Magnetocaloric effect and thermal conductivity of Gd(OH)3 and Gd2O(OH)4(H2O)2.
TLDR
Investigation of two gadolinium hydroxides reveals that the thermal conductivity for 1 is significantly better than that for 2, and magnetic studies indicate that both 1 and 2 exhibit antiferromagnetic interaction.About:
This article is published in Chemical Communications.The article was published on 2015-04-14 and is currently open access. It has received 89 citations till now. The article focuses on the topics: Gadolinium & Magnetic refrigeration.read more
Citations
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Ultrastrong Alkali-Resisting Lanthanide-Zeolites Assembled by [Ln60] Nanocages.
TL;DR: These lanthanide-zeolites themselves can efficiently catalyze the cycloaddition of CO2 with epoxides under mild conditions, opening a new space for seeking novel and/or multifunctional zeolites.
Journal ArticleDOI
In-situ synthesis of molecular magnetorefrigerant materials
TL;DR: In this article, the synthesis, structure and magnetochemistry of molecular magnetorefrigerant materials via in-situ synthesis, with an emphasis on the generation of ligands, metal ions and templates.
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Temperature- and vapor-induced reversible single-crystal-to-single-crystal transformations of three 2D/3D GdIII-organic frameworks exhibiting significant magnetocaloric effects.
Sui-Jun Liu,Chen Cao,Shu-Li Yao,Teng-Fei Zheng,Zheng-Xiang Wang,Chao Liu,Jinsheng Liao,Jing-Lin Chen,Yun-Wu Li,He-Rui Wen +9 more
TL;DR: In this paper, a new metal-organic framework (MOF) [Gd(pda)(ox)0.5(H2O)2]n (1) has been successfully constructed and structurally characterized.
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A brilliant cryogenic magnetic coolant: magnetic and magnetocaloric study of ferromagnetically coupled GdF3
Yan-Cong Chen,Jan Prokleška,Wei-Jian Xu,Jun-Liang Liu,Jiang Liu,Wei-Xiong Zhang,Jian-Hua Jia,Vladimír Sechovský,Ming-Liang Tong +8 more
TL;DR: In this paper, the crystal structure, magnetic susceptibility and isothermal magnetization for the inorganic framework material GdF3 were measured, and the isothermal entropy change was evaluated up to 9 T.
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Densely Packed Lanthanide Cubane Based 3D Metal–Organic Frameworks for Efficient Magnetic Refrigeration and Slow Magnetic Relaxation
TL;DR: Magnetic investigations confirm that complex 1 exhibits one of the largest cryogenic magnetocaloric effects among the molecular magnetic refrigerant materials reported so far, and the structural analyses reveal the presence of a self-assembled crown-shaped building unit with a cubane-based rectangular moiety that leads to a special array of metal centers in 3D space in the complexes.
References
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Flash Method of Determining Thermal Diffusivity, Heat Capacity, and Thermal Conductivity
TL;DR: In this paper, a high-intensity short-duration light pulse is absorbed in the front surface of a thermally insulated specimen, and the resulting temperature history of the rear surface is measured by a thermocouple and recorded with an oscilloscope and camera.
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Magnetocaloric effect and magnetic refrigeration
TL;DR: In this article, the magnetocaloric effect along with recent progress and future needs in both the characterization and exploration of new magnetic refrigerant materials with respect to their magnetoric properties are discussed.
Book
Physical properties of crystals
TL;DR: The International Tables for Crystallography as mentioned in this paper is the definitive resource and reference work for crystallography and structural science, containing articles and tables of data relevant to crystallographic research and to applications of crystallographic methods in all sciences concerned with the structure and properties of materials.
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Recent Progress in Exploring Magnetocaloric Materials
TL;DR: The magnetocaloric effect (MCE) has attracted increasing interest because of its high efficiency and environment friendliness as mentioned in this paper, and the recent progress in exploring effective MCE materials is reviewed with emphasis on the MCE in the LaFe13-x6-based alloys discovered by us.
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Thirty years of near room temperature magnetic cooling: Where we are today and future prospects
TL;DR: The seminal study by Brown in 1976 showed that it was possible to use the magnetocaloric effect to produce a substantial cooling effect near room temperature as discussed by the authors, and since then, over 25 magnetic cooling units have been built and tested throughout the world.