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ReviewNitroxide-mediated polymerization

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TLDR
In this article, a comprehensive review of NMP is presented, from its discovery to 2012, covering all aspects, features and achievements of the NMP, from synthetic approaches to nitroxides and alkoxyamines, kinetic aspects and polymerization features.
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This article is published in Progress in Polymer Science.The article was published on 2013-01-01. It has received 1002 citations till now. The article focuses on the topics: Polymerization & Radical polymerization.

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Journal ArticleDOI

Utilization of Poor RAFT Control in Heterogeneous RAFT Polymerization

TL;DR: In this article, the authors developed heterogeneous reversible addition-fragmentation chain transfer (RAFT) polymerization from an unusual angle by deliberately using RAFT agents with poor controllability.
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Sulfonium salt based charge transfer complexes as dual thermal and photochemical polymerization initiators for composites and 3D printing

TL;DR: In this paper, a new dual initiators based on a phenacyl sulfonium salt (ITXPhenS) acceptor and selected donors capable of initiating both thermal and photochemical polymerizations are investigated.
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Poly(thioacrylate)s: expanding the monomer toolbox of functional polymers

TL;DR: In this paper, a simple synthetic approach was presented to prepare various thioacrylate monomers as well as their controlled radical polymerization for the first time, and the obtained polymers were analyzed in detail using GPC, NMR, TGA, DSC and water contact angle.
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PEG Molecular Net-Cloth Grafted on Polymeric Substrates and Its Bio-Merits

TL;DR: This paper reports a non-swelling “PEG molecular net-cloth” on a solid surface, fabricated using a novel “visible light induced surface controlled graft cross-linking polymerization” (VSCGCP) technique, applicable to any C-H containing surface, and can be easily tailored for a broad range of applications.
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Photo-Enhanced Antimicrobial Activity of Polymers Containing an Embedded Photosensitiser

TL;DR: In this article, a photo-sensitive acrylate monomer was used as a self-catalyst in the photoinduced electron/energy transfer-reversible addition fragmentation chain transfer (PET-RAFT) polymerization process and a photosensitiser (PS) for antibacterial applications.
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