Plant oils: The perfect renewable resource for polymer science?!
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TLDR
In this paper, the authors provide an overview of the present situation with special attention to the use of olefin metathesis and thiol-ene chemistry as synthetic methods and as polymerization techniques.About:
This article is published in European Polymer Journal.The article was published on 2011-05-01 and is currently open access. It has received 551 citations till now.read more
Citations
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Progress of Polymers from Renewable Resources: Furans, Vegetable Oils, and Polysaccharides
TL;DR: Oils, and Polysaccharides Alessandro Gandini,*,‡ Talita M. Lacerda,†,‡ Antonio J. F. Carvalho,† and Eliane Trovatti†.
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Progress in Renewable Polymers from Natural Terpenes, Terpenoids, and Rosin
TL;DR: This review covers recent progress in the field of renewable bio-based monomers and polymers from natural resources: terpenes, terpenoids, and rosin, which are a class of hydrocarbon-rich biomass with abundance and low cost, holding much potential for utilization as organic feedstocks for green plastics and composites.
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From monomers to polymers from renewable resources: Recent advances
TL;DR: In this article, the authors present a panoramic overview of the recent progress, but mainly of the broad possibilities that are still available in the hands of researchers working on this topic.
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Recent advances in vegetable oil-based polymers and their composites
Chaoqun Zhang,Thomas F. Garrison,Thomas F. Garrison,Samy A. Madbouly,Samy A. Madbouly,Michael R. Kessler +5 more
TL;DR: A review of recent advances in polymeric materials from vegetable oils in terms of preparation, characterization, and properties can be found in this article, where nano-composites and fiber reinforced composites based on bio-polymers matrices are reviewed.
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A Review of Natural Fibers Used in Biocomposites: Plant, Animal and Regenerated Cellulose Fibers
TL;DR: In this paper, the reinforcement potential of natural fibers and their properties have been described in numerous papers and the chemical composition and properties of each of the fibers changes, which demands the detailed comparison of these fibers.
References
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Rubbery Thermosets by Ring‐Opening Metathesis Polymerization of a Functionalized Castor Oil and Cyclooctene
TL;DR: In this article, a modified castor oil containing norbornene moieties and cyclooctene has been synthesized and characterized and the results showed that the presence of the soluble fractions helps to plasticize the materials and give added thermal stability.
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Biobased thermosets from the free‐radical copolymerization of conjugated linseed oil
TL;DR: In this paper, the bulk free-radical copolymerization of 100% conjugated linseed oil, acrylonitrile, and divinylbenzene was used to construct polymeric thermosets.
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Acyclic Triene Metathesis Oligo‐ and Polymerization of High Oleic Sun Flower Oil
TL;DR: In this article, high oleic sunflower oil, a renewable raw material consisting of triglycerides with internal C=C-double bonds, was polymerized via acyclic triene metathesis (ATMET) to highly branched and functionalized polyesters.
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Studying and Suppressing Olefin Isomerization Side Reactions During ADMET Polymerizations.
TL;DR: It was shown that the addition of benzoquinone to the polymerization mixture prevented the olefin isomerization and second generation ruthenium metathesis catalysts may now be used for the preparation of well-defined polymers via ADMET with very little isomersization, which was not possible before.
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Preparation of acrylated and urethanated triacylglycerols
TL;DR: In this article, a preliminary study had shown that the internal double bonds present on the unsaturated aliphatic chains were too unreactive for any viable polymerization process, chemical modifications were investigated involving the grafting of polymerizable moieties on hydroxy or epoxide groups present in castor oil or in epoxidized soybean oil.
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