Reactions of Ferrate(VI) with Iodide and Hypoiodous Acid: Kinetics, Pathways, and Implications for the Fate of Iodine during Water Treatment

TLDR: Overall, due to a rapid oxidation of I- to IO3- with short-lifetimes of HOI, ferrate(VI) oxidation appears to be a promising option for I-DBP mitigation during treatment of I--containing waters.

Abstract: Oxidative treatment of iodide-containing waters can form toxic iodinated disinfection byproducts (I-DBPs). To better understand the fate of iodine, kinetics, products, and stoichiometries for the reactions of ferrate(VI) with iodide (I–) and hypoiodous acid (HOI) were determined. Ferrate(VI) showed considerable reactivities to both I– and HOI with higher reactivities at lower pH. Interestingly, the reaction of ferrate(VI) with HOI (k = 6.0 × 103 M–1 s–1 at pH 9) was much faster than with I– (k = 5.6 × 102 M–1 s–1 at pH 9). The main reaction pathway during treatment of I–-containing waters was the oxidation of I– to HOI and its further oxidation to IO3– by ferrate(VI). However, for pH > 9, the HOI disproportionation catalyzed by ferrate(VI) became an additional transformation pathway forming I– and IO3–. The reduction of HOI by hydrogen peroxide, the latter being produced from ferrate(VI) decomposition, also contributes to the I– regeneration in the pH range 9–11. A kinetic model was developed that could w...