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Porosity effect on the electrical conductivity of sintered powder compacts

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Abstract
A new equation for calculating the electrical conductivity of sintered powder compacts is proposed. In this equation, the effective resistivity of porous compacts is a function of the fully dense material conductivity, the porosity of the compact and the tap porosity of the starting powder. The new equation is applicable to powder sintered compacts from zero porosity to tap porosity. A connection between this equation and the percolation conduction theory is stated. The proposed equation has been experimentally validated with sintered compacts of six different metallic powders. Results confirm very good agreement with theoretical predictions.

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Journal ArticleDOI

Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review

TL;DR: The early history, synthesis and characterization, mechanical properties, and Li+ ion transport mechanisms of inorganic sulfide and oxide electrolytes, and promising electrolyte systems based on sulfides and argyrodites are reported.
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Li7PS6 and Li6PS5X (X: Cl, Br, I): Possible Three-dimensional Diffusion Pathways for Lithium Ions and Temperature Dependence of the Ionic Conductivity by Impedance Measurements

TL;DR: In this paper, the specific Li-ionic conductivities of the lithium argyrodites Li7PS6 and Li6PS5X (X: Cl, Br, I) and their temperature dependences are measured by impedance spectroscopy using different electron-blocking and ion-blocking electrode systems.
Journal ArticleDOI

Influence of porosity on the bulk and grain-boundary electrical properties of Gd-doped ceria

TL;DR: In this paper, the effects of porosity on the grain and grain-boundary transport properties of the solid-state electrolyte Ce 0.9 Gd 0.1 O 1.95 (CGO) have been analyzed with a modified brick-layer model.
Journal ArticleDOI

Flexible Polymeric Substrates for Electronic Applications

TL;DR: In this paper, a flexible substrate is defined when the material is processed such that individual component complies to a comparable degree of bending without deterioration of electronic/optoelectronic performance.
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Smart nanopaper based on cellulose nanofibers with hybrid PEDOT:PSS/polypyrrole for energy storage devices

TL;DR: It is concluded that the good mechanical, electrical and electrochemical properties of the ternary formulation can apply for smart nanopaper in flexible electronics and energy storage devices.
References
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Book

A Treatise on Electricity and Magnetism

TL;DR: The most influential nineteenth-century scientist for twentieth-century physics, James Clerk Maxwell (1831-1879) demonstrated that electricity, magnetism and light are all manifestations of the same phenomenon: the electromagnetic field as discussed by the authors.
Book

Introduction to percolation theory

TL;DR: In this article, a scaling solution for the Bethe lattice is proposed for cluster numbers and a scaling assumption for cluster number scaling assumptions for cluster radius and fractal dimension is proposed.
Journal ArticleDOI

A Mathematical Treatment of the Electric Conductivity and Capacity of Disperse Systems I. The Electric Conductivity of a Suspension of Homogeneous Spheroids

TL;DR: In this article, the authors derived a relation between the specific conductivities of the suspension, the suspending medium and the suspended spheroids, and the volume concentration of the spheroid, where $x$ is a function of the ratio
Journal ArticleDOI

On a relation between percolation theory and the elasticity of gels

TL;DR: In this paper, the authors compare the macroscopic conductance of a resistor network with a fraction p of conducting links, and the elastic modulus E of a gel obtained by polymerization of z-functional units (p being the fraction of reacted bonds).
Journal ArticleDOI

Thermal Conductivity: VIII, A Theory of Thermal Conductivity of Porous Materials

TL;DR: In this article, the effective thermal conductivity of a porous material is due to both conduction and radiation processes, and a theory is presented relating the effective conductivity to the conductivities of the solid material, to the emissivity of the surface of the pores, and to the size, shape, and distribution of the porous material.
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