Plant oils: The perfect renewable resource for polymer science?!
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TLDR
In this paper, the authors provide an overview of the present situation with special attention to the use of olefin metathesis and thiol-ene chemistry as synthetic methods and as polymerization techniques.About:
This article is published in European Polymer Journal.The article was published on 2011-05-01 and is currently open access. It has received 551 citations till now.read more
Citations
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Journal ArticleDOI
Synthesis of plant oil-based amide copolymethacrylates and their use as viscosity index improvers
Juliette Lomège,Violette Mohring,Vincent Lapinte,Claire Negrell,Jean-Jacques Robin,Sylvain Caillol +5 more
TL;DR: In this paper, polymeric materials derived from fatty acids (FA)s were synthesized through free radical polymerization and evaluated as viscosity index improvers (VII) in an organic triglyceride lube oil (OTO).
Journal ArticleDOI
Correction to Synthesis and Characterization of Thermosetting Furan-Based Epoxy Systems
TL;DR: In this paper, an important error in that work regarding the preparation of the benzyl-based analogue systems (BOB) was discovered, which resulted in epoxy-rich systems being tested that have lower Tg than those prepared at stoichiometry.
DissertationDOI
Synthesis of Stimuli-responsive Hydrogels from Glycerol
TL;DR: The step-growth polymerization of glycerol to relatively high molecular weight polyglycerol was investigated and several soluble catalysts and their reaction mechanisms were compared and their effect on polymer molecular weight and microstructure was measured.
Journal ArticleDOI
Allylic oxidation of methyl 10‐undecenoate and nucleophilic additions to methyl 9‐oxo‐10‐undecenoate
Ludger Hinkamp,Hans J. Schäfer +1 more
TL;DR: In this paper, the electrophilic double bond in enone 4 reacts in good to excellent yield with a variety of nucleophiles, including methyl malonate, acetylacetone, and methyl acetoacetate Michael-adducts.
Journal ArticleDOI
Acyclic triene metathesis (ATMET) miniemulsion polymerization of linseed oil produces polymer nanoparticles with comparable molecular weight to that of bulk reactions
Cristian de Oliveira Romera,Priscilla Barreto Cardoso,Michael A. R. Meier,Claudia Sayer,Pedro Henrique Hermes de Araújo +4 more
TL;DR: In this paper, a cyclic triene metathesis (ATMET) polymerization of linseed oil was performed in bulk and mini-emulsion to evaluate the activity of different types of ruthenium-based catalysts (Grubbs 1st and 2nd generations, Hoveyda-grubbs 2nd generation and Umicore M2) in both systems.
References
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Journal ArticleDOI
Thiol–Ene Click Chemistry
TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
Journal ArticleDOI
Recent developments in the chemistry of halogen-free flame retardant polymers
Shuiyu Lu,Ian Hamerton +1 more
TL;DR: An overview of recent developments of the chemistry of halogen-free flame retardant polymers is presented in this article, along with their thermal stabilities and flame-retardant properties.
Journal ArticleDOI
Thiol-ene “click” reactions and recent applications in polymer and materials synthesis
TL;DR: In this paper, a review highlights examples of recent applications of both the radical-mediated and base/nucleophile-initiated thiol-ene reactions in polymer and materials synthesis.
Journal ArticleDOI
Plant oil renewable resources as green alternatives in polymer science
TL;DR: The synthesis of monomers as well as polymers from plant fats and oils has already found some industrial application and recent developments in this field offer promising new opportunities, as is shown within this contribution.
Journal ArticleDOI
Click Chemistry beyond Metal-Catalyzed Cycloaddition
TL;DR: This Minireview discusses the success and applicability of new, in particular metal-free, click reactions, which expand the opportunities for synthesizing small organic compounds as well as tailor-made macromolecules and bioconjugates.
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