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ReviewNitroxide-mediated polymerization

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TLDR
In this article, a comprehensive review of NMP is presented, from its discovery to 2012, covering all aspects, features and achievements of the NMP, from synthetic approaches to nitroxides and alkoxyamines, kinetic aspects and polymerization features.
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This article is published in Progress in Polymer Science.The article was published on 2013-01-01. It has received 1002 citations till now. The article focuses on the topics: Polymerization & Radical polymerization.

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Triazine-mediated controlled radical polymerization: new unimolecular initiators

TL;DR: Triazine-based unimolecular initiators have been shown to mediate the controlled radical polymerization of several monomer classes, yielding polymers with low dispersities, targeted molecular weights, and active chain ends as mentioned in this paper.
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Facile iron-mediated dispersant-free suspension polymerization of methyl methacrylate via reverse ATRP in water.

TL;DR: Polymerization results demonstrated typical "living"/controlled characteristics of ATRP: first-order polymerization kinetics, linear increase of molecular weights with monomer conversion and narrow molecular weight distributions for the resultant PMMA particles.
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Opportunities for dual RDRP agents in synthesizing novel polymeric materials

TL;DR: The present review highlights the state of the art of dual systems, with a particular emphasis on orthogonality considerations and the potential of dual agents for accessing new polymeric materials.
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Old meets new: Combination of PLA and RDRP to obtain sophisticated macromolecular architectures

TL;DR: In this article, the synthesis of polylactide (PLA) based copolymers by combination of reversible-deactivation radical polymerization (RDRP) techniques with ring-opening polymerisation (ROP) processes is discussed.
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