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Transition Metal Oxides: An Introduction to Their Electronic Structure and Properties

P. A. Cox
TLDR
In this article, the authors present a chemical aspects structural principles of electronic classification and models of electronic structure: ionic models cluster models band theory intermediate models, point-defects and semiconduction, electronic carrier properties.
Abstract
Part 1 Introduction: scope and plan of the book chemical aspects structural principles electronic classification. Part 2 Models of electronic structure: ionic models cluster models band theory intermediate models. Part 3 Insulating oxides: d0 compounds other closed-shell oxides transition metal impurities magnetic insulators. Part 4 Defects and semiconduction: electronic carrier properties the point-defect model carrier binding energies and spectroscopy transition to the metallic state. Part 5 Metallic oxides: simple metals electron correlation and magnetic anomalies Lattice interactions superconductivity.

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The Role of Metal Ion Dopants in Quantum-Sized TiO2: Correlation between Photoreactivity and Charge Carrier Recombination Dynamics

TL;DR: In this article, the presence of metal ion dopants in the TiO_2 crystalline matrix significantly influences photoreactivity, charge carrier recombination rates, and interfacial electron-transfer rates.
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Review of the anatase to rutile phase transformation

TL;DR: A comprehensive analysis of the reported effects of dopants on the anatase to rutile phase transformation and the mechanisms by which these effects are brought about is presented in this article, yielding a plot of the cationic radius versus the valence characterised by a distinct boundary between inhibitors and promoters.
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Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting

TL;DR: The current state of research on nanoscale-enhanced photoelectrodes and photocatalysts for the water splitting reaction with special emphasis of Fe(2)O(3) with an outlook on the challenges in solar fuel generation with nanoscales inorganic materials is reviewed.
Journal ArticleDOI

Systematic XPS studies of metal oxides, hydroxides and peroxides

TL;DR: In this article, the results of a systematic XPS study, under high controlled conditions, of different basic oxides of transition metals, alkali and alkaline-earth metals are presented; the XPS data of some hydroxides and peroxides are also reported.
Journal ArticleDOI

Metal oxides for solid-state gas sensors: What determines our choice?

TL;DR: In this article, the analysis of various parameters of metal oxides and the search of criteria, which could be used during material selection for solid-state gas sensor applications, were the main objectives of this review.
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