Journal ArticleDOI
Transition-metal-catalyzed epoxidations
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This article is published in Chemical Reviews.The article was published on 1989-05-01. It has received 931 citations till now. The article focuses on the topics: Transition metal.read more
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Electronic Structure and Multicatalytic Features of Redox-Active Bis(arylimino)acenaphthene (BIAN)-Derived Ruthenium Complexes
TL;DR: The article examines the newly designed and structurally characterized redox-active BIAN-derived trpy and naphthalene π-system of BIAN or BIAO, which are efficient and selective precatalysts in transforming a wide variety of alkenes to corresponding epoxides in the presence of PhI(OAc)2 as an oxidant in CH2Cl2 at 298 K.
Journal ArticleDOI
Synthetic oxidations with hypochlorites. a review
Journal ArticleDOI
Peroxomolybdate(VI)–citrate and –malate complex interconversions by pH-dependence. Synthetic, structural and spectroscopic studies
TL;DR: The reaction of potassium molybdate(VI) with biologically relevant ligands, citric and malic acids, in the presence of H2O2 was investigated for the effect of pH variations on the product pattern.
Journal ArticleDOI
Enhanced Reactivity of 2‐Rhodaoxetanes through a Labile Acetonitrile Ligand
Bas de Bruin,Johanna A. W. Verhagen,Caroline H. J. Schouten,Anton W. Gal,Derek Feichtinger,Dietmar A. Plattner +5 more
TL;DR: New cationic, square-planar, ethene complexes [(Rbpa)RhI(C2H4)]+ have been selectively oxygenated in acetonitrile by aqueous hydrogen peroxide to 2-rhoda(III)oxetanes with a labile acetitrile ligand.
Journal ArticleDOI
Microporous Zirconia–Silica Mixed Oxides Made by Sol–Gel as Catalysts for the Liquid-Phase Oxidation of Olefins with Hydrogen Peroxide
TL;DR: In this paper, the preparation of a series of microporous zirconia-silica mixed oxides by sol-gel is reported, which have been characterized by BET methods, thermogravimetric analysis, X-ray diffraction analysis, UV-vis spectroscopy, and TPD of ammonia.
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