Journal ArticleDOI
Magnetic Molecular Conductors
Eugenio Coronado,Peter Day +1 more
TLDR
Comparing Magnetic Metals and Semiconductors with Halometalate Anions and Chain Anions: Maleonitriledithiolates 5439 4.1.Abstract:
2.2. BETS Salts with Halometalate Anions 5424 3. Magnetic Metals and Semiconductors 5426 3.1. Mononuclear Metal Complexes 5427 3.1.1. Tetrahalometalates 5427 3.1.2. Hexahalo Anions 5431 3.1.3. Pseudohalide-Containing Anions 5431 3.2. Polynuclear Metal Complexes 5433 3.2.1. Dimeric Anions 5433 3.2.2. Polyoxometalate Clusters 5434 3.3. Chain Anions: Maleonitriledithiolates 5439 4. Ferromagnetic Conductors 5441 5. Ferrimagnetic Insulators 5443 6. Conclusions 5445 7. Acknowledgment 5446 8. References 5446read more
Citations
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Old materials with new tricks: multifunctional open-framework materials.
TL;DR: This critical review provides an up-to-date survey to this new generation of multifunctional open-framework solids, classified into five different sections: magnetic, chiral, conducting, optical, and labile open-frameworks for sensing applications.
Journal ArticleDOI
Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science
TL;DR: Functionalization via covalent grafting of organic functions allows to tune the redox and acid-base properties, and the solubility of polyoxometalates, to enhance their stability and biological activity and to reduce their toxicity.
Journal ArticleDOI
Polyoxometalate water oxidation catalysts and the production of green fuel.
Hongjin Lv,Yurii V. Geletii,Chongchao Zhao,James W. Vickers,Guibo Zhu,Zhen Luo,Jie Song,Tianquan Lian,Djamaladdin G. Musaev,Craig L. Hill +9 more
TL;DR: This review addresses central issues in green energy generation, the challenges in water oxidation catalyst development, and the possible uses of polyoxometalates in greenEnergy science.
Journal ArticleDOI
A polynuclear lanthanide single-molecule magnet with a record anisotropic barrier.
Po-Heng Lin,Tara J. Burchell,Liviu Ungur,Liviu F. Chibotaru,Wolfgang Wernsdorfer,Muralee Murugesu +5 more
TL;DR: The synthesis, structure, and magnetism of a tetranuclear dysprosium(III) SMM that exhibits the largest relaxation barrier seen for any polynuclear SMM to date is reported.
Journal ArticleDOI
Dynamic magnetic MOFs
TL;DR: This review combines the use of coordination chemistry with the concepts of molecular magnetism to design magnetic Metal-Organic Frameworks (MOFs) in which the crystalline network undergoes a dynamic change upon application of an external stimulus.
References
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Journal ArticleDOI
Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound
Eugenio Coronado,José Ramón Galán-Mascarós,José Ramón Galán-Mascarós,Carlos J. Gómez-García,Vladimir Laukhin,Vladimir Laukhin +5 more
TL;DR: The synthesis of single crystals formed by infinite sheets of this magnetic coordination polymer interleaved with layers of conducting BEDT-TTF cations are reported, and it is shown that this molecule-based compound displays ferromagnetism and metallic conductivity.
Journal ArticleDOI
Polyoxometalate-Based Molecular Materials
TL;DR: The present article highlights recent results and provides a perspective of the use of polyoxometalates in the construction of molecule-based materials, combining inorganic metal complexes that act as structural or magnetic components with an organic π-electron donor or acceptor molecule that furnishes the pathway for electronic conductivity.
Journal ArticleDOI
Design of metal-complex magnets. Syntheses and magnetic properties of mixed-metal assemblies {NBu4[MCr(ox)3]}x (NBu4+ = tetra(n-butyl)ammonium ion; ox2- = oxalate ion; M = Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+)
Hiroko Tamaki,Zhuang J. Zhong,Naohide Matsumoto,Sigeo Kida,Masayuki Koikawa,Norio Achiwa,Yuzo Hashimoto,Hisashi Okawa +7 more
TL;DR: The reaction of K 3 [Cr(ox) 3 ].3H 2 O, a metal(II) salt, and tetra(n-butyl)ammonium bromide in the molar ratio of 1:1:1.5 in water at room temperature afforded a series of mixed-metal assemblies with the formula {NBu 4 [MCr(ox), 3 ]} x (M=Mn 2+, Fe 2+, Co 2+
Journal ArticleDOI
Magnetic-field-induced superconductivity in a two-dimensional organic conductor
Shinya Uji,H. Shinagawa,Taichi Terashima,Taro Yakabe,Y. Terai,M. Tokumoto,A. Kobayashi,Hisashi Tanaka,Hayao Kobayashi +8 more
TL;DR: Resistance and magnetic-torque experiments on single crystals of the quasi-two-dimensional organic conductor λ-(BETS)2FeCl4, where BETS is bis(ethylenedithio)tetraselenafulvalene are reported, and it is found that for magnetic fields applied exactly parallel to the conducting layers of the crystals, superconductivity is induced for fields above 17 T at a temperature of 0.1 K.