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Thiopyrans and Their Benzo Derivatives

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The article was published on 2020-01-01. It has received 1 citations till now. The article focuses on the topics: Ring (chemistry) & Section (typography).

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Base-catalyzed tandem Michael/dehydro-Diels-Alder reaction of α,α-dicyanoolefins with electron-deficient 1,3-conjugated enynes: a facile entry to angularly fused polycycles.

TL;DR: A base-promoted tandem Michael addition and DDA reaction of α,α-dicyanoolefins with electron-deficient 1,3-conjugated enynes was realized and control experiments support the stepwise anionic reaction pathway rather than the concerted reaction pathway.
Journal ArticleDOI

Proline-based reduced dipeptides as recyclable and highly enantioselective organocatalysts for asymmetric Michael addition.

TL;DR: A series of novel proline-based reduced dipeptides was developed and evaluated for a direct Michael addition of ketones and aldehydes to nitroalkenes and achieved excellent yields, diastereoselectivities and enantioselectivity in the presence of 5 mol% catalyst.
Journal ArticleDOI

Synthesis of 6-Fluoroalkyl 6H-Benzo[c]chromenes via Visible-Light-Promoted Radical Addition/Cyclization of Biaryl Vinyl Ethers

TL;DR: A novel visible-light-promoted cascade cyclization reaction for the synthesis of 6-fluoroalkyl 6 H-benzo[ c]chromenes has been successfully realized and provided the desired products in moderate to good yields.
Journal ArticleDOI

Combining prolinamides with 2-pyrrolidinone: Novel organocatalysts for the asymmetric aldol reaction

TL;DR: In this article, the combination of prolinamides with derivatives bearing the 2-pyrrolidinone scaffold, deriving from pyroglutamic acid, led to the identification of novel organocatalysts for the intermolecular asymmetric aldol reaction.