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Journal ArticleDOI

Rechargeable lithium batteries

John Owen
- 01 Jan 1997 - 
- Vol. 26, Iss: 4, pp 259-267
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TLDR
The market for lithium batteries is undergoing a rapid expansion as new applications demand higher densities of energy and power storage as mentioned in this paper, which can reach specific energies of 880 and 500 W h kg−1 respectively.
Abstract
The market for lithium batteries is undergoing a rapid expansion as new applications demand higher densities of energy and power storage. Simple theoretical estimates show that lithium and lithium ion cells can reach specific energies of 880 and 500 W h kg–1 respectively. With an electrolyte conductivity above 3 × 10–4 S cm–1 and thickness below 0.01 cm, a power density of 300 W dm–3 can be obtained without excessive energy losses. Diffusion in porous or polymer composite electrodes is enhanced by an interpenetrating electrolyte provided the electrode particles are small. Batteries using transition metal oxide positive electrodes and carbon negative electrodes are expected to give practical specific energies up to 180 W. h kg–1 including packaging and other essential additional materials in the near future.

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A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries

TL;DR: In this paper, the authors report the feasibility to approach such capacities by creating highly ordered interwoven composites, where conductive mesoporous carbon framework precisely constrains sulphur nanofiller growth within its channels and generates essential electrical contact to the insulating sulphur.
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Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts

TL;DR: The battery electrochemistry and catalytic mechanism of oxygen reduction reactions are discussed on the basis of aqueous and organic electrolytes, and the design and optimization of air-electrode structure are outlined.
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Electrochemically Active Polymers for Rechargeable Batteries.

TL;DR: The goal of the present article is to provide a survey of electroactive polymers in view of potential applications in rechargeable batteries, and reviews the preparative methods and the electrochemical performance of polymers as rechargeable battery electrodes.
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Review of gel-type polymer electrolytes for lithium-ion batteries

TL;DR: In this paper, the advantages and characteristics of employing polymer electrolytes in solid-state lithium-ion batteries are discussed, and some critical concepts and points associated with this emerging technology that still require attention are discussed.
Journal ArticleDOI

Recent advances in rechargeable battery materials: a chemist’s perspective

TL;DR: In this tutorial review, the most recent and significant scientific advances in the field of rechargeable batteries, whose performance is dependent on their underlying chemistry, are covered and special emphasis is given to progress in lithium-based technologies.
References
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Journal ArticleDOI

LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density

TL;DR: In this paper, a new system LixCoO2 (0 Li x CoO 2 Li ) is proposed, which shows low overvoltages and good reversibility for current densities up to 4 mA cm−2 over a large range of x.
Journal ArticleDOI

The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model

TL;DR: In this article, it is suggested that in practical nonaqueous battery systems the alkali and alkaline earth metals are always covered by a surface layer which is instantly formed by the reaction of the metal with the electrolyte.
Journal ArticleDOI

Lithium insertion into manganese spinels

TL;DR: In this article, Li has been inserted chemically and electrochemically into Mn3O4 and Li[Mn2]O4 at room temperature from X-ray diffraction.
Journal ArticleDOI

Polyphosphazene solid electrolytes

TL;DR: In this article, the phosphazene polymer (NP(OC2H40C2H4OCH3)n, MEEP, was synthesized and amorphous solvent-free salt complexes were performed with LiSo3CF3, NaSO3 CF3, Sr(SO 3CF3)2, and AgSO3cf3.25.
Journal ArticleDOI

Correlation between surface chemistry, morphology, cycling efficiency and interfacial properties of Li electrodes in solutions containing different Li salts

TL;DR: In this article, the influence of the Li salt used on the behaviour of Li electrodes in tetrahydrofurane (THF) and propylene carbonate (PC) solutions was investigated.
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