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Thiopyrans and Their Benzo Derivatives

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The article was published on 2020-01-01. It has received 1 citations till now. The article focuses on the topics: Ring (chemistry) & Section (typography).

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[3+3] Annulation of donor-acceptor cyclopropanes with mercaptoacetaldehyde: application to the synthesis of tetrasubstituted thiophenes.

TL;DR: A conceptually new method for synthesis of tetrasubstituted thiophenes in two steps from trans-2-aroyl-3-aryl-cyclopropane-1,1-dicarboxylates and 1,4-dithiane-2,5-diol has been developed.
Journal ArticleDOI

Chiral quaternary alkylammonium ionic liquid [Pro-dabco][BF4]: as a recyclable and highly efficient organocatalyst for asymmetric Michael addition reactions

TL;DR: In this paper, a series of chiral quaternary ammonium ionic liquids have been synthesized and shown to be very effective catalysts for the asymmetric Michael addition reactions of ketones and aldehydes to nitroolefins with excellent yields and diastereoselectivities.
Journal ArticleDOI

Copper-Catalyzed Domino Synthesis of 2-Arylthiochromanones through Concomitant C-S Bond Formations Using Xanthate as Sulfur Source.

TL;DR: An efficient domino process for the synthesis of thioflavanones has been described using a copper catalyst without addition of any external ligand using xanthate as an odorless sulfur source.
Journal ArticleDOI

Enzymatic Synthesis of Novel Chiral Sulfoxides Employing Baeyer–Villiger Monooxygenases

TL;DR: Careful selection of the reaction conditions, starting sulfide, and biocatalyst can be used to achieve good to excellent enantiomeric excess values and valuable chiral synthons can be obtained by performing the reactions under mild and environmentally friendly conditions.
Journal ArticleDOI

Fused xanthone derivatives as antiproliferative agents.

TL;DR: The furanoxanthone psorospermin is a highly promising isolated xanthone derivative exhibiting significant cytotoxicity through a novel mechanism of action, being an irreversible topoisomerase II poison and it was selected for further development as an antineoplastic agent.