Journal ArticleDOI
Unfavorable Coordination of Copper with Methyl Vinyl Ketone in Atom Transfer Radical Polymerization
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This article is published in Macromolecules.The article was published on 2006-07-06. It has received 34 citations till now. The article focuses on the topics: Radical polymerization & Cobalt-mediated radical polymerization.read more
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Synthesis of functional polymers by post-polymerization modification.
TL;DR: This Review surveys different classes of reactive polymer precursors bearing chemoselective handles and discusses issues related to the preparation of these reactive polymers by direct polymerization of appropriately functionalized monomers as well as the post-polymerization modification of these precursor into functional polymers.
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Smart “All Acrylate” ABA Triblock Copolymer Bearing Reactive Functionality via Atom Transfer Radical Polymerization (ATRP): Demonstration of a “Click Reaction” in Thermoreversible Property
TL;DR: In this paper, tailor-made ABA triblock copolymers bearing a reactive pendant furfuryl group were successfully synthesized by atom transfer radical polymerization, and the chemical compositions were calculated by 1H NMR, and molecular weights and molecular weight distributions were determined by gel permeation chromatography analysis.
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Tailoring Polymer Dispersity by RAFT Polymerization: A Versatile Approach
Richard Whitfield,Kostas Parkatzidis,Nghia P. Truong,Nghia P. Truong,Tanja Junkers,Athina Anastasaki +5 more
TL;DR: In this article, a batch method based on reversible addition-fragmentation chain transfer (RAFT) polymerization was proposed to tailor the molecular weight distributions for a wide range of monomer classes, including acrylates, acrylamides, methacrylate, and styrene.
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A comparison of RAFT and ATRP methods for controlled radical polymerization
TL;DR: In this paper, the authors compared reversible addition-fragmentation chain-transfer (RAFT) and atom transfer radical polymerization (ATRP) to identify their mechanistic strengths and weaknesses, versatility and latest synthetic advances.
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Photoinduced Organocatalyzed Atom Transfer Radical Polymerization (O-ATRP): Precision Polymer Synthesis Using Organic Photoredox Catalysis.
TL;DR: The development of photo-induced organocatalyzed atom transfer radical polymerization (O-ATRP) has received considerable attention since its introduction in 2014 as mentioned in this paper, allowing well-defined polymers to be produced under mild reaction conditions using organic photoredox catalysts.
References
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Journal ArticleDOI
Controlled/"living" radical polymerization. atom transfer radical polymerization in the presence of transition-metal complexes
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Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris- (triphenylphosphine)ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization
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Functional polymers by atom transfer radical polymerization
TL;DR: Atom transfer radical polymerization (ATRP) is one of the most successful methods to polymerize styrenes, (meth)acrylates and a variety of other monomers in a controlled fashion, yielding polymers with molecular weights predetermined by the ratio of the concentrations of consumed monomer to introduced initiator and with low polydispersities as discussed by the authors.
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Controlled/Living Radical Polymerization
TL;DR: A review of the evolution of radical polymerization can be found in this article, which summarizes the materials that can now be prepared, and highlights some of the commercialization efforts currently underway.