Plant oils: The perfect renewable resource for polymer science?!
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TLDR
In this paper, the authors provide an overview of the present situation with special attention to the use of olefin metathesis and thiol-ene chemistry as synthetic methods and as polymerization techniques.About:
This article is published in European Polymer Journal.The article was published on 2011-05-01 and is currently open access. It has received 551 citations till now.read more
Citations
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Pressure Sensitive Adhesives Based on Epoxidized Soybean Oil: Correlation Between Curing Conditions and Rheological Properties
TL;DR: Ciannamea et al. as discussed by the authors presented a model for the study of the relationship between Ingenieria and Científicos in Ciencia y Tecnologia de Materiales.
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Isomerizing Hydroformylation of Cashew Nut Shell Liquid
TL;DR: In this paper, a small library of bisphosphorus ligands was evaluated in the rhodium-catalyzed isomerizing hydroformylation (I-HF) of cashew nut shell liquid (CNSL).
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Rapeseed Oil as Renewable Resource for Polyol Synthesis
TL;DR: In this paper, the reaction of Ro amidization with DEA was investigated, as well as optimum conditions for polyol synthesis was established to obtain polyols for polyurethane production.
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Synthesis of a biobased monomer derived from castor oil and copolymerization in aqueous medium
Larissa S. Laurentino,Larissa S. Laurentino,Anderson M. M. S. Medeiros,Anderson M. M. S. Medeiros,Fabricio Machado,Cristiane Costa,Pedro Henrique Hermes de Araújo,Claudia Sayer +7 more
TL;DR: In this article, the double-bonded double bonds of ricinoleic acid were epoxied in the presence of acrylic acid to form acrylated ricinolesic acid (ARA) and free radical copolymerizations of ARA and methyl methacrylate (MMA) were carried out in miniemulsion, resulting in latexes stable over a long storage time.
References
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Thiol–Ene Click Chemistry
TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
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Recent developments in the chemistry of halogen-free flame retardant polymers
Shuiyu Lu,Ian Hamerton +1 more
TL;DR: An overview of recent developments of the chemistry of halogen-free flame retardant polymers is presented in this article, along with their thermal stabilities and flame-retardant properties.
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Thiol-ene “click” reactions and recent applications in polymer and materials synthesis
TL;DR: In this paper, a review highlights examples of recent applications of both the radical-mediated and base/nucleophile-initiated thiol-ene reactions in polymer and materials synthesis.
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Plant oil renewable resources as green alternatives in polymer science
TL;DR: The synthesis of monomers as well as polymers from plant fats and oils has already found some industrial application and recent developments in this field offer promising new opportunities, as is shown within this contribution.
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Click Chemistry beyond Metal-Catalyzed Cycloaddition
TL;DR: This Minireview discusses the success and applicability of new, in particular metal-free, click reactions, which expand the opportunities for synthesizing small organic compounds as well as tailor-made macromolecules and bioconjugates.
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