 Cu microenvironment plays a critical role in CO2 hydrogenation. In contrast to the MOF-supported Pd3 Cu (Pd3 Cu/UiO-66), the Pd3 Cu@UiO-66 exhibits a much higher methanol production rate due to the close proximity between CO2 and H2 activation sites, which greatly facilitates their interaction and conversion. This work provides a new avenue to the integration of solar and thermal energy for efficient CO2 hydrogenation under moderate conditions. read more
Citations
More filters
Journal ArticleDOI
Solar Energy Catalysis
TL;DR: In this paper , the authors proposed a definition of solar energy catalysis, and highlighted the limitations and future research directions of different types of sun-powered catalytic reactions, such as photocatalysis, photothermal, solar cell powered electrocatalysis and pyroelectric catalysis.
Journal ArticleDOI
Porous materials for capture and catalytic conversion of CO2 at low concentration
TL;DR: In this article , a review of the recent developments of porous materials, including zeolites, metal-organic frameworks, porous organic polymers, porous carbon, and functionalized mesoporous materials, is presented.
Journal ArticleDOI
Atomically Dispersed Lewis Acid Sites Meet Poly(ionic liquid)s Networks for Solvent-free and Co-catalyst-free Conversion of CO2 to Cyclic Carbonates
Hu Peng,Qiu-hong Zhang,Yinming Wang,Honglin Gao,Nianrong Zhang,Jing Zhou,Linjuan Zhang,Qiu Yang,Qihao Yang,Zhiyi Lu +9 more
TL;DR: In this article , a catalyst composed of porous carbon matrix with atomically dispersed Lewis acid sites (i.e., AlO5 motifs) and imidazolium-based poly(ionic liquid)s (denoted as [email protected]) was fabricated.
Journal ArticleDOI
Metal–Organic Framework‐Based Photocatalysis for Solar Fuel Production
Juan Xiao,Rui Li,Hai-Long Jiang +2 more
TL;DR: In this paper , the authors take the photocatalytic active sites as a particular perspective, summarizing the progress of MOF-based photocatalysis for solar fuel production; mainly including three categories of solar-chemical conversions, including water splitting to hydrogen fuel, carbon dioxide reduction to hydrocarbon fuels, and nitrogen fixation to high-energy fuel carriers such as ammonia.
Journal ArticleDOI
Advances of photothermal chemistry in photocatalysis, thermocatalysis, and synergetic photothermocatalysis for solar-to-fuel generation
TL;DR: In this article , the authors provide a comprehensive review of the current advances in photothermal catalysis along with a guide for understanding the mechanisms and rational material designs to pursue solar fuel that would diversify and increase the sustainability of our energy supply.
References
More filters
Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
Journal ArticleDOI
Recent advances in catalytic hydrogenation of carbon dioxide
TL;DR: A critical review of recent developments in hydrogenation reaction, with emphases on catalytic reactivity, reactor innovation, and reaction mechanism, provides an overview regarding the challenges and opportunities for future research in the field.
Journal ArticleDOI
The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
Malte Behrens,Felix Studt,Igor Kasatkin,Stefanie Kühl,Michael Hävecker,Frank Abild-Pedersen,Stefan Zander,Frank Girgsdies,Patrick Kurr,Benjamin-Louis Kniep,Michael Tovar,Richard W. Fischer,Jens K. Nørskov,Jens K. Nørskov,Robert Schlögl +14 more
TL;DR: This work shows how to identify the crucial atomic structure motif for the industrial Cu/ZnO/Al2O3 methanol synthesis catalyst by using a combination of experimental evidence from bulk, surface-sensitive, and imaging methods collected on real high-performance catalytic systems in combination with density functional theory calculations.
Journal ArticleDOI
Imparting functionality to a metal–organic framework material by controlled nanoparticle encapsulation
Guang Lu,Shaozhou Li,Zhen Guo,Omar K. Farha,Brad G. Hauser,Xiaoying Qi,Yi Wang,Xin Wang,Sanyang Han,Xiaogang Liu,Xiaogang Liu,Joseph S. DuChene,Hua Zhang,Qichun Zhang,Xiaodong Chen,Jan Ma,Say Chye Joachim Loo,Wei David Wei,Yanhui Yang,Joseph T. Hupp,Fengwei Huo +20 more
TL;DR: A controlled encapsulation strategy is reported that enables surfactant-capped nanostructured objects of various sizes, shapes and compositions to be enshrouded by a zeolitic imidazolate framework (ZIF-8).
Journal ArticleDOI
Carbon capture and conversion using metal–organic frameworks and MOF-based materials
TL;DR: This review provides a comprehensive account of significant progress in the design and synthesis of MOF-based materials, including MOFs, MOF composites and MOF derivatives, and their application to carbon capture and conversion.
Related Papers (5)
Hydrogen Formation in the Reactions of Methanol on Supported Au Catalysts
Low Temperature Methanol Synthesis in Slurry Phase With a Hybrid Copper-Formate System
Baoshan Hu,Kaoru Fujimoto +1 more