Showing papers on "Archean published in 2014"

Multi-stage crustal growth and cratonization of the North China Craton

Abstract: The North China Craton (NCC) has a complicated evolutionary history with multi-stage crustal growth, recording nearly all important geological events in the early geotectonic history of the Earth. Our studies propose that the NCC can be divided into six micro-blocks with >∼3.0–3.8 Ga old continental nuclei that are surrounded by Neoarchean greenstone belts (GRB). The micro-blocks are also termed as high-grade regions (HGR) and are mainly composed of orthogneisses with minor gabbros and BIF-bearing supracrustal beds or lenses, all of which underwent strong deformation and metamorphism of granulite- to high-grade amphibolite-facies. The micro-blocks are, in turn, from east to west, the Jiaoliao (JL), Qianhuai (QH), Ordos (ODS), Ji'ning (JN) and Alashan (ALS) blocks, and Xuchang (XCH) in the south. Recent studies led to a consensus that the basement of the NCC was composed of different blocks/terranes that were finally amalgamated to form a coherent craton at the end of Neoarchean. Zircon U-Pb data show that TTG gneisses in the HGRs have two prominent age peaks at ca. 2.9–2.7 and 2.6–2.5 Ga which may correspond to the earliest events of major crustal growth in the NCC. Hafnium isotopic model ages range from ca. 3.8 to 2.5 Ga and mostly are in the range of 3.0–2.6 Ga with a peak at 2.82 Ga. Recent studies revealed a much larger volume of TTG gneisses in the NCC than previously considered, with a dominant ca. 2.7 Ga magmatic zircon ages. Most of the ca. 2.7 Ga TTG gneisses underwent metamorphism in 2.6–2.5 Ga as indicated by ubiquitous metamorphic rims around the cores of magmatic zircon in these rocks. Abundant ca. 2.6–2.5 Ga orthogneisses have Hf-in-zircon and Nd whole-rock model ages mostly around 2.9–2.7 Ga and some around 2.6–2.5 Ga, indicating the timing of protolith formation or extraction of the protolith magma was from the mantle. Therefore, it is suggested that the 2.6–2.5 Ga TTGs probably represent a coherent event of continental accretion and major reworking (crustal melting). As a distinct characteristic, nearly all GRBs in the NCC underwent amphibolite-facies metamorphism. Zircon U-Pb ages of metamorphosed GRB mafic rocks mainly show two peak ranges at ∼2.6–2.5 and 2.8–2.7 Ga. The mafic rocks are commonly believed to be derived from metabasalts, it is therefore possible that the ages represent the time of metamorphism. The tectonic settings of the GRBs are still a problem. Their geochemical characteristics are, respectively, similar to back-arc basins, rifts, island arcs or suggest imprints of mantle plumes. BIFs occur in all GRBs but also in the HGRs. This metallogenic specificity is quite different from all Phanerozoic geotectonic settings. The ∼2.5 Ga metamorphic-magmatic event is stronger than in most other cratons in the world. How to understand the geological significance of the 2.5 Ga event? The following points are emphasized: (1) nearly all old rocks >2.5 Ga underwent metamorphism at ∼2.52–2.5 Ga; (2) Archean basement rocks in the NCC experienced strong partial melting and migmatization; (3) granitoid rocks derived from partial melting include potassium granites, TTG granites and monzonites. These granitoids rocks intruded both the Archean greenstone belts and micro-blocks; (4) ∼2.5 Ga mafic dikes (amphibolites), granitic dikes (veins) and syenitic-ultramafic dykes are also developed. Therefore, we suggest an assembly model that all micro-blocks in the NCC were welded together by late Archean greenstone belts at the end of the late Neoarchean. We also propose that the various micro-blocks were surrounded by small ocean basins, and the old continental crust and the oceanic crust were hotter than today. Subduction and collision were on much smaller scales as compared to the Phanerozoic plate tectonic regime, although the tectonic style and mechanisms were more or less similar. The formation of crustal melt granites is one of the processes of cratonization, inducing generation of stable upper and lower crustal layers. This process also generated an upper crust of more felsic composition and a lower crust of more mafic composition, due to molten residual materials and some underplated gabbros.

Iron Formations: Their Origins and Implications for Ancient Seawater Chemistry

Abstract: Iron formations are economically significant, iron- and silica-rich sedimentary rocks that are restricted to Precambrian successions. There are no known modern or Phanerozoic analogues for these deposits that are comparable in terms of areal extent and thickness. Although many aspects of iron formation origin remain debatable, it is generally accepted that secular changes in the style of deposition are genetically linked to plate tectonic processes, mantle plume events, and evolution of Earth's surface environments. Two types of Precambrian iron formations have been recognized based on depositional and tectonic settings. Iron formations formed proximal to volcanic centers are interlayered with or laterally linked to submarine volcanic rocks and, in some cases, with volcanogenic massive sulfide (VMS) deposits. In contrast, larger sedimentary rock-hosted iron formations are developed in passive-margin settings and typically lack a direct association with volcanic rocks. A full gradation between these two end-members exists in the rock record. Texturally, iron formations are divided into two groups. Banded iron formation (BIF) is predominant in Archean to earliest Paleoproterozoic successions, whereas granular iron formation (GIF) is more common in middle to late Paleoproterozoic successions, having been deposited in shallow-marine settings after the rise of atmospheric oxygen at ~2.4 Ga. Secular changes in the style of iron formation deposition have been linked to a diverse array of environmental changes. Geochronologic studies emphasize the periodicity in deposition of giant iron formations, which are coeval with large igneous provinces (LIPs). Giant sedimentary rock-hosted iron formations first appeared ~ 2.6 Ga, possibly when the construction of large continents changed the heat flux across the core–mantle boundary. From ~ 2.6 to ~ 2.4 Ga, global mafic-to-ultramafic magmatism culminated in the deposition of giant sedimentary rock-hosted iron formations in South Africa, Australia, Brazil, Russia, and Ukraine. The younger BIFs in this age range were deposited immediately before a shift from reducing to oxidizing conditions in the ocean–atmosphere system. Counterintuitively, enhanced magmatism at 2.50–2.45 Ga, which likely delivered large amounts of reductants to shallow-marine environments, may have triggered atmospheric oxidation. After the rise of atmospheric oxygen ~ 2.4 Ga, GIF became more abundant in the rock record than BIF. Iron formations largely disappeared ~ 1.85 Ga, reappearing at the end of the Neoproterozoic, again tied to periods of intense magmatic activity and also, in this case, to global-scale glaciations, during the so-called snowball Earth events. In the Phanerozoic, deeper-water iron formation deposition became restricted to local areas of closed to semi-closed basins, where volcanic and hydrothermal activity was extensive, such as in back-arc basins. In contrast, episodically deposited, basin-scale Phanerozoic oolitic and pisolitic ironstones are linked to periods of intense magmatic activity and ocean anoxia. Late Paleoproterozoic iron formations and at least some Paleozoic ironstones were deposited at the redoxcline, where biological and nonbiological oxidation occurred. In contrast, older iron formations were deposited in anoxic oceans, where ferrous iron oxidation by anoxygenic photosynthetic bacteria was likely an important process. Endogenic and exogenic factors contributed to the production of the conditions necessary for deposition of iron formation. Mantle plume events that led to the emplacement of LIPs also enhanced spreading rates of mid-ocean ridges and resulted in higher growth rates of oceanic plateaus; both processes thus contributed to a higher hydrothermal iron flux to the oceans. Oceanic and atmospheric redox states determined the fate of this flux. When the hydrothermal flux overwhelmed the ocean oxidation state, iron was transported and deposited distally from hydrothermal vents. Where the hydrothermal flux was insufficient to overwhelm the ocean redox state, iron was deposited mainly proximally, generally as oxides or sulfides; manganese was more mobile. It is concluded that occurrences of BIF, GIF, Phanerozoic ironstones, and hydrothermal sedimentary rocks of exhalative origin (exhalites) surrounding VMS systems are a record of a complex interplay among mantle plume events, plate tectonics, and ocean redox conditions throughout Earth's history, in which mantle heat unidirectionally decreased and the surface oxidation state mainly unidirectionally increased, accompanied by superimposed shorter-term fluctuations.

Four billion years of ophiolites reveal secular trends in oceanic crust formation

Abstract: We combine a geological, geochemical and tectonic dataset from 118 ophiolite complexes of the major global Phanerozoic orogenic belts with similar datasets of ophiolites from 111 Precambrian greenstone belts to construct an overview of oceanic crust generation over 4 billion years. Geochemical discrimination systematics built on immobile trace elements reveal that the basaltic units of the Phanerozoic ophiolites are dominantly subduction-related (75%), linked to backarc processes and characterized by a strong MORB component, similar to ophiolites in Precambrian greenstone sequences (85%). The remaining 25% Phanerozoic subduction-unrelated ophiolites are mainly (74%) of Mid-Ocean-Ridge type (MORB type), in contrast to the equal proportion of Rift/Continental Margin, Plume, and MORB type ophiolites in the Precambrian greenstone belts. Throughout the Phanerozoic there are large geochemical variations in major and trace elements, but for average element values calculated in 5 bins of 100 million year intervals there are no obvious secular trends. By contrast, basaltic units in the ophiolites of the Precambrian greenstones (calculated in 12 bins of 250 million years intervals), starting in late Paleo- to early Mesoproterozoic (ca. 2.0–1.8 Ga), exhibit an apparent decrease in the average values of incompatible elements such as Ti, P, Zr, Y and Nb, and an increase in the compatible elements Ni and Cr with deeper time to the end of the Archean and into the Hadean. These changes can be attributed to decreasing degrees of partial melting of the upper mantle from Hadean/Archean to Present. The onset of geochemical changes coincide with the timing of detectible changes in the structural architecture of the ophiolites such as greater volumes of gabbro and more common sheeted dyke complexes, and lesser occurrences of ocelli (varioles) in the pillow lavas in ophiolites younger than 2 Ga. The global data from the Precambrian ophiolites, representative of nearly 50% of all known worldwide greenstone belts provide significant clues for the operation of plate tectonic processes in the Archean.

Heading down early on? Start of subduction on Earth

Abstract: How the Earth’s earliest crust was formed and when present-day plate tectonics (i.e., subduction) and life commenced remain fundamental questions in Earth sciences. Whereas the bulk composition of the crust is similar to that of rocks generated in subduction settings, it does not necessarily follow that melting and crust formation require subduction. Many workers suggest that subduction may have only commenced toward the end of the Archean or later. Here we observe that both the stratigraphy and geochemistry of rocks found in Quebec, Canada, that have been variously argued to be 4.4 or 3.8 Ga in age, closely match those from the modern-day Izu-Bonin-Mariana forearc. We suggest that this geochemical stratigraphy might provide a more robust test of ancient tectonic setting than individual chemical or isotopic signatures in rocks or detrital minerals. If correct, the match suggests that at least some form of subduction may have been operating as early as the Hadean or Eoarchean. This could have provided an ideal location for the development of first life.

Heading down early on? Start of subduction on Earth

Abstract: How the Earth’s earliest crust was formed and when present-day plate tectonics (i.e., subduction) and life commenced remain fundamental questions in Earth sciences. Whereas the bulk composition of the crust is similar to that of rocks generated in subduction settings, it does not necessarily follow that melting and crust formation require subduction. Many workers suggest that subduction may have only commenced toward the end of the Archean or later. Here we observe that both the stratigraphy and geochemistry of rocks found in Quebec, Canada, that have been variously argued to be 4.4 or 3.8 Ga in age, closely match those from the modern-day Izu-Bonin-Mariana forearc. We suggest that this geochemical stratigraphy might provide a more robust test of ancient tectonic setting than individual chemical or isotopic signatures in rocks or detrital minerals. If correct, the match suggests that at least some form of subduction may have been operating as early as the Hadean or Eoarchean. This could have provided an ideal location for the development of first life.

O2 constraints from Paleoproterozoic detrital pyrite and uraninite

Abstract: Redox-sensitive detrital grains such as pyrite and uraninite in sedimentary successions provide one of the most conspicuous geological clues to a different composition of the Archean and early Paleoproterozoic atmosphere. Today, these minerals are rapidly chemically weathered within short transport distances. Prior to the rise of oxygen, low O2 concentrations allowed their survival in siliciclastic deposits with grain erosion tied only to physical transport processes. After the rise of oxygen, redox-sensitive detrital grains effectively vanish from the sedimentary record. To get a better understanding of the timing of this transition, we examined sandstones recorded in a scientifi c drill core from the South African 2.415 Ga Koegas Subgroup, a mixed siliciclastic and iron formation–bearing unit deposited on the western deltaic margin of the Kaapvaal craton in early Paleoproterozoic time. We observed detrital pyrite and uraninite grains throughout all investigated sandstone beds in the section, indicating the rise of oxygen is younger than 2.415 Ga. To better understand how observations of detrital pyrite and uraninite in sedimentary rocks can quantitatively constrain Earth surface redox conditions, we constructed a model of grain erosion from chemical weathering and physical abrasion to place an upper limit on ancient environmental O2 concentrations. Even conservative model calculations for deltaic depositional systems with suffi cient transport distances (approximately hundreds of kilometers) show that redox-sensitive detrital grains are remarkably sensitive to environmental O2 concentrations, and they constrain the Archean and early Paleoproterozoic atmosphere to have <3.2 × 10 –5 atm of molecular O2. These levels are lower than previously hypothesized for redox-sensitive detrital grains, but they are consistent with estimates made from other redox proxy data, including the anomalous fractionation of sulfur isotopes. The binary loss of detrital pyrite and uraninite from the sedimentary record coincident with the rise of oxygen indicates that atmospheric O2 concentrations rose substantially at this time and were never again suffi ciently low (<0.01 atm) to enable survival and preservation of these grains in short transport systems.

The Geologic History of Seawater

Abstract: The geologic record provides clues to the history of seawater over the past 4 Gy. This article highlights key insights from the rapid progress of the past decade, focusing on periods of important geochemical changes and how these changes influenced and were influenced by the evolution of life on Earth. In the Hadean, Archean, and Paleoproterozoic, the origin of the oceans, the emergence of the biosphere, and the rise of oxygen take center stage, especially as revealed by the marine geochemistry of carbon, sulfur, and redox-sensitive metals. In the Meso- and Neoproterozoic, the focus shifts to the interplay between the evolution of the ocean carbon and oxygen cycles and the biology that mediates these cycles. In the Phanerozoic, the discussion centers on cycles in the Mg 2 + /Ca 2 + ratio of seawater, δ 34 S, and Sr 2 + /Ca 2 + , and how they coincide with the mineralogies of limestones and evaporites. How the timing of these cycles may connect to the breakup and assembly of tectonic plates, midocean ridge crust production and hydrothermal activity, global chemical weathering, seawater chemistry, and biomineralization are reviewed. Influences on the mineralogy of shell-building organisms, particularly during the time mineralized skeletons first evolved, are also considered.

Archean komatiite volcanism controlled by the evolution of early continents

Abstract: The generation and evolution of Earth’s continental crust has played a fundamental role in the development of the planet. Its formation modified the composition of the mantle, contributed to the establishment of the atmosphere, and led to the creation of ecological niches important for early life. Here we show that in the Archean, the formation and stabilization of continents also controlled the location, geochemistry, and volcanology of the hottest preserved lavas on Earth: komatiites. These magmas typically represent 50–30% partial melting of the mantle and subsequently record important information on the thermal and chemical evolution of the Archean–Proterozoic Earth. As a result, it is vital to constrain and understand the processes that govern their localization and emplacement. Here, we combined Lu-Hf isotopes and U-Pb geochronology to map the four-dimensional evolution of the Yilgarn Craton, Western Australia, and reveal the progressive development of an Archean microcontinent. Our results show that in the early Earth, relatively small crustal blocks, analogous to modern microplates, progressively amalgamated to form larger continental masses, and eventually the first cratons. This cratonization process drove the hottest and most voluminous komatiite eruptions to the edge of established continental blocks. The dynamic evolution of the early continents thus directly influenced the addition of deep mantle material to the Archean crust, oceans, and atmosphere, while also providing a fundamental control on the distribution of major magmatic ore deposits.

Proterozoic onset of crustal reworking and collisional tectonics: Reappraisal of the zircon oxygen isotope record

Abstract: A global U-Pb and δ18O zircon database shows temporal changes in the magmatic record related to changes in the degree of crustal reworking. The δ18O composition of bulk sediment remains relatively constant through geologic time, with a mean value of 14.9‰. In contrast, the δ18O values in magmatic zircons vary from relatively low values averaging ∼6‰ in the Archean to increasingly higher and scattered values defining a series of peaks and troughs in post-Archean data. The degree of crustal reworking increases at times of supercontinent assembly. Therefore we attribute the pattern of post-Archean δ18O values recorded by magmatic zircons to a significant increase in the incorporation of high δ18O sediment in response to enhanced crustal thickening and reworking associated with the onset of collisional tectonics, especially during formation of supercontinents.

Oxygenation of the Archean atmosphere: New paleosol constraints from eastern India

Abstract: It is widely believed that atmospheric oxygen saturation rose from −5 present atmospheric level (PAL) in the Archean to >10 −2 PAL at the Great Oxidation Event (GOE) at ca. 2.4 Ga, but it is unclear if any earlier oxygenation events occurred. Here we report U-Pb zircon data indicating that a pyrophyllite-bearing paleosol, from Keonjhar in the Precambrian Singhbhum Craton of eastern India, formed between 3.29 and 3.02 Ga, making it one of very few known Archean paleosols globally. Field and geochemical evidence suggests that the upper part of the paleosol was eroded prior to unconformable deposition of an overlying sequence of shallow-marine siliciclastic sediments. A negative cerium anomaly within the currently preserved level of the paleosol indicates that ancient oxidative weathering occurred in the original upper soil profile. The presence of redox-sensitive detrital uraninite and pyrite together with a complete absence of pyrophyllite in the overlying sediments indicate that the mineralogical and geochemical features of the paleosol were established prior to the unconformable deposition of the sediments and are not related to subsequent diagenetic or hydrothermal effects. We suggest that a transient atmospheric oxygenation event occurred at least 600 m.y. prior to the GOE and ∼60 m.y. prior to a previously documented Archean oxygenation event. We propose that several pulsed and short-lived oxygenation events are likely to have occurred prior to the GOE, and that these changes to atmospheric composition arose due to the presence of organisms capable of oxygenic photosynthesis.

Detrital zircons in basement metasedimentary protoliths unveil the origins of southern India

Abstract: Coupled U-Pb and Hf isotopic analysis of detrital zircons from metasedimentary rocks of the Southern Granulite terrane (India) provides provenance information that helps unravel their paleotectonic position before Gondwana amalgamated. The metasedimentary packages of the Salem block (southernmost extension of Dharwar craton) record a restricted juvenile late Archean to early Paleoproterozoic (2.7–2.45 Ga) source provenance and epsilon Hf values between +0.3 and +8.8. Similar late Archean juvenile crust is found throughout the Dharwar craton and represents a likely source for the Salem block metasedimentary rocks. By contrast, the metasedimentary rocks of the Madurai block (south of the Salem block) show a predominantly Archean to Paleoproterozoic provenance (3.2–1.7 Ga) in the northern part of the Madurai block and a largely late Mesoproterozoic to Neoproterozoic provenance (1.1–0.65 Ga) in the southern part of the Madurai block. Collectively, the Madurai block metasedimentary rocks record a mixture of reworked Archean and Paleoproterozoic sources, as well as juvenile Paleoproterozoic, late Mesoproterozoic, and evolved Neoproterozoic sources. These detrital signatures best fit the combined basement ages of the Congo-Tanzania-Bangweulu block and central Madagascar (Azania), thus linking the tectonic evolution of the southernmost tip of India to these domains throughout much of the Proterozoic. The diachroneity of metamorphic ages obtained from the rims of Madurai block detrital zircons attests to their poly-metamorphic history that is different from that of the Salem block. The contrasting metamorphic and depositional histories between the Salem and Madurai blocks place them on opposite sides of the Mozambique Ocean until the latest Neoproterozoic when they came together to form Gondwana.