Can Zinc oxide be doped with neutron transmutation doping?5 answersYes, Zinc oxide (ZnO) can indeed be doped through neutron transmutation doping. Research has shown that neutron irradiation of ZnO can lead to the transmutation of Zinc (Zn) into Gallium (Ga), Gadolinium (Gd), and Iron (Fe), and even Copper (Cu). Neutron irradiation of ZnO results in the creation of Cu-65 from Zn-65, as confirmed by the detection of characteristic gamma rays and EPR spectroscopic results. Additionally, neutron transmutation doping has been observed to change the majority mobile carrier in ZnO nanorods from electrons to holes, showcasing the effectiveness of this method in altering the material's properties. Therefore, neutron transmutation doping presents a viable method for introducing dopants into ZnO crystals.
How does nitrogen doping affect the electrical properties of graphite in Li-ion batteries?5 answersNitrogen doping significantly influences the electrical properties of graphite in Li-ion batteries. Studies have shown that nitrogen-doped materials exhibit enhanced electrochemical performance compared to pristine graphite anodes. Nitrogen doping introduces functional groups and alters the surface morphology, leading to improved crystallinity, stability, and rate capability. The presence of nitrogen in the carbon matrix enhances the binding ability of Li+ ions, improves the charge-transfer process, and induces more defects, ultimately enhancing the efficiency of Li-ion cells. Additionally, the nitrogen-doped carbon-coated nano-Si/graphite composites demonstrate stable specific capacity and excellent rate performance, highlighting the positive impact of nitrogen doping on the electrical properties of graphite in Li-ion batteries.
Is there any research on the effects of xenon diflouride on silicon nitride?5 answersXenon difluoride (XeF2) has been studied for its effects on silicon nitride (SiN) in several research papers. Wu and Karwacki demonstrated that XeF2 can selectively etch TiN from SiN surfaces, converting it into a volatile species. Balakshin et al. investigated the destruction of the silicon crystal structure under irradiation and found that defects accumulate in the modified layer, leading to the formation of amorphous layers. Bergonzo and Boyd explored the use of excimer lamps for direct photodeposition of SiN from mixtures of silane and ammonia, resulting in good film qualities. Reents et al. observed the reaction of cationic silicon clusters with XeF2, leading to mono- or difluorination of the clusters. Mustafa et al. produced SiN thin films using RF magnetron sputtering and characterized their structure, surface morphology, and optical properties.
Doping in Extrinsic Semiconductors5 answersDoping in extrinsic semiconductors refers to the process of introducing impurity atoms into pure semiconductors to modify their electrical conductivity. This controlled introduction of impurities allows for the tuning of the conductivity in a highly controlled manner. Extrinsic doping can significantly enhance the structural, optical, electronic, and electrical properties of semiconductor materials, leading to improved performance in photocatalytic and photoelectrochemical applications. By incorporating dopants into semiconductors, the number of free charge carriers (electrons or holes) can be increased, resulting in "p-type" or "n-type" semiconductors. Doping is crucial for the development of nanoscale semiconductor devices, as it allows for the optimization of key optoelectronic properties such as electron mobility and carrier lifetime. Electrostatic doping is an alternative method that replaces chemical doping and provides high electron/hole density in semiconductor devices through gate-induced free charges.
What is the properties of n-doping carbon?5 answersN-doping carbon has various properties. N-doped TiO2/carbon composites showed changes in structural and surface characteristics, improving their adsorption but decreasing photocatalytic efficiency. Carbon-coated Cu nanocomposites with N-doping achieved enhanced dielectric loss in both microwave and THz bands. Nitrogen-doped carbon quantum dots (N-CQDs) derived from biomass showed significant enhancement in fluorescence emission properties compared to pure glucose-derived CQDs without nitrogen doping. Nitrogen-doped carbon materials with a high nitrogen content and uniform distribution exhibited excellent electrochemical performance in lithium-ion batteries and sodium-ion batteries. Carbon nano-onions (CNOs) prepared with nitrogen self-doping showed good fluorescence performance, with stable blue light emission that could be used for data encryption and decryption.
How to increase Nitrogen doping using pyrolysis and urea or ammoniaon carbon based material?5 answersTo increase nitrogen doping in carbon-based materials using pyrolysis and urea or ammonia, several methods have been proposed. One approach involves annealing a GO@CNTs precursor and an ammonia source compound in an inert atmosphere to obtain a nitrogen-doped carbon-based composite material. Another method utilizes a pyrolysis-deposition-self-doping (PDSD) technique in a confined graphite canister, which significantly increases the nitrogen content in the resulting hard carbon material. Additionally, nitrogen-doped carbon nanofibers can be prepared by thermal treatment of electrospun PVP nanofibers via the pyrolysis of g-C3N4, with the nitrogen content being tunable based on the treatment temperature. Furthermore, introducing exogenous nitrogen, such as NH3, during biomass pyrolysis has been shown to increase the nitrogen content and the number of nitrogen-containing functional groups in the resulting bio-char material. Finally, a preparation method involving the pyrolysis of urea and a soluble trivalent complexing ferric salt has been proposed to obtain a nitrogen-doping carbon substrate-supported Fe3O4 composite material.