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Journal ArticleDOI

Transition-metal-catalyzed epoxidations

Karl Anker Joergensen
- 01 May 1989 - 
- Vol. 89, Iss: 3, pp 431-458
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This article is published in Chemical Reviews.The article was published on 1989-05-01. It has received 931 citations till now. The article focuses on the topics: Transition metal.

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Coordination chemistry of vanadium in biological systems

TL;DR: This work has shown that vanadium-protein interactions with nucleic acids, as well as other systems, are related to dopamine-substituted bleomycin and J-monooxygenase respectively.
Journal ArticleDOI

Zeolite-encapsulated Mn(II) complexes as catalysts for selective alkene oxidation

TL;DR: In this paper, it was shown that when encapsulated in the supercages of zeolites X and Y, cis-[Mn(bpy)2]2+ complexes can catalyse selective epoxidation of alkenes without complications from competing processes such as self-oxidation or catalase activity.
Journal ArticleDOI

Oxovanadium complexes in catalytic oxidations

TL;DR: In this paper, an overview on the application of oxovanadium complexes as catalysts or mediators for oxidations by molecular oxygen, peroxidative oxygenations (both including epoxidations), halogenations and carboxylations of aliphatic and aromatic hydrocarbons, and/or olefins, toward the syntheses of a variety of organic compounds, such as alcohols, ketones, epoxides, aldehydes, organohalides and orcarboxylic acids.
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Alkylrhenium oxides as homogeneous epoxidation catalysts: Activity, selectivity, stability, deactivation

TL;DR: In this article, the synthesis and crystal structure of the monomeric amino-functionalized complex O 3 ReO(O 2 ) 2 · H 2 O 2 (4A) and its (violet) polymeric form (4B ) are reported.
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