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Journal ArticleDOI

Structure determination of Ca2MnO4 and Ca2MnO3.5 by X-ray and neutron methods

TLDR
The X-ray and neutron structures of polycrystalline Ca 2 MnO 3.5 by Rietveld analysis have been determined as mentioned in this paper, and the relationship between the CaMnO 3 /CaMnNO 2.5 structures is discussed.
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This article is published in Journal of Solid State Chemistry.The article was published on 1982-11-01. It has received 317 citations till now. The article focuses on the topics: Lattice constant & Rietveld refinement.

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Neutron diffraction study of Pr1 − xCaxMnO3 perovskites

TL;DR: In this paper, a powder neutron diffraction study of Pr 1 − x Ca x - Mn 3+ 1− x Mn 4+ x O 3 (0 x 3+ ions and their orbitals) was revealed.
Journal ArticleDOI

Electronic and ionic transport properties and other physical aspects of perovskites

TL;DR: The perovskites and their related structures exhibit several features of technical as well as fundamental interest, such as oxide-ion conduction with/without electronic conduction, oxidation catalysis, ferroic displacements in classic and relaxor ferroelectrics, half-metallic ferromagnetism and high-temperature superconductivity.
Journal ArticleDOI

Evolution of Oxygen-Vacancy Ordered Crystal Structures in the Perovskite Series SrnFenO3n−1 (n=2, 4, 8, and ∞), and the Relationship to Electronic and Magnetic Properties

TL;DR: In this article, the authors used time-of-flight neutron powder diffraction to determine the correct crystal structures for Sr4Fe4O11 (orthorhombic, space group Cmmm, a=10.974(1) A, b=7.702(1), and c=5.473(1)-A) and Sr8Fe8O23 (tetragonal, I4/mmm) through comparison of the goodness of fit for Rietveld refinements of candidate models and bond-length distributions.
Journal ArticleDOI

Ca2Mn2O5 as Oxygen-Deficient Perovskite Electrocatalyst for Oxygen Evolution Reaction

TL;DR: It is demonstrated that oxygen-deficient perovskite, A2B2O5, is a new class of high performance electrocatalyst for those reactions that involve active oxygen intermediates, such as reduction of oxygen and OER in water splitting.
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Sodium Hydride as a Powerful Reducing Agent for Topotactic Oxide Deintercalation: Synthesis and Characterization of the Nickel(I) Oxide LaNiO2

TL;DR: In this paper, the capability of sodium hydride as a reducing agent in oxide deintercalation reactions is explored, and a similar infinite-layer phase is prepared by reduction of NdNiO3.
References
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Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides

TL;DR: The effective ionic radii of Shannon & Prewitt [Acta Cryst. (1969), B25, 925-945] are revised to include more unusual oxidation states and coordinations as mentioned in this paper.
Journal ArticleDOI

Simple ways of determining perovskite structures

TL;DR: In this article, a simple technique is described for ascertaining trial models for the structures of perovskites, which relies on an understanding of the fundamental components of the structure and rules are given for determining trial models rapidly.
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