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Shape-Controllable Synthesis and Morphology-Dependent Luminescence Properties of GaOOH:Dy3+ and β-Ga2O3:Dy3+

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TLDR
The beta-Ga(2)O(3):Dy(3+) phosphor with a submicroellipsoid shape shows the highest relative emission intensity and quantum yield compared with other morphologies, and the obtained phosphors have potential applications in the areas of fluorescent lamps and field emission displays (FEDs).
Abstract
Dy3+-doped gallium oxide hydroxides (GaOOH:Dy3+) with various morphologies (submicrospindles, submicroellipsoids, 3D hierarchical microspheres) were synthesized by a facile soft-chemical method. After annealing at 1000 °C, the GaOOH:Dy3+ precursor was easily converted to β-Ga2O3:Dy3+ phosphors which kept their original morphologies. The as-prepared GaOOH:Dy3+ and β-Ga2O3:Dy3+ products were characterized using X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), low- to high-resolution transmission electron microscopy (TEM), selected area electron diffraction (SAED), photoluminescence (PL) spectra, cathodoluminescence (CL) spectra, and quantum yield (QY). With an increase in pH from 4 to 9, the morphology of GaOOH:Dy3+ varied from submicrospindles to 3D hierarchical microspheres of self-assembled nanoparticles. A possible mechanism for the formation of various morphologies of GaOOH:Dy3+ and β-Ga2O3:Dy3+ was proposed. Under ultraviolet and low-voltage electron beam excitation, the p...

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Journal ArticleDOI

Recent progress in low-voltage cathodoluminescent materials: synthesis, improvement and emission properties

TL;DR: This review summaries the recent progress in the chemical synthesis and improvement of novel, rare-earth and transition metal ions activated inorganic cathodoluminescent materials in powder and thin film forms and discusses the research prospects and future directions of FED phosphors.
Journal ArticleDOI

Eu3+/Tb3+-doped La2O2CO3/La2O3 nano/microcrystals with multiform morphologies: facile synthesis, growth mechanism, and luminescence properties.

TL;DR: A series of controlled experiments indicate that the pH values in the initial reaction systems, carbon sources, and simple ions were responsible for the shape determination of the LaCO(3)OH products.
Journal ArticleDOI

Luminescence and Energy Transfer Properties of Ca2Ba3(PO4)3Cl and Ca2Ba3(PO4)3Cl:A (A = Eu2+/Ce3+/Dy3+/Tb3+) under UV and Low-Voltage Electron Beam Excitation

TL;DR: Under the low voltage electron beam excitation, Tb(3+) ion doped Ca2Ba3(PO4)3Cl samples present different luminescence properties compared with their PL spectra, which is ascribed to the different excitation mechanism.
Journal ArticleDOI

Luminescence and energy transfer of Eu3+ or/and Dy3+ co-doped in Sr3AlO4F phosphors with NUV excitation for WLEDs

TL;DR: In this paper, a single doped and codoped Sr3AlO4F phosphors were prepared in a reducing atmosphere by the conventional solid-state reaction method, and the XRD was used to confirm the crystal structure of the phosphors and their photoluminescence (PL) properties were studied by the excitation and emission spectra.
Journal ArticleDOI

Controllable synthesis and tunable luminescence properties of Y2(WO4)3:Ln3+ (Ln = Eu, Yb/Er, Yb/Tm and Yb/Ho) 3D hierarchical architectures

TL;DR: The results reveal that the morphology and dimensions of the as-prepared precursors can be effectively tuned by altering the amounts of organic SDBS and the reaction time, and the possible formation mechanism was also proposed.
References
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Journal ArticleDOI

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