Journal ArticleDOI
PtCl4‐Catalyzed Domino Synthesis of Fused Bicyclic Acetals
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This article is published in Angewandte Chemie.The article was published on 2008-01-01. It has received 91 citations till now. The article focuses on the topics: Hydroalkoxylation & Bicyclic molecule.read more
Citations
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Recent advances in catalytic sequential reactions involving hydroelement addition to carbon-carbon multiple bonds.
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Gold‐Catalyzed Dehydrative Transformations of Unsaturated Alcohols
Berenger Biannic,Aaron Aponick +1 more
TL;DR: In this article, a review of Au-catalyzed substitution reactions of unsaturated alcohols in which water serves as a leaving group is given, and the mechanisms by which the reactions are believed to occur are also reviewed.
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Au-Catalyzed Cyclization of Monopropargylic Triols: An Expedient Synthesis of Monounsaturated Spiroketals
TL;DR: The gold-catalyzed cyclization of monopropargylic triols to form olefin-containing spiroketals is reported, which is rapid and high yielding when 2 mol % of the catalyst generated in situ from Au[P(t-Bu)(2)(o-biphenyl)]Cl and AgOTf is employed in THF.
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Highly efficient chemoselective synthesis of polysubstituted pyrroles via isocyanide-based multicomponent domino reaction.
TL;DR: A multicomponent domino reaction for the chemoselective, catalyst-free synthesis of polysubstituted pyrroles from readily available isocyanides, primary or secondary amines, and gem-diactivated olefins has been developed.
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Gold catalyzed oxycyclizations of alkynols and alkyndiols
TL;DR: This overview focuses on the most recent achievements on gold-catalyzed oxycyclizations, both from alkynols and alkyndiols, and their use in different cascade processes and total synthesis.
References
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Journal ArticleDOI
Gold-Catalyzed Organic Reactions
TL;DR: Important vinylgold intermediates, the transmetalation from gold to other transition metals, the development of new ligands for gold catalysis, and significant contributions from computational chemistry are other crucial points for the field highlighted here.
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Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids
Alois Fürstner,Paul W. Davies +1 more
TL;DR: The ability of platinum and gold catalysts to effect powerful atom-economic transformations has led to a marked increase in their utilization and the application of platinum- and gold-catalyzed transformations in natural product synthesis is discussed.
Journal ArticleDOI
Cascade reactions in total synthesis.
TL;DR: The power of cascade reactions in total synthesis is illustrated in the construction of complex molecules and underscore their future potential in chemical synthesis.
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Transition-metal-catalyzed addition of heteroatom-hydrogen bonds to alkynes.
Book
Domino Reactions in Organic Synthesis
TL;DR: It is shown that domino reactions initiated by oxidation or reduction or reduction, as well as other mechanisms, can be inhibited by various materials, such as Na6(CO3)(SO4), Na2SO4, Na2CO3, and so on.