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Journal ArticleDOI

The exciton mechanism: Studies in model compounds

Richard S. Schneider
- 01 Jan 1970 - 
- Vol. 29, Iss: 1, pp 27-36
TLDR
In this paper, the authors discussed the little model for a macromolecular high temperature superconductor in terms of its component parts, and showed that polymeric metallocenes, in which planar aromatic hydrocarbon rings and meatal atmos alternate, may be suitable.
Abstract
The “Little” model for a macromolecular high temperature superconductor can be discussed in terms of its component parts. Studies on molecules designed to serve as the polyene and the polyene spine indicate that polymeric metallocenes, in which planar aromatic hydrocarbon rings and meatal atmos alternate, may be suitable. Toward this end the hydrocarbon dicyclopentanaphthalene, and various substituted derivatives were synthesized, and the polymerization of the corresponding dianions with ferrous chloride were investigated.

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Citations
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Journal ArticleDOI

On the possibility of effective attraction between delocalized electrons in organic systems

TL;DR: In this paper, the attractive interaction between delocalized electrons arising from the polarization of both their σ and neighbouring π-systems is shown to overcompensate the Coulomb repulsion.
Book ChapterDOI

Multidecker Organometallic Sandwich Polymers; Prospective Conductive Backbones for the Formation of Macromolecular Architectures Conforming to the Excitonic Superconductor Topology Proposed by Little

TL;DR: In this article, a multilayer structure of perovskites has been described as a factor in enhancing an excitonic interaction between conductive planes mediated through an intervening Cu-O chain.
References
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Journal ArticleDOI

A New Type of Organo-Iron Compound

TL;DR: In this article, the reaction of Grignard reagents with anhydrous ferric chloride was studied, but no definite evidence for organo-iron compounds was found in such reactions.
Journal ArticleDOI

Possibility of synthesizing an organic superconductor

TL;DR: In this article, London's idea that superconductivity might occur in organic macromolecules is examined in the light of the BCS theory of superconductivities and it is shown that the criterion for the occurrance of such a state can be met in certain organic polymers.
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