Journal ArticleDOI
Recent advances in acyl radical enabled reactions between aldehydes and alkenes
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TLDR
A summary of the state of the art in this field with a specific emphasis on the working models and corresponding mechanisms is provided in this paper, where the discussion is divided according to the kind of alkenes and reaction type.About:
This article is published in Chemical Communications.The article was published on 2021-06-22. It has received 23 citations till now.read more
Citations
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Cu(I)-Catalyzed Chemo- and Enantioselective Desymmetrizing C-O Bond Coupling of Acyl Radicals.
Zhangshou Yu,Yong-Feng Cheng,Ji-Ren Liu,Wu Yang,Dan Xu,Yu Tian,Jun-Qian Bian,Zhong‐Liang Li,Li-Wen Fan,Cheng Luan,Ang Gao,Qiang-Shuai Gu,Xin-Yuan Liu +12 more
TL;DR: In this paper , a transition-metal-catalyzed enanti-lective desymmetrizing C-O bond coupling of acyl radicals was proposed for the rapid preparation of chiral C3 building blocks from readily available alcohols, particularly the industrially relevant glycerol.
Journal ArticleDOI
Tandem vinyl radical Minisci-type annulation on pyridines: one-pot expeditious access to azaindenones
Dong Xia,Xin-Fang Duan +1 more
TL;DR: In this paper, a new regiospecific alkylative/alkenylative cascade annulation of pyridines has been achieved whilst the corresponding classic Minisci alky lative annulation failed.
Journal ArticleDOI
α-Acylation of Alkenes by a Single Photocatalyst.
TL;DR: In this paper , a single photocatalyst driven α-acylation of fluoromethyl-, alkyl-, sulfonyl- and thiolation of alkenes with high chemo-and regioselectivity under extremely mild conditions is presented.
Journal ArticleDOI
Visible-light induced transition-metal and photosensitizer-free conversion of aldehydes to acyl fluorides under mild conditions
TL;DR: In this article , a green method for the synthesis of acyl fluorides from aldehydes via C(sp2)-H fluorination is presented, in the absence of transition-metal and external photosensitizer.
Journal ArticleDOI
Photoredox‐Mediated Deoxygenative Radical Additions of Aromatic Acids to Vinyl Boronic Esters and gem‐Diborylalkenes
TL;DR: In this paper , a deoxygenative radical addition of aromatic carboxylic acids to gem-dibortlalkenes is described, in which the reaction proceeds under mild photoredox catalysis and involves the photochemical C−O bond activation of aromatic CARB in the presence of PPh3.
References
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Journal ArticleDOI
Catalytic Asymmetric Dihydroxylation
Journal ArticleDOI
Cross-dehydrogenative coupling (CDC): exploring C-C bond formations beyond functional group transformations.
TL;DR: This work over the past several years to form carbon-carbon bonds directly from two different C-H bonds under oxidative conditions, cross-dehydrogenative coupling (CDC) is described, which provides an alternative to the separate steps of prefunctionalization and defunctionsalization that have traditionally been part of synthetic design.
Journal ArticleDOI
Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation
TL;DR: This critical review covers the recent progresses on the regioselective dehydrogenative direct coupling reaction of heteroarenes, including arylation, olefination, alkynylation, and amination/amidation mainly utilizing transition metal catalysts.
Journal ArticleDOI
Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions
TL;DR: Oxidative X-X Bond Formations between Two Nucleophiles 1819 5.1.
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