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Recent progress in research on tungsten materials for nuclear fusion applications in Europe

Michael Rieth, +70 more
- 01 Jan 2013 - 
- Vol. 432, Iss: 1, pp 482-500
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TLDR
In this article, the progress of work within the EFDA long-term fusion materials program in the area of tungsten alloys is reviewed, with a detailed overview of the latest results on materials research, fabrication processes, joining options, high heat flux testing, plasticity studies, modelling, and validation experiments.
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This article is published in Journal of Nuclear Materials.The article was published on 2013-01-01 and is currently open access. It has received 599 citations till now.

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Nuclear fusion

TL;DR: The advantages of nuclear fusion as an energy source and research progress in this area are summarized in this article, where the current state of the art is described, including the Compact Ignition Tokamak (CIT), International Thermonuclear Experimental Reactor (ITER), and a US design called TIBER II.
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Designing Radiation Resistance in Materials for Fusion Energy

TL;DR: In this article, three fundamental options for designing radiation resistance are outlined: Utilize matrix phases with inherent radiation tolerance, select materials in which vacancies are immobile at the design operating temperatures, or engineer materials with high sink densities for point defect recombination.
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Primary radiation damage: A review of current understanding and models

TL;DR: In this article, the authors consider the extensive experimental and computer simulation studies that have been performed over the past several decades on what the nature of the primary damage is, and provide alternatives to the current international standard for quantifying this energetic particle damage, the Norgett-Robinson-Torrens displacements per atom (NRT-dpa) model for metals.
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Materials research for fusion

TL;DR: Fusion materials research started in the early 1970s following the observation of the degradation of irradiated materials used in the first commercial fission reactors as mentioned in this paper, and has been the subject of decades of worldwide research efforts underpinning the present maturity of the fusion materials research program.
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Radiation damage in nanostructured materials

TL;DR: In this paper, the authors summarized and analyzed the current understandings on the influence of various types of internal defect sinks on reduction of radiation damage in primarily nanostructured metallic materials, and partially on nanoceramic materials.
References
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Journal ArticleDOI

Efficiency and availability driven R&D issues for DEMO

TL;DR: In this paper, an approach based on the analysis of overall plant functional requirements sheds new light on R&D needs, focusing on efficiency and availability, which is an absolute requirement to ensure that the ambitious goals of this device will be ultimately met.
Journal ArticleDOI

Micro-mechanical measurements of fracture toughness of bismuth embrittled copper grain boundaries

TL;DR: In this article, a method for fracture testing using micro-cantilevers, manufactured using focussed ion beam machining and tested using a nanoindenter, was described, and used to measure the fracture toughness of selected grain boundaries in bismuth-embrittled copper.
Journal ArticleDOI

Vacuum plasma-sprayed tungsten on EUROFER and 316L: Results of characterisation and thermal loading tests

TL;DR: In this paper, mixed tungsten/steel interlayers were applied to reduce the residual and thermal stresses at the substrate-coating interface and to improve the adhesion of the coating.
Journal ArticleDOI

Re-emission and thermal desorption of deuterium from plasma sprayed tungsten coatings for application in ASDEX-upgrade

TL;DR: In this article, the deuterium trapped in wrought tungsten was compared with model calculations with the PIDAT code in order to estimate the parameters governing diffusion, surface recombination and trapping in Tungsten.
Journal ArticleDOI

Self passivating W-based alloys as plasma-facing material

TL;DR: In this paper, binary and ternary tungsten alloys were synthesized by magnetron sputtering and the oxidation behavior was measured with a thermobalance set-up under synthetic air at temperatures up to 1273 K. Binary alloys of W-Si showed good self-passivation properties by forming a SiO 2 film at the surface.
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Frequently Asked Questions (23)
Q1. What contributions have the authors mentioned in the paper "Recent progress in research on tungsten materials for nuclear fusion applications in europe" ?

In this paper, the authors present a detailed review of the use and properties of tungsten materials for the first wall of a fusion tokamak. 

The main requirements of tungsten materials for structural divertor applications compriseproperties like high thermal conductivity, high temperature strength and stability, high recrystallization temperature, and enough ductility for an operation period of about two years under enormous neutron load. 

It was demonstrated that diffusion bonding at only 700 °C can be successfully performed with a minimal alteration of the microstructure of the base materials and strongly reduced formation of vanadium-carbide. 

The linear oxidation rate of tungsten at 1000 °C is about 1.410-2 mg cm-2 s-1 [43], which in the approximately 1000 m2 DEMO first wall would correspond to a release of half a ton of tungsten oxides per hour. 

Powder injection moulding (PIM) was investigated as a mass fabrication option for the tungstenarmour tiles which had to be joined to the thimbles. 

After the implantation has stopped (region III), the D retention drops and a remnant D flux to the W surface takes place for about 10 min. 

The use of tungsten as first wall (FW) armour of a fusion power reactor represents an importantsafety concern in the event of a loss of coolant accident with simultaneous air ingress into the reactor vessel. 

But even neglecting the irradiation effects (due to the large gaps in the knowledge of properties of these materials), there are still unsolved problems related to the use and properties of tungsten materials. 

Due to the fabrication route, missing mechanical working and/or an increased impurity level could also be an additional explanation for this severe brittleness. 

In helium cooled divertor designs tungsten materials are also considered for structural use (e.g. as pressurized pipes or thimbles). 

The formation of intermetallic compounds in tungsten alloys is just one of the factors responsible for their increased hardening, the other being the conventional solute hardening that gives rise to the embrittlement of the alloys that occurs even in the limit where the concentration of the alloying elements is small. 

It shows that the vacancy formation energy in W-Ta alloys depends sensitively on the lattice site at which a vacancy is formed, whereas in W-V alloys it is almost independent of the location of the vacancy site. 

In the first case, pure metallic powders were mechanically mixed, compacted, and molten to allow for brazing filler materials with homogeneous compositions. 

In a recent development, precursor powders are fabricated under certain solution conditions where the particle growth could be controlled to produce uniformly yttrium doped nano-sized tungsten oxides. 

In W, the production of impurities, such as Re, Ta, and Os, is fairly significant, being of the order of a few thousand to tens of thousands of atomic parts per million (appm) over a typical DEMO-like first-wall 5-year neutron exposure. 

Preliminary results of mechanical characterization of these W-W joints using Ti-Fe fillers gave rise to an average shear strength of 140 ± 8 MPa. 

So far, only rhenium is known to improve the ductility of tungsten by solid solution but its usefor fusion energy applications has been ruled out for various reasons (cost, irradiation embrittlement). 

The oxidation behaviour of the WCr12Ti2.5 alloy is similar to that of the WCr10Si10 material; in this case the oxidation rate is similar to that of thin films of same composition at 600 °C but higher at 800 and 1000 °C [48]. 

Only grain growing and physical sputtering were identified as the surface modification processes of the pure hydrogen loaded materials (Fig. 17). 

The results show the possibility of designing alloys where vacancies form within a desired range of temperature, suggesting the possibility of developing alloys with improved stability under irradiation. 

the fracture resistance may increase with crack propagation, which implies that it is not always possible to characterize the material‘s toughness with one single value such as plane strain fracture toughness KIC or critical energy release rate GIC. 

In what follows, the results, conclusions, and outlooks are summarized for each of theW&WALLOYS programme‘s main subtopics, which are (1) fabrication, (2) structural W materials, (3) W armour materials, and (4) materials science and modelling. 

Further investigations into the effect of grain boundary crystallography and chemistry are currently on-going, but it appears that tantalum has no beneficial effects, and may even have detrimental effects, on the fracture properties of tungsten.