Plant oils: The perfect renewable resource for polymer science?!
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TLDR
In this paper, the authors provide an overview of the present situation with special attention to the use of olefin metathesis and thiol-ene chemistry as synthetic methods and as polymerization techniques.About:
This article is published in European Polymer Journal.The article was published on 2011-05-01 and is currently open access. It has received 551 citations till now.read more
Citations
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Effect of process conditions on the properties of castor oil maleate and styrene copolymer produced by bulk polymerization
TL;DR: In this paper, the influence of process conditions on the chemical characteristics and yield of polymers based on castor oil was evaluated, and a wide range of molecular weights (Mw from 15,809 to 38,656) could be produced, with dispersity ranging from 2.0 to 4.8.
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Vinyl ester resin modified with acrylated epoxidised soybean (AESO) and linseed (AELO) oils: effect of additional urethane crosslinking
TL;DR: In this paper, Bisphenol A-based vinyl ester resin (VE) was modified with acrylated epoxidised soybean and linseed oils (AESO and AELO, respectively) in 10 wt.
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Effect of functionality and content of epoxidized soybean oil on the physical properties of a modified diglycidyl ether of bisphenol A resin system
Seok Jin Lim,Dae Su Kim +1 more
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Dual catalytic performance of arene‐ruthenium amine complexes for norbornene ring‐opening metathesis and methyl methacrylate atom‐transfer radical polymerizations
Thais R. Cruz,Eliada A. Silva,Douglas P. Oliveira,Daniele M. Martins,Patrik D.S. Gois,Antonio E.H. Machado,Pedro I. S. Maia,Beatriz E. Goi,Benedito S. Lima-Neto,Valdemiro P. Carvalho-Jr +9 more
TL;DR: In this article, the authors present a study of the relationship between the Universidade de São Paulo and Uberlândia in Brazil, where the authors propose a method to use the UNESP-Universidadão de Ciências e Tecnologia (UNESP) to train a research team.
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Phosphorus-based fatty acid methyl esters.
TL;DR: A base-induced dehydrochlorination reaction using ArPCl2 and hydroxy-terminated fatty esters resulted in metastable diester for which hydrolytic cleavage undergo phosphine oxidation and expulsion of one fatty chain, and ArPOCl2 provides stable, phosphorylated fatty acid diesters.
References
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Thiol–Ene Click Chemistry
TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
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Recent developments in the chemistry of halogen-free flame retardant polymers
Shuiyu Lu,Ian Hamerton +1 more
TL;DR: An overview of recent developments of the chemistry of halogen-free flame retardant polymers is presented in this article, along with their thermal stabilities and flame-retardant properties.
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Thiol-ene “click” reactions and recent applications in polymer and materials synthesis
TL;DR: In this paper, a review highlights examples of recent applications of both the radical-mediated and base/nucleophile-initiated thiol-ene reactions in polymer and materials synthesis.
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Plant oil renewable resources as green alternatives in polymer science
TL;DR: The synthesis of monomers as well as polymers from plant fats and oils has already found some industrial application and recent developments in this field offer promising new opportunities, as is shown within this contribution.
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Click Chemistry beyond Metal-Catalyzed Cycloaddition
TL;DR: This Minireview discusses the success and applicability of new, in particular metal-free, click reactions, which expand the opportunities for synthesizing small organic compounds as well as tailor-made macromolecules and bioconjugates.
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