Journal ArticleDOI
Simultaneous Presence of Open Metal Sites and Amine Groups on a 3D Dy(III)-Metal-Organic Framework Catalyst for Mild and Solvent-Free Conversion of CO2 to Cyclic Carbonates.
Reza Abazari,Soheila Sanati,Ali Morsali,Alexander M. Kirillov,Alexander M. Kirillov,Alexandra M. Z. Slawin,Cameron L. Carpenter-Warren +6 more
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TLDR
In this article, a 3D metal-organic framework with micropores and free NH2 groups was proposed to promote the chemical fixation of CO2 to cyclic carbonates.Abstract:
Carbon dioxide (CO2) fixation to generate chemicals and fuels is of high current importance, especially toward finding mild and efficient strategies for catalytic CO2 transformation to value added products. Herein, we report a novel Lewis acid-base bifunctional amine-functionalized dysprosium(III) metal-organic framework [Dy3(data)3·2DMF]·DMF (2,5-data: 2,5-diamino-terephthalate), NH2-TMU-73. This compound was fully characterized and its crystal structure reveals a 3D metal-organic framework (MOF) with micropores and free NH2 groups capable of promoting the chemical fixation of CO2 to cyclic carbonates. NH2-TMU-73 is built from the Dy(III) centers and data2- blocks, which are arranged into an intricate underlying net with a rare type of xah topology. After activation, NH2-TMU-73 and its terephthalate-based analogue (TMU-73) were applied for CO2-to-epoxide coupling reactions to produce cyclic carbonates. Important features of this catalytic process concern high efficiency and activity in the absence of cocatalyst, use of solvent-free medium, atmospheric CO2 pressure, and ambient temperature conditions. Also, NH2-TMU-73 features high structural stability and can be recycled and reused in subsequent catalytic tests. An important role of free amino groups and open metal sites in the MOF catalyst was highlighted when suggesting a possible reaction mechanism.read more
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Bimetallic metal–organic frameworks and MOF-derived composites: Recent progress on electro- and photoelectrocatalytic applications
TL;DR: In this paper , a review of the state-of-the-art on bimetallic MOFs and derived composites for the main current types of electro- and photoelectrocatalytic applications is presented.
Journal ArticleDOI
Bimetallic metal–organic frameworks and MOF-derived composites: Recent progress on electro- and photoelectrocatalytic applications
Ekta Rani,Yingtang Zhou,Reza Abazari,Vishnu Sivarudran Pillai,Jing Chen,Loreto Cartagena Caffarena,Muhammad Tahir,Muhammad Tahir,Anuj Kumar,Riyadh Ramadhan Ikreedeegh,Ekta Rani,Harishchandra Singh,Alexander M. Kirillov,Alexander M. Kirillov +13 more
TL;DR: In this article, a review of the state-of-the-art on bimetallic MOFs and derived composites for the main current types of electro- and photo-electrocatalytic applications is presented.
Journal ArticleDOI
Third-Order Nonlinear Optical Behavior of an Amide-Tricarboxylate Zinc(II) Metal-Organic Framework with Two-Fold 3D+3D Interpenetration.
Reza Abazari,Reza Abazari,Elnaz Yazdani,Marzieh Nadafan,Alexander M. Kirillov,Alexander M. Kirillov,Junkuo Gao,Alexandra M. Z. Slawin,Cameron L. Carpenter-Warren +8 more
TL;DR: In this article, a new metal-organic framework (MOF), [Zn4(μ4-O)(μ6-L)2(H2O)2]n·nDMF (ZSTU-10), was assembled from zinc(II) nitrate and N,N',N''-bis(4-carboxylate)trimesicamide linkers and fully characterized.
Journal ArticleDOI
Trimetallic metal–organic frameworks and derived materials for environmental remediation and electrochemical energy storage and conversion
Xinzhi Luo,Reza Abazari,Muhammad Tahir,Weidong Fan,Anuj Kumar,Tina Kalhorizadeh,Alexander M. Kirillov,Ali Reza Amani-Ghadim,Jing M. Chen,Yingtang Zhou +9 more
TL;DR: In this paper , the authors extended prior reviews on mono-and bimetallic MOF-based systems with a main goal of creating a roadmap for the introduction of heterotrimetallic MOFs as more advanced materials for electrochemical energy storage and conversion.
Journal ArticleDOI
First-row transition metal-based materials derived from bimetallic metal-organic frameworks as highly efficient electrocatalysts for electrochemical water splitting
TL;DR: In this article , the development of highly efficiency electrocatalysts to produce hydrogen and oxygen from water electrolysis through electrochemical water splitting is a mature technology for hydrogen generation, and many studies have focused on the developing of highly efficient electrocatalyssts.
References
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