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Scales of solute hydrogen-bonding: their construction and application to physicochemical and biochemical processes
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This article is published in Chemical Society Reviews.The article was published on 1993-01-01. It has received 1896 citations till now. The article focuses on the topics: Solvation & High-performance liquid chromatography.read more
Citations
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The solubility of gases and vapours in ethanol - the connection between gaseous solubility and water-solvent partition
TL;DR: Ostwald solubility coefficients, as log L, for solutes in water and ethanol have been combined to give log PEtOH for partition between the two pure solvents.
Journal ArticleDOI
High temperature and highly selective stationary phases of ionic liquid bonded polysiloxanes for gas chromatography.
TL;DR: This work synthesized a novel ionic liquid (IL) bonded polysiloxane with anion of bis-trifluoromethanesulfonylimide with good selectivity for fatty acid methyl esters, polychlorinated biphenyls (PCBs) and aromatic amines, and evaluated the selectivity of the novel stationary phases for analytes.
Journal ArticleDOI
Physical Absorption Of CO2 in Protic and Aprotic Ionic Liquids: An Interaction Perspective
Ekaterina I. Izgorodina,Jennifer L. Hodgson,Derick C. Weis,Steven J. Pas,Douglas R. MacFarlane +4 more
TL;DR: The structure-reactivity relationships determined in this study may help in the optimization of the physical absorption process by means of ionic liquids, with dispersion forces playing an important role in CO2 solubility.
Journal ArticleDOI
Enthalpy of Solvation Correlations for Gaseous Solutes Dissolved in Benzene and in Alkane Solvents Based on the Abraham Model
TL;DR: In this article, an Abraham solvation equation with five descriptors was used to correlate the experimental solvation enthalpies to within standard deviations of 1.85, 1.84, and 2.08.
Journal ArticleDOI
Adsorption of volatile organic vapors by activated carbon derived from rice husk under various humidity conditions and its statistical evaluation by linear solvation energy relationships
TL;DR: In this paper, the adsorption of sixteen volatile organic compounds (VOCs) in the gas phase by activated carbon (AC) generated from waste rice husk was investigated under two different levels of relative humidity (RH) by inverse gas chromatography (IGC).
References
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Journal ArticleDOI
The use of characteristic volumes to measure cavity terms in reversed phase liquid chromatography
Michael H. Abraham,J. C. McGowan +1 more
TL;DR: In this paper, it was shown that the use of the McGowans characteristic volume, Vx, is equivalent to using Leahy's computer-calculated intrinsic volumes, V1, for the cavity term mV/100, for 209 gaseous, liquid, and solid solutes.
Journal ArticleDOI
Do general anaesthetics act by competitive binding to specific receptors
Nicholas P. Franks,W. R. Lieb +1 more
TL;DR: It is shown that, over a 100,000-fold range of potencies, the activity of a pure soluble protein can be inhibited by 50% at anaesthetic concentrations which are essentially identical to those which anaesthetize animals.
Journal ArticleDOI
Hydrogen bonding: XVI. A new solute salvation parameter, π2H, from gas chromatographic data
TL;DR: In this article, the general salvation equation, log VG0 (or log L) was used to set up a new π2H parameter of solute dipolarity-polarisability, mainly through the extensive data of McReynolds and Patte et al.
Related Papers (5)
Determination of sets of solute descriptors from chromatographic measurements
The use of characteristic volumes to measure cavity terms in reversed phase liquid chromatography
Michael H. Abraham,J. C. McGowan +1 more