Journal ArticleDOI
Transition-metal-catalyzed epoxidations
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This article is published in Chemical Reviews.The article was published on 1989-05-01. It has received 931 citations till now. The article focuses on the topics: Transition metal.read more
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Book ChapterDOI
Biomimetic Oxidation of Hydrocarbons with Air over Metalloporphyrins
TL;DR: In this paper, a metalloporphyrin-catalyzed catalysts were used as catalysts to catalyze a wide variety of oxidation reactions including epoxidation, hydroxylation, dealkylation and degradation.
Journal ArticleDOI
Highly efficient epoxidation of alkenes with hydrogen peroxide catalyzed by tungsten hexacarbonyl supported on multi-wall carbon nanotubes
Mehdi Nooraeipour,Majid Moghadam,Shahram Tangestaninejad,Valiollah Mirkhani,Iraj Mohammadpoor-Baltork,S. Masoud Nabavizadeh +5 more
TL;DR: In this article, the preparation, characterization, and catalytic activity of W(CO)6 supported on multi-wall carbon nanotubes modified with 4-aminopyridine is reported.
Journal ArticleDOI
Imidomolybdenum(IV) porphyrin complexes: synthesis, characterization, and intermetal imido transfer reactivity.
TL;DR: The imido(meso-tetra-p-tolylporphyrinato)molybdenum(IV) complexes, (TTP)Mo=NR, can be prepared by the reaction of (T TP)MoCl2 with 2 equiv of LiNHR in toluene and resulted in complete imido group transfer and two-electron redox of the metal centers.
Journal ArticleDOI
Copper-catalyzed mild desulfonylation of vinyl sulfonyl molecules
TL;DR: The first Cu-catalyzed chemical selective desulfonylation of vinyl sulfonyl fluorides and their corresponding olefins was developed using B2pin2-water as the reductant as discussed by the authors.
Journal ArticleDOI
Investigation of the effect of VOx/ZrO2 structure on the catalytic activity in cyclohexene epoxidation
TL;DR: In this paper, the effect of high temperature treatment on the structure of the materials as well as on the catalytic properties of the vanadate species was investigated in the epoxidation of cyclohexene, with TBHP as the oxidant and heptane as the solvent.
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