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The chemistry of clay-organic reactions

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The article was published on 1974-01-01 and is currently open access. It has received 1180 citations till now. The article focuses on the topics: Organic reaction.

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Complex formation of cation-exchanged montmorillonites with propylene carbonate; osmotic swelling in aqueous electrolyte solutions

TL;DR: In this paper, it was shown that the C=0 stretching band of intercalated propylene carbonate (PC) molecules shifts to lower frequencies, and the amount of the shift increased with the increase of the polarizing power of the interlayer cations, which is interpreted in terms of the formation of thick electric double-layers consisting of PC and H2O between the 2:1 layers.
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Adsorption of l-lysine on montmorillonite

TL;DR: In this paper, the results of a study investigating the adsorption of l -lysine (0.025-0.4 m) onto montmorillonite were reported. And they found that lysine adaption is first dominated by cation exchange and then by adsorction of electrically neutral lysines (as a zwitterion), as indicated by chemical and FTIR evidence.
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Microstructural changes of reference montmorillonites by cationic surfactants

TL;DR: In this article, the characteristics of montmorillonites modified with the cationic surfactant hexadecyltrimethylammonium (HDTMA) were evaluated by investigating adsorption isotherms and microstructures.
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Effects of organic cation structure on behavior of organobentonites

TL;DR: In this paper, the effects of four quaternary ammonium cations (TMA, DTMA, HDTMA and BTEA) on the mechanical properties of a modified Wyoming bentonite were quantified.
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Effect of nanoclay addition on the fiber/matrix adhesion in epoxy/glass composites:

TL;DR: In this paper, various kinds of organo-modified clays were dispersed at different amounts in an epoxy matrix, and the viscosity of the epoxy resin resulted still acceptable for a possible usage a...
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