Journal ArticleDOI
Precision Measurements of the Lattice Constants of Twelve Common Metals
TLDR
In this article, the lattice constant for aluminum, iron, nickel, copper, molybdenum, palladium, silver, tungsten, platinum, gold, lead and bismuth was determined within 1 percent (03 percent for W) for aluminum.Abstract:
The lattice constant $a$ has been determined within 01 percent (03 percent for W) for aluminum, iron, nickel, copper, molybdenum, palladium, silver, tungsten, platinum, gold, lead and bismuth, by direct comparison with NaCl, $a(\mathrm{NaCl})=2814$A As pure samples as could be obtained were used, from 9955 percent for Ni to 999995 percent for tungsten, and in many cases commercially pure samples were also measured for comparison The results for the purest samples are summarized in Table XIII The density from the x-ray data is in each case (except Al and Ag) greater than the density of the bulk metal as given in the literature, the difference being rather large for Mo (1021 vs 91), for Pd (1225 vs 119) and W (1932 vs 1877) For pure W remarkably sharp lines were obtained For Bi a piece of a single artificial crystal was usedread more
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Bismuthene for highly efficient carbon dioxide electroreduction reaction
Yang Fa,Yang Fa,Ahmed O. Elnabawy,Roberto Schimmenti,Ping Song,Jiawei Wang,Zhangquan Peng,Shuang Yao,Ruiping Deng,Shuyan Song,Yue Lin,Manos Mavrikakis,Weilin Xu,Weilin Xu +13 more
TL;DR: A large-scale synthesis of free-standing Bismuthene is shown and its electrocatalytic activity for CO 2 reduction to formate is demonstrated, suggesting that selective formation of HCOO − indeed can proceed easily on BismUThene (111) facet due to the unique compressive strain.
Journal ArticleDOI
Cysteine-Induced Modifications of Zero-valent Silver Nanomaterials: Implications for Particle Surface Chemistry, Aggregation, Dissolution, and Silver Speciation
Andreas Gondikas,Andreas Gondikas,Amanda J. Morris,Amanda J. Morris,Brian C. Reinsch,Brian C. Reinsch,Stella M. Marinakos,Gregory V. Lowry,Gregory V. Lowry,Heileen Hsu-Kim,Heileen Hsu-Kim +10 more
TL;DR: The findings of this study demonstrate the need to consider multiple interlinked transformation processes when assessing the bioavailability, environmental risks, and safety of nanoparticles, particularly in the presence of metal-binding ligands.
Journal ArticleDOI
Single-particle mapping of nonequilibrium nanocrystal transformations
Xingchen Ye,Matthew R. Jones,Layne B. Frechette,Qian Chen,Alexander S. Powers,Peter Ercius,Gabriel Dunn,Grant M. Rotskoff,Son C. Nguyen,Vivekananda P. Adiga,Alex Zettl,Alex Zettl,Eran Rabani,Eran Rabani,Eran Rabani,Phillip L. Geissler,A. Paul Alivisatos +16 more
TL;DR: Understanding reaction trajectories provides important fundamental insight connecting high-energy nanocrystal morphologies to the development of kinetically stabilized surface features and demonstrates the importance of developing tools capable of probing short-lived nanoscale species at the single-particle level.
Journal ArticleDOI
Establishing the Accuracy of Broadly Used Density Functionals in Describing Bulk Properties of Transition Metals.
TL;DR: A systematic study shows that PW91 and PBE consistently provide the smallest differences between the calculated and experimental values, which may be the origin for the reduced surface chemical activity and the better performance of RPBE describing adsorption energies.
Journal ArticleDOI
Cellular uptake and transport of gold nanoparticles incorporated in a liposomal carrier.
Devika B. Chithrani,Michael Dunne,James Stewart,Christine Allen,David A. Jaffray,David A. Jaffray +5 more
TL;DR: The liposomal approach resulted in a thousand-fold enhancement in the cellular uptake of Au NPs compared to conventional delivery methods, with the nanoparticles residing in lysosomes within 40 minutes of incubation.
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