Journal ArticleDOI
Controlled/living radical polymerization: Features, developments, and perspectives
TLDR
In this article, a review of recent mechanistic developments in the field of controlled/living radical polymerization (CRP) is presented, with particular emphasis on structure-reactivity correlations and "rules" for catalyst selection in ATRP, for chain transfer agent selection in reversible addition-fragmentation chain transfer (RAFT) polymerization, and for the selection of an appropriate mediating agent in stable free radical polymerisation (SFRP), including organic and transition metal persistent radicals.About:
This article is published in Progress in Polymer Science.The article was published on 2007-01-01. It has received 2869 citations till now. The article focuses on the topics: Living free-radical polymerization & Reversible addition−fragmentation chain-transfer polymerization.read more
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Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives
TL;DR: The current status and future perspectives in atom transfer radical polymerization (ATRP) are presented in this paper, with a special emphasis on mechanistic understanding of ATRP, recent synthetic and process development, and new controlled polymer architectures enabled by ATRP.
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Progress in the production and modification of PVDF membranes
TL;DR: A comprehensive overview of recent progress on the production and modification of polyvinylidene fluoride (PVDF) membranes for liquid-liquid or liquid-solid separation can be found in this article.
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Polymer Brushes via Surface-Initiated Controlled Radical Polymerization: Synthesis, Characterization, Properties, and Applications
Raphael Barbey,Laurent Lavanant,Dusko Paripovic,Nicolas Schüwer,Caroline Sugnaux,Stefano Tugulu,Harm-Anton Klok +6 more
TL;DR: This data indicates that self-Assembled Monolayers and Walled Carbon Nanotubes with high adhesion to Nitroxide-Mediated Polymerization have potential in the well-Defined Polymer Age.
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Design and Preparation of Porous Polymers
TL;DR: This work presents a new mesoporous composite material suitable for high-performance liquid chromatography and shows good chiral recognition ability and high uniformity in various racemates.
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The development of microgels/nanogels for drug delivery applications
TL;DR: This review describes the recent developments of microgel/nanogel particles as drug delivery carriers for biological and biomedical applications, including stability for prolonged circulation in the blood stream, novel functionality for further bioconjugation, and biodegradability for sustained release of drugs for a desired period of time.
References
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Journal ArticleDOI
Living free-radical polymerization by reversible addition - Fragmentation chain transfer: The RAFT process
John Chiefari,Y. K. Chong,Frances Ercole,Julia Krstina,Justine Leigh Jeffery,Tam P. T. Le,Roshan T. A. Mayadunne,Gordon Francis Meijs,Catherine Louise Moad,Graeme Moad,Ezio Rizzardo,San H. Thang +11 more
TL;DR: The authors proposed a reversible additive-fragmentation chain transfer (RAFT) method for living free-radical polymerization, which can be used with a wide range of monomers and reaction conditions and in each case it provides controlled molecular weight polymers with very narrow polydispersities.
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Controlled/"living" radical polymerization. atom transfer radical polymerization in the presence of transition-metal complexes
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