Transformation of symmetrization order to nuclear-spin magnetization by chemical reaction and nuclear magnetic resonance.
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A method of obtaining very large nuclear-spin polarizations and a means of extending the resultant sensitivity enhancement to other spins is proposed in which the transfer of order occurs through population differences not associated with magnetization.Abstract:
A method of obtaining very large nuclear-spin polarizations is proposed and illustrated by density-operator calculations. The prediction is that chemical reaction and rf irradiation can convert the scalar parahydrogen state into polarization of order unity on the nuclear spins of the products of molecular-hydrogen addition reactions. A means of extending the resultant sensitivity enhancement to other spins is proposed in which the transfer of order occurs through population differences not associated with magnetization.read more
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Clinical-Scale Batch-Mode Production of Hyperpolarized Propane Gas for MRI.
Oleg G. Salnikov,Panayiotis Nikolaou,Nuwandi M. Ariyasingha,Kirill V. Kovtunov,Igor V. Koptyug,Eduard Y. Chekmenev,Eduard Y. Chekmenev +6 more
TL;DR: It is shown that high polarization values can be retained despite the significant increase in the production rate of hyperpolarized propane, which enables the future use of this compound as a new inhalable contrast agent for diagnostic detection via MRI.
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Magnetic resonance imaging of (1)H long lived states derived from parahydrogen induced polarization in a clinical system.
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Organic Reaction Monitoring of a Glycine Derivative Using Signal Amplification by Reversible Exchange-Hyperpolarized Benchtop Nuclear Magnetic Resonance Spectroscopy.
Heelim Chae,Sein Min,Hye Jin Jeong,Sung Keon Namgoong,Sangwon Oh,Kiwoong Kim,Kiwoong Kim,Keunhong Jeong +7 more
TL;DR: This study is the first example of the monitoring of the organic reaction by SABRE and benchtop NMR, and it will open new possibilities for applying this sys-tem to many other organic reactions, and also provide more fruitful future applications such as drug discovery and mech-anism study.
Journal ArticleDOI
The effect of oxidative and reductive treatments of titania-supported metal catalysts on the pairwise hydrogen addition to unsaturated hydrocarbons
Oleg G. Salnikov,Dudari B. Burueva,Evgeniy Yu. Gerasimov,Andrey V. Bukhtiyarov,Alexander K. Khudorozhkov,Igor P. Prosvirin,Larisa M. Kovtunova,Danila A. Barskiy,Valerii I. Bukhtiyarov,Kirill V. Kovtunov,Igor V. Koptyug +10 more
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Journal ArticleDOI
Following Metabolism in Living Microorganisms by Hyperpolarized 1H NMR
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