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Triplet Photosensitizers Showing Strong Absorption of Visible Light and Long-Lived Triplet Excited States and Application in Photocatalysis: A Mini Review

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This article is published in Energy & Fuels.The article was published on 2021-08-19. It has received 19 citations till now. The article focuses on the topics: Absorption (electromagnetic radiation).

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Selective population of triplet excited states in heavy-atom-free BODIPY-C60 based molecular assemblies

TL;DR: In this article , the lifetime and formation quantum yield of the triplet-excited state were investigated on a BODIPY-fullerene-distyryl BOVIPY triad (BDP-C60-DSBDP) and its reference dyads.
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Sensitizing photoactive metal–organic frameworks via chromophore for significantly boosting photosynthesis

TL;DR: Wang et al. as discussed by the authors proposed a promising strategy to improve the sensitizing ability of the typical photoactive MOFs (UiO-Ir) by engineering its metal coordination center with NBI (1,8-naphthalenebenzimidizole) chromophore.
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Photo-induced reversible nitric oxide capture by Fe-M(CO2H)4 (M = Co, Ni, Cu) as a building block of mixed-metal BTC-based MOFs.

TL;DR: In this article , the photo-induced switching behavior of mixed-metal Fe-M (M = Co, Ni, Cu) formate (Fe-M(CO2H)4), as an experimentally feasible strategy for the reversible capture of nitric oxide (NO), was explored.
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Transition metal(II) complexes of halogenated derivatives of (E)-4-(2-(pyridin-2-ylmethylene)hydrazinyl)quinazoline: structure, antioxidant activity, DNA-binding DNA photocleavage, interaction with albumin and in silico studies.

TL;DR: In this paper , two halogenated quinazoline derivatives, namely [(E)-4-(2-((6-bromopyridin-2-yl)methylene)hydrazinyl)quinazoline] (L1) and [(E]-4-( 2-((3-fluoropyrin-1-yl)-2-polymorphic-hexyl)-hexyl) methylene) hydrazyl) quinnazoline) (L2), were synthesized and characterized.
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Charge Transfer Mediated Triplet Excited State Formation in Donor-Acceptor-Donor BODIPY: Application for Recording of Holographic Structures in Photopolymerizable Glass

TL;DR: In this paper , a BODIPY triad bearing anthracene or pyrene as electron donating subunits was prepared through a stepwise synthesis, and photoinduced electron transfer and formation of long-lived triplet excited states via spin-orbit charge was performed.
References
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Journal ArticleDOI

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

TL;DR: The conversion of these bench stable, benign catalysts to redox-active species upon irradiation with simple household lightbulbs represents a remarkably chemoselective trigger to induce unique and valuable catalytic processes.
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Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis

TL;DR: The inactivity of the parent UiO-67 framework and the reaction supernatants in catalytic water oxidation, CO(2) reduction, and organic transformations indicate both the molecular origin and heterogeneous nature of these catalytic processes.
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Triplet photosensitizers: from molecular design to applications

TL;DR: This review article summarizes some molecular design rationales for triplet PSs, based on the molecular structural factors that facilitate ISC, and the design of transition metal complexes with large molar absorption coefficients in the visible spectral region and long-lived triplet excited states is presented.
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