Journal ArticleDOI
Remarkable Effect of Ethylene Gas in the Intramolecular Enyne Metathesis of Terminal Alkynes.
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This article is published in Journal of Organic Chemistry.The article was published on 1998-08-14. It has received 243 citations till now. The article focuses on the topics: Enyne metathesis & Intramolecular force.read more
Citations
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Journal ArticleDOI
Olefin Metathesis and Beyond
TL;DR: In this paper, the authors provide an overview of the development of catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups.
Journal ArticleDOI
Synthesis of oxygen- and nitrogen-containing heterocycles by ring-closing metathesis.
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Metathesis Reactions in Total Synthesis
Kyriacos C. Nicolaou,Kyriacos C. Nicolaou,Paul G. Bulger,Paul G. Bulger,David Sarlah,David Sarlah +5 more
TL;DR: Examples of total syntheses in which metathesis reactions of olefins, enynes, and alkynes played a crucial role and which imparted to these endeavors certain elements of novelty, elegance, and efficiency are highlighted.
Journal ArticleDOI
Synthesis of phosphorus and sulfur heterocycles via ring-closing olefin metathesis
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Macrocyclization by Ring‐Closing Metathesis in the Total Synthesis of Natural Products: Reaction Conditions and Limitations
TL;DR: The efforts of many research groups to develop efficient RCM reactions on their way towards the total synthesis of natural macrocyclic products are summarized in this Minireview.
References
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Journal ArticleDOI
Synthesis and Applications of RuCl2(CHR‘)(PR3)2: The Influence of the Alkylidene Moiety on Metathesis Activity
TL;DR: In this paper, the reactions of RuCl2(PPh3)3 with a number of diazoalkanes were surveyed, and alkylidene transfer was observed for RCHN2 and various para-substituted aryl diazalkanes p-C6H4X CHN2.
Journal ArticleDOI
A Series of Well‐Defined Metathesis Catalysts–Synthesis of [RuCl2(CHR′)(PR3)2] and Its Reactions
Journal ArticleDOI
Synthesis of molybdenum imido alkylidene complexes and some reactions involving acyclic olefins
Richard R. Schrock,John S. Murdzek,Guillermo C. Bazan,Jennifer Robbins,Marcello DiMare,Marie B. O'Regan +5 more
TL;DR: In this paper, a precursor to imido alkylidene complexes that is related to 2 has been prepared by the sequence MoO{sub 2} {yields} MoO(NAr)Cl{sub 3} (dme = 1,2-dimethoxyethane) and Me{ sub 3}SiNHAr (Ar = 2,6-diisopropylphenyl) yields Mo(C-t-Bu)(NHAr), which upon treatment with a catalytic amount of NEt-sub 3] is transformed into
Journal ArticleDOI
Ring-Closing Metathesis and Related Processes in Organic Synthesis
TL;DR: The transition metal alkylidene-catalyzed olefin metathesis reaction and the related transition metal-mediated carbonyl olefination reaction are two such processes as discussed by the authors.
Journal ArticleDOI
Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media
TL;DR: In this paper, an Ru(II) complex with a strained olefin was used to produce a carbene species that polymerizes norbornene in organic media both in the absence and presence of protic/aqueous solvents.
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