Journal ArticleDOI
The chemical interpretation and practice of linear solvation energy relationships in chromatography
Mark F. Vitha,Peter W. Carr +1 more
TLDR
This review focuses on the use of linear solvation energy relationships (LSERs) to understand the types and relative strength of the chemical interactions that control retention and selectivity in the various modes of chromatography ranging from gas chromatography to reversed phase and micellar electrokinetic capillary chromatography.About:
This article is published in Journal of Chromatography A.The article was published on 2006-09-08. It has received 456 citations till now. The article focuses on the topics: Solvation & Solvophobic.read more
Citations
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Journal ArticleDOI
Chiral recognition by enantioselective liquid chromatography: Mechanisms and modern chiral stationary phases
TL;DR: This tutorial review is mainly focused on mechanisms of chiral recognition and enantiomer distinction of popular chiral selectors and corresponding chiral stationary phases and attempts to provide the reader with vivid images of molecular recognition mechanisms of selected chiral selector-selectand pairs on basis of solid-state X-ray crystal structures and simulated computer models.
Journal ArticleDOI
Extraction of organic compounds with room temperature ionic liquids.
Colin F. Poole,Salwa K. Poole +1 more
TL;DR: These studies indicate that the solution properties of ionic liquids are similar to those of polar organic solvents, which is of interest for applications in separation science.
Journal ArticleDOI
Performance of SM6, SM8, and SMD on the SAMPL1 test set for the prediction of small-molecule solvation free energies.
TL;DR: The SM6, SM8, and SMD quantum mechanical aqueous continuum solvation models are applied to predict free energies of aQueous solvation for 61 molecules in the SAMPL1 test set, and it is suggested that the uncertainty in the target solvation free energies for these molecules may be quite large.
Journal ArticleDOI
Fast, comprehensive two-dimensional liquid chromatography.
TL;DR: This report is deliberately focused on the issues involved in doing fast 2DLC by means of elevating the column temperature; however, many issues of broader applicability will be discussed.
Journal ArticleDOI
The many faces of packed column supercritical fluid chromatography--a critical review.
Eric Lesellier,Caroline West +1 more
TL;DR: This paper is a review of the main features of SFC, focusing essentially on achiral separations, but several fundamental aspects discussed here are also relevant to chiral SFC separations.
References
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Book
Molecular Thermodynamics of Fluid-Phase Equilibria
TL;DR: In this article, the authors introduce the notion of uniformity of intensive potentials as a criterion of phase equilibrium, and propose a model for solubilities of solids in liquid mixtures.
Book
Applied Linear Regression
TL;DR: In this paper, the authors present a method to estimate the least squares of a scatterplot matrix using a simple linear regression model, and compare it with the mean function of the scatterplot matrices.
Journal ArticleDOI
Linear solvation energy relationships. 23. A comprehensive collection of the solvatochromic parameters, .pi.*, .alpha., and .beta., and some methods for simplifying the generalized solvatochromic equation
TL;DR: In this article, a table of donnees (pour de nombreux solvants) des valeurs des parametres M*, α and β donnant respectivement la polarisabilite du solvant, son pouvoir de donneur de proton, and d'accepteur de protons dans les liaisons hydrogene solute-solvant
Book
Inorganic Chemistry: Principles of Structure and Reactivity
TL;DR: In this article, inorganic chemistry principles of structure and reactivity are presented. But, they do not cover how to use these principles in the design of products, and they are not available in any type of product.
Journal ArticleDOI
Free Volume and Entropy in Condensed Systems III. Entropy in Binary Liquid Mixtures; Partial Molal Entropy in Dilute Solutions; Structure and Thermodynamics in Aqueous Electrolytes
Henry S. Frank,Marjorie W. Evans +1 more
TL;DR: The first and second papers in this series, which make it possible to interpret entropy data in terms of a physical picture, are applied to binary solutions, and equations are derived relating energy and volume changes when a solution is formed to the entropy change for the process as discussed by the authors.
Related Papers (5)
Determination of sets of solute descriptors from chromatographic measurements
Column selectivity from the perspective of the solvation parameter model.
Colin F. Poole,Salwa K. Poole +1 more