Journal ArticleDOI
Scales of solute hydrogen-bonding: their construction and application to physicochemical and biochemical processes
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This article is published in Chemical Society Reviews.The article was published on 1993-01-01. It has received 1896 citations till now. The article focuses on the topics: Solvation & High-performance liquid chromatography.read more
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Solubility of gases and vapours in propan-1-ol at 298 K
TL;DR: In this article, the Ostwald solubility coefficient of gases and vapours in propan-1-ol at 298 K was combined with additional values calculated from solubilities of propan 1-ol and vapour pressures to yield a total of 79 log LPrOH values at 298
Journal ArticleDOI
Correlation and prediction of solute transfer to chloroalkanes from both water and the gas phase
Laura M. Sprunger,Sai S. Achi,William E. Acree,Michael H. Abraham,Albert J. Leo,David Hoekman +5 more
TL;DR: In this article, the authors derived correlations with the Abraham solvation parameter model for chloroform and carbon tetrachloride, and validated the derived correlations using training set and test set analyses.
Journal ArticleDOI
Retention characteristics of porous graphitic carbon in reversed-phase liquid chromatography with methanol-water mobile phases.
TL;DR: The solvation parameter model poorly predicts the retention properties of angular molecules, probably due to the failure of the characteristic volume to correctly model the contact surface area for the interaction ofangular molecules with the planar graphite surface.
Journal ArticleDOI
Air to brain, blood to brain and plasma to brain distribution of volatile organic compounds: linear free energy analyses.
TL;DR: Partition coefficients, K(brain), for volatile organic compounds, VOCs, from air to brain have been collected for 81 compounds (air to human brain and air to rat brain), and values for partition between (blood or plasma) to brain, P(bp-brain), were available for 99 V OCs.
Journal ArticleDOI
Interactions of Hydroxy Compounds and Sugars with Anions1
TL;DR: In this paper, NMR titrations with up to four different OH signals as well as with some CH signals allow accurate and consistent calculation of equilibrium constants K and complexation induced shifts (CIS), and observed CIS and K values agree with the formation of 3 different 1:1 complexes of similar stability for the phosphate receptor, with binding one anion between the 2-, 3-, 4-, and 6-OH groups of the glucoside,...
References
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The use of characteristic volumes to measure cavity terms in reversed phase liquid chromatography
Michael H. Abraham,J. C. McGowan +1 more
TL;DR: In this paper, it was shown that the use of the McGowans characteristic volume, Vx, is equivalent to using Leahy's computer-calculated intrinsic volumes, V1, for the cavity term mV/100, for 209 gaseous, liquid, and solid solutes.
Journal ArticleDOI
Do general anaesthetics act by competitive binding to specific receptors
Nicholas P. Franks,W. R. Lieb +1 more
TL;DR: It is shown that, over a 100,000-fold range of potencies, the activity of a pure soluble protein can be inhibited by 50% at anaesthetic concentrations which are essentially identical to those which anaesthetize animals.
Journal ArticleDOI
Hydrogen bonding: XVI. A new solute salvation parameter, π2H, from gas chromatographic data
TL;DR: In this article, the general salvation equation, log VG0 (or log L) was used to set up a new π2H parameter of solute dipolarity-polarisability, mainly through the extensive data of McReynolds and Patte et al.
Related Papers (5)
Determination of sets of solute descriptors from chromatographic measurements
The use of characteristic volumes to measure cavity terms in reversed phase liquid chromatography
Michael H. Abraham,J. C. McGowan +1 more