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Journal ArticleDOI

Thermal stability of nitride thin films

Lars Hultman
- 01 Apr 2000 - 
- Vol. 57, Iss: 1, pp 1-30
TLDR
In this paper, a review of the thermal stability of state-of-the-art transition metal nitride thin films synthesized by physical vapour deposition techniques is presented, where the authors show that they are successfully applied as well.
About
This article is published in Vacuum.The article was published on 2000-04-01. It has received 535 citations till now. The article focuses on the topics: Nitride & Physical vapor deposition.

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Citations
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Journal ArticleDOI

Microstructural design of hard coatings

TL;DR: In this article, the authors demonstrate the correlation between microstructure and mechanical as well as tribological properties of hard ceramic coatings and demonstrate that nanostructure dependent hardness increase (compared to hardness of the bulk counterparts) sustains higher annealing temperatures than hardness increase due to an increased density of point-and/or line-defects.
Journal ArticleDOI

Different approaches to superhard coatings and nanocomposites

TL;DR: In this paper, different approaches to the preparation of superhard coatings such as intrinsically superhard materials, coatings whose hardness is enhanced by energetic ion bombardment during deposition, and nanostructured super-hard materials are discussed with the emphasis on the question of how to distinguish between the different mechanisms of hardness enhancement in thin coatings.
Journal ArticleDOI

Hard nanocomposite coatings: Thermal stability, oxidation resistance and toughness

TL;DR: In this paper, the authors report on the enhanced hardness of nanocomposite coatings, their thermal stability, protection of the substrate against oxidation at temperatures above 1000°C, X-ray amorphous coatings thermally stable above 1000 °C and new advanced hard Nanocomposites with enhanced toughness which exhibit (i) low values of the effective Young's modulus E ⁎ satisfying the condition H/E < 0.1, (ii) high elastic recovery W e ǫ ≥ 60%, (iii) strongly improved tribological properties,
Journal ArticleDOI

Self-organized nanostructures in the Ti–Al–N system

TL;DR: In this paper, a model system, Ti1-xAlxN, was chosen as such coatings are known for their excellent wear resistance enabling improved m... and the phenomenon of age hardening could be evidenced in thin film applications.
Journal ArticleDOI

Nanoparticle plasmonics: going practical with transition metal nitrides

TL;DR: In this article, a brief discussion on alternative plasmonic materials for localized surface plasmor applications and focuses on transition metal nitrides, in particular, titanium nitride, which has recently been shown to be a high performance refractory material that could replace and even outperform gold in various plammonic devices.
References
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Book

Thermochemical properties of inorganic substances

Ihsan Barin, +1 more
TL;DR: In this paper, a volume of tables conveying the thermochemical parameters of more than 2000 substances, cover enthalpy, entropy, chemical potential and Planck's function, and commentaries on the chemical reactions of the relevant component and indications of stability/metastability.
Journal ArticleDOI

The search for novel, superhard materials

TL;DR: The recent development in the field of superhard materials with Vickers hardness of ⩾40 GPa is reviewed in this article, where two basic approaches are outlined including the intrinsic superhard material, such as diamond, cubic boron nitride, C3N4, carbonitrides, etc. and extrinsic, nanostructured materials for which superhardness is achieved by an appropriate design of their microstructure.
Journal ArticleDOI

Material selection for hard coatings

TL;DR: In this paper, the potential of multicomponent boride, carbide, nitride, and oxide systems as coating materials is discussed in view of their potential as coating material.
Journal ArticleDOI

Point Defects in Metals

TL;DR: In this article, the fraction of atom sites that are vacant for lead at its melting temperature of 327°C (600 K) is computed. But the fraction is not fixed.
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