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Reaction products, structure and properties of alkali-activated metakaolin cements incorporated with supplementary materials – a review

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TLDR
In this article, the authors present a review of the properties and properties of mixed alkali-activated metakaolin cements incorporating with mineral supplementary materials from the point of view of the supplementary additions raw materials base, features of reaction products, structure, properties and formation process.
Abstract
Incorporation of mineral blending and/or modifying additions which are single- or multi-component materials is one of the main trends in the development of both Portland clinker-based and non-clinker cements. There is an increasing scientific and industrial interest in alkali-activated binders as ecologically and technically promising inorganic materials. Progress in this area is also derived from advances in the technologies of production and processing of a wider range of mineral materials from natural and waste origins, and by constant expansion of the raw materials base of alkali-activated materials. This paper reviews (i) alkali-activated metakaolin-based cements incorporated with mineral supplementary materials from the point of view of the supplementary additions raw materials base, features of reaction products, structure, properties and formation process; (ii) a range and classification of mineral additions to alkali-activated metakaolin cements; (iii) the feasibilities of improving the structure and properties of mixed alkali-activated metakaolin cements.

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Journal ArticleDOI

Alkali-silica reaction in concrete: Mechanisms, mitigation and test methods

TL;DR: The most recent and relevant achievements and the existing knowledge concerning the reaction mechanisms of ASR are reviewed, and the conditioning factors, diagnostic and prognostic methodologies, preventive measures and test methods (including their limitations) conducted at an academic level are reviewed.
Journal ArticleDOI

Correlation between initial SiO2/Al2O3, Na2O/Al2O3, Na2O/SiO2 and H2O/Na2O ratios on phase and microstructure of reaction products of metakaolin-rice husk ash geopolymer

TL;DR: In this article, phase evolution and microstructure development of metakaolin-rice husk ash geopolymer have been investigated, and the initial molar ratios of SiO2/Al2O3 were designed in the range of 2.0-7.0 with Na2O/Al 2O3 ratios of 0.6-1.6, NaO/SiO2 of 0.,20-0.72 and H2O-Na2O of 10.0 -20.0, respectively.
Journal ArticleDOI

Reaction mechanisms of alkali-activated materials

TL;DR: The main products obtained in the alkaline activation reaction were also addressed, using the definition of polysialates and zeolites, in the case of geopolymers, and the tobermorite structure, in case of materials rich in calcium as mentioned in this paper.
Journal ArticleDOI

Alkali-Activated Materials and Geopolymer: a Review of Common Precursors and Activators Addressing Circular Economy

TL;DR: In this paper, the authors reviewed different types, mechanisms, and result of mechanical and durability properties of alkali-activated materials and geopolymer reported in literature and discussed future projections of waste materials that have cementitious properties and can replace ordinary Portland cement and be used in alkali activated materials.
Journal ArticleDOI

Properties of geopolymer sourced from construction and demolition waste: A review

TL;DR: In this paper , the authors reviewed the current state-of-the-art on the geopolymer paste, mortar, and concrete production and their properties, with special attention paid to geopolymers incorporating CDW.
References
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Journal ArticleDOI

Geopolymer technology: the current state of the art

TL;DR: A brief history and review of geopolymer technology is presented with the aim of introducing the technology and the vast categories of materials that may be synthesized by alkali activation of aluminosilicates as mentioned in this paper.
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Supplementary cementitious materials

TL;DR: The use of silica-rich SCMs influences the amount and kind of hydrates formed and thus the volume, the porosity and finally the durability of these materials.
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The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation

TL;DR: In this paper, the effects of ground granulated blast furnace slag (GGBFS) on the microstructure and mechanical properties of metakaolin (MK) based geopolymers were studied.
Journal ArticleDOI

Cement substitution by a combination of metakaolin and limestone

TL;DR: In this paper, the coupled substitution of metakaolin and limestone in Portland cement (PC) was investigated and the mechanical properties were studied in mortars and the microstructural development in pastes by X-ray diffraction, thermogravimetry analysis, mercury intrusion porosimetry and isothermal calorimetry.
Journal ArticleDOI

Fire-resistant geopolymer produced by granulated blast furnace slag

TL;DR: In this paper, the use of granulated blast furnace slag as an active filler in the making of geopolymers was described, and a 10 mm thick geopolymer panel was exposed to a 1100 °C flame, with the measured reverse-side temperatures reaching less than 350 °C after 35 min.
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