Plant oils: The perfect renewable resource for polymer science?!
Reads0
Chats0
TLDR
In this paper, the authors provide an overview of the present situation with special attention to the use of olefin metathesis and thiol-ene chemistry as synthetic methods and as polymerization techniques.About:
This article is published in European Polymer Journal.The article was published on 2011-05-01 and is currently open access. It has received 551 citations till now.read more
Citations
More filters
Journal ArticleDOI
Olefin cross-metathesis as a valuable tool for the preparation of renewable polyesters and polyamides from unsaturated fatty acid esters and carbamates
TL;DR: Olefin cross-metathesis of unsaturated fatty acid methyl ester (FAME) derived benzyl carbamates with methyl acrylate is described in this article, where the obtained byproduct, an α,β-unsaturated ester, was further modified via thia-Michael addition reactions in order to synthesize branched AA-type or AB-type monomers for the preparation of polyesters.
Journal ArticleDOI
From Polyethylene to Polyester: Influence of Ester Groups on the Physical Properties
TL;DR: The melting temperature of these ALCPEs showed an inverse proportional trend with respect to the amount of ester groups in the polymer structure, ranging from 132.1 °C (M/E = ∞) to 91.5 °C as discussed by the authors.
Journal ArticleDOI
Synthesis and application of novel UV-curable hyperbranched methacrylates from renewable natural tannic acid
TL;DR: In this article, an acrylated epoxidized soybean oil (AESO) was combined with a novel kind of biorenewable tannic acid-based hyperbranched methacrylates (TAHAs).
Journal ArticleDOI
Properties of alkoxysilane castor oil synthesized via thiol-ene and its polyurethane/siloxane hybrid coating films
TL;DR: In this article, a new silanized castor oil (MSCO) composed of 3-mercaptopropyl trimethoxy silane via thiol-ene coupling (TEC) was used as a functional polyol in the preparation of a series of bio-based polyurethane/siloxane (SiPU) hybrid coatings through reactions with different castor-oil-and-isophorone-diisocyanate (IPDI) ratios.
Journal ArticleDOI
Photoinitiator Free Resins Composed of Plant-Derived Monomers for the Optical µ-3D Printing of Thermosets.
TL;DR: Here, for the first time, it is validated that pure AESO and mixtures of AESo and VDM can be used for 3D microstructuring by employing direct laser writing lithography technique.
References
More filters
Journal ArticleDOI
Thiol–Ene Click Chemistry
TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
Journal ArticleDOI
Recent developments in the chemistry of halogen-free flame retardant polymers
Shuiyu Lu,Ian Hamerton +1 more
TL;DR: An overview of recent developments of the chemistry of halogen-free flame retardant polymers is presented in this article, along with their thermal stabilities and flame-retardant properties.
Journal ArticleDOI
Thiol-ene “click” reactions and recent applications in polymer and materials synthesis
TL;DR: In this paper, a review highlights examples of recent applications of both the radical-mediated and base/nucleophile-initiated thiol-ene reactions in polymer and materials synthesis.
Journal ArticleDOI
Plant oil renewable resources as green alternatives in polymer science
TL;DR: The synthesis of monomers as well as polymers from plant fats and oils has already found some industrial application and recent developments in this field offer promising new opportunities, as is shown within this contribution.
Journal ArticleDOI
Click Chemistry beyond Metal-Catalyzed Cycloaddition
TL;DR: This Minireview discusses the success and applicability of new, in particular metal-free, click reactions, which expand the opportunities for synthesizing small organic compounds as well as tailor-made macromolecules and bioconjugates.
Related Papers (5)
Vegetable oil-based polymeric materials: synthesis, properties, and applications
Ying Xia,Richard C. Larock +1 more