Journal ArticleDOI
The exciton mechanism: Studies in model compounds
TLDR
In this paper, the authors discussed the little model for a macromolecular high temperature superconductor in terms of its component parts, and showed that polymeric metallocenes, in which planar aromatic hydrocarbon rings and meatal atmos alternate, may be suitable.Abstract:
The “Little” model for a macromolecular high temperature superconductor can be discussed in terms of its component parts. Studies on molecules designed to serve as the polyene and the polyene spine indicate that polymeric metallocenes, in which planar aromatic hydrocarbon rings and meatal atmos alternate, may be suitable. Toward this end the hydrocarbon dicyclopentanaphthalene, and various substituted derivatives were synthesized, and the polymerization of the corresponding dianions with ferrous chloride were investigated.read more
Citations
More filters
Journal ArticleDOI
On the possibility of effective attraction between delocalized electrons in organic systems
TL;DR: In this paper, the attractive interaction between delocalized electrons arising from the polarization of both their σ and neighbouring π-systems is shown to overcompensate the Coulomb repulsion.
Book ChapterDOI
Multidecker Organometallic Sandwich Polymers; Prospective Conductive Backbones for the Formation of Macromolecular Architectures Conforming to the Excitonic Superconductor Topology Proposed by Little
Ben Bush,J. J. Lagowski +1 more
TL;DR: In this article, a multilayer structure of perovskites has been described as a factor in enhancing an excitonic interaction between conductive planes mediated through an intervening Cu-O chain.
References
More filters
Journal ArticleDOI
A New Type of Organo-Iron Compound
T. J. Kealy,P. L. Pauson +1 more
TL;DR: In this article, the reaction of Grignard reagents with anhydrous ferric chloride was studied, but no definite evidence for organo-iron compounds was found in such reactions.
Journal ArticleDOI
Possibility of synthesizing an organic superconductor
TL;DR: In this article, London's idea that superconductivity might occur in organic macromolecules is examined in the light of the BCS theory of superconductivities and it is shown that the criterion for the occurrance of such a state can be met in certain organic polymers.
Journal ArticleDOI
The Aromatic Reactivity of Ferrocene, Ruthenocene and Osmocene1,2
Journal ArticleDOI
The Chemistry and Structure of Ferrocene. VIII. Interannular Resonance and the Mechanism of Electrophilic Substitution
Journal ArticleDOI
Ultraviolet Spectra of Organometallic Compounds1,2
Related Papers (5)
Construction of aromatic-ring-layered structures using a terphenylene-layered polymer as the scaffold
New methods of C‐C and C‐O bond formation in the synthesis of conjugated polymers
Markus Klapper,Klaus Müllen +1 more