Journal ArticleDOI
ReviewNitroxide-mediated polymerization
Julien Nicolas,Yohann Guillaneuf,Catherine Lefay,Denis Bertin,Didier Gigmes,Bernadette Charleux +5 more
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TLDR
In this article, a comprehensive review of NMP is presented, from its discovery to 2012, covering all aspects, features and achievements of the NMP, from synthetic approaches to nitroxides and alkoxyamines, kinetic aspects and polymerization features.About:
This article is published in Progress in Polymer Science.The article was published on 2013-01-01. It has received 1002 citations till now. The article focuses on the topics: Polymerization & Radical polymerization.read more
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Journal ArticleDOI
Living Initiator-Transfer Anionic Polymerization of Isocyanates by Sodium Diphenylamide
Chang-Geun Chae,In-Gyu Bak,Yves Lansac,Yves Lansac,Shashadhar Samal,Yun Hee Jang,Jae-Suk Lee +6 more
TL;DR: In this paper, a dimerically self-associated sodium diphenylamide (NaDPA) was introduced as a robust chain-end-protective initiator in the anionic polymerization of n-hexyl isocyanate in the absence or presence of sodium tetraphenylborate (NaBPh4) additive.
Book ChapterDOI
Synthetic applications of click chemistry in thermosetting block and graft polymers
TL;DR: In this paper , the authors have given more emphasis on click chemistry that has been used for the creation of specific molecular architectures, impossible or difficult to realize through classical anionic or controlled radical polymerization methods.
Journal ArticleDOI
Investigations into CTA-differentiation-involving polymerization of fluorous monomers: exploitation of experimental variances in fine-tuning of molecular weights
TL;DR: In this paper, the impact of different conditions and substrates on the reaction outputs of UHMW fluoropolymers was investigated, aiming at achieving logical control of the differentiation process and accurate regulation of the molecular weight.
Journal ArticleDOI
Tailoring the Gibbs Free Energy of the Nitroxide Exchange Reaction: Substituent and Solvent Effects.
David Sulzer,Angela Bihlmeier +1 more
TL;DR: In this article, the influence of substituents and solvents on the Gibbs free energy of the nitroxide exchange reaction was studied and a quantum chemical study of the reaction was presented.
Journal ArticleDOI
pH-Dependent Structure of Block Copolymer Micelles Featuring a Polyampholyte Corona: A Combined Experimental and Theoretical Approach
Jonas Eichhorn,Yulia D. Gordievskaya,Yulia D. Gordievskaya,Yulia D. Gordievskaya,Elena Yu. Kramarenko,Elena Yu. Kramarenko,Alexei R. Khokhlov,Alexei R. Khokhlov,Alexei R. Khokhlov,Felix H. Schacher +9 more
TL;DR: This work describes the preparation as well as experimental and theoretical investigations of blockCopolymer micelles based on amphiphilic, pH-responsive block copolymers featuring bipyridine liga...