Journal ArticleDOI
ReviewNitroxide-mediated polymerization
Julien Nicolas,Yohann Guillaneuf,Catherine Lefay,Denis Bertin,Didier Gigmes,Bernadette Charleux +5 more
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TLDR
In this article, a comprehensive review of NMP is presented, from its discovery to 2012, covering all aspects, features and achievements of the NMP, from synthetic approaches to nitroxides and alkoxyamines, kinetic aspects and polymerization features.About:
This article is published in Progress in Polymer Science.The article was published on 2013-01-01. It has received 1002 citations till now. The article focuses on the topics: Polymerization & Radical polymerization.read more
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Versatile cobalt complexes for initiating immortal ring-opening polymerization (ROP) of lactide (LA), mediating living radical polymerization of t-butyl acrylate (tBA) and catalyzing copolymerization of LA and tBA by combination of ROP and organometallic-mediated radical polymerization
TL;DR: In this article, a low-cost, highly active and versatile amino-bis(phenolate) cobalt complexes were developed for copolymerization of lactide and acrylate.
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A sterically hindered cobalt o-iminobenzosemiquinone complex in the polymerization of vinyl monomers
TL;DR: In this article, the influence of cobalt II on the radical polymerization of methyl methacrylate and styrene under the conditions of radical initiation by azo-bis-isobutyric acid dinitrile in the temperature range 70-90°C has been studied.
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Anisotropic and Self-Healing Copolymer with Multiresponsive Capability via Recyclable Alloy-Mediated RDRP
TL;DR: In this article, a triple stimuli sensitive block copolymer is prepared by magnetically separable and reusable (up to multiple cycles) Ni-Co alloy nanoparticles mediated reversible deactivation radical polymerization (RDRP) at 25°C.
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Controlling Molecular Aggregation-Induced Emission by Controlled Polymerization.
TL;DR: In this paper, the main polymerization techniques involved in these polymers are summarized and the key parameters that affect their photophysical properties are analyzed, and a set of general guidelines for AIE polymer design, along with personal perspectives on the direction of future research are provided.
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Oxygen-demanding Photocontrolled RAFT Polymerization under Ambient Conditions.
TL;DR: In this article , a photocontrolled reversible addition-fragmentation chain transfer (RAFT) process is developed by initiating polymerization through a 1,3-diaminopropane-triethylborane (DAPTB)-diphenyl iodonium salt (Ph2 I+ ) complex under ambient temperature and atmosphere.