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Showing papers on "Premixed flame published in 2001"


Journal ArticleDOI
TL;DR: In this article, the authors used Raman scattering and laser-induced fluorescence to measure temperature, the major species (N2, O2, CH4, CO2, H2O, CO, and H2), OH, and NO in steady laminar opposed-flow partially premixed flames of methane and air.

495 citations


Journal ArticleDOI
TL;DR: In this article, the effects of laminar velocities and flame response to stretch were investigated both experimentally and computationally for spherical premixed flames with various diluents, including hydrogen, oxygen, argon, and helium.

307 citations


Journal ArticleDOI
TL;DR: In this paper, a flamelet-generated manifold method for premixed combustion systems is applied to laminar flames, which can be used to give accurate predictions, a semi-practical furnace is modeled and the results are compared with results of detailed computations.

305 citations


Journal ArticleDOI
01 Jan 2001-Fuel
TL;DR: In this paper, the authors used the signal from the first electronically excited state of a premixed laminar flame to ground (at 305.4nm) to determine the viability of using OH chemiluminescence as an active control parameter for high-pressure, premixed flames.

225 citations


Journal ArticleDOI
TL;DR: In this article, the computational singular perturbation for the analysis and reduction of complicated chemical mechanisms has been extended to the complex eigensystem and the characteristic time scale for each species was defined by using the time scales of the independent modes weighted by radical pointers, and the time scale of each species normalized by a characteristic time-scale of the system was used as a criterion in determining the quasi-steady state species.

217 citations


Journal ArticleDOI
TL;DR: In this paper, a large eddy simulation (LES) was applied to the calculation of a turbulent hydrogen diffusion flame using a conserved scalar formalism, and the results of the simulations show that LES is capable of producing good agreement with measurements of mean velocity, Reynolds stresses and fluxes.

210 citations


Journal ArticleDOI
TL;DR: In this paper, large-scale explosions of initially quiescent methane-air and propane-air mixtures at atmospheric pressure are reported, in which the flame speed of a hemispherical flame is measured up to radii just beyond 3 m. Theoretical expressions for flame speed are presented for both regimes.

192 citations


Journal ArticleDOI
TL;DR: In this article, the effects of obstruction geometry, blockage ratio and venting pressure on overpressures resulting from premixed flame deflagration were investigated, and it was found that the deflagation overpressure increases with increasing ventingpressure.
Abstract: This paper introduces a new experimental set-up for investigating the effects of obstruction geometry, blockage ratio and venting pressure on overpressures resulting from premixed flame deflagration. Obstructions shaped as cylinders, triangles, squares, diamonds and plates or walls are studied here covering blockage ratios ranging from about 10% to more than 75%. It is found that the deflagration overpressure increases with increasing venting pressure. Also, the maximum overpressure increases, generally with increasing blockage ratio but the rate of increase depends on the obstruction geometry. The wall/plate type obstruction leads to the highest overpressures and the cylindrical obstruction yields the lowest overpressure. The time taken to reach the maximum overpressure decreases with increasing blockage ratio and changes with obstruction geometry implying that the flame accelerates faster due to changed local turbulence levels and length scales.

171 citations


Journal ArticleDOI
TL;DR: In this paper, a linear model has been constructed to estimate the effect of entropy waves on the thermo-acoustic response and stability of a combustor with a choked exit nozzle, as it might be found in a gas turbine.
Abstract: Thermoacoustic instabilities are a cause for concern in combustion applications as diverse as small household burners, gas turbines or rocket engines. In this work, a feedback mechanism is analyzed, which couples combustion chamber acoustics with convectively transported fluctuations of entropy (entropy waves) generated within a premixed flame. Essential elements of this thermo-acoustic feedback loop are fluctuations in fuel concentration, induced by acoustic disturbances at the location of fuel injection, convective transport of fuel inhomogeneities through the premixing section of the burner, modulations in heat release rate and hot gas entropy resulting from the consumption of fuel/air mixture with varying fuel concentration by the flame, and the generation of sound through entropy non-uniformities at the turbine inlet. From a qualitative analysis based on relative phases, it is concluded that depending on the various convective and acoustic time lags involved, entropy waves may couple constructively as well as destructively with combustor acoustics. However, such qualitative analysis does not indicate whether the coupling between entropy and acoustic waves is strong enough to significantly influence thermo-acoustic stability. Therefore, a linear model has been constructed to estimate the effect of entropy waves on the thermo-acoustic response and stability of a combustor with a choked exit nozzle, as it might be found in a gas turbine. Note that phenomena like dispersion of convective waves, distributed heat release, vortical velocities, etc., have not been taken into account, as they would burden the presentation with unnecessary complexity. Results obtained indicate that the interaction between combustor acoustics and entropy waves can be significant, especially for the lowest non-axisymmetric modes, and even at frequencies higher than those usually associated with convective waves. As expected, it was observed that the coupling between pressure and entropy waves at the exit nozzle can enhance as well as reduce the thermo-acoustic stability of a combustor, or the responsiveness to an external or internal fluid-mechanic excitation mechanism. It is concluded that comprehensive thermo-acoustic analysis of a premixed combustor with a choked exit must in general include generation and propagation of entropy waves and coupling with combustor acoustics.

169 citations


Journal ArticleDOI
TL;DR: In this paper, a chemical kinetic mechanism for the combustion of n -decane has been compiled and validated for a wide range of combustion regimes, including thermal decomposition of alkanes, H-atom abstraction, alkyl radical isomerization and β-decomposition for the high temperature range, and a few additional reactions at low temperatures.

165 citations



Journal ArticleDOI
01 Sep 2001-Fuel
TL;DR: In this paper, the authors investigated the possibility of using chemiluminescence as an active feedback control parameter to deduce the equivalence ratio, and therefore NO x production and combustion stability, for premixed flames at high pressure.

Journal ArticleDOI
TL;DR: In this article, the effects of large-scale advection through a Lagrangian volume transport scheme and small-scale turbulent stirring and flame propagation were modeled using a one-dimensional linear eddy model.
Abstract: Large Eddy Simulations (LES) of turbulent premixed flames in the flamelet regime are carried out using a new subgrid combustion model. This model explicitly incorporates the effects of large-scale advection through a Lagrangian volume transport scheme and the effects of small-scale turbulent stirring and flame propagation (subgrid effects) using a one-dimensional linear eddy model. Three-dimensional turbulent stagnation point premixed flames are simulated with the new model and a conventional flame speed model. It is seen that the conventional model implemented using a finite difference discretization of the scalar equations on a typical three-dimensional LES grid is unable to capture the flamelet nature of the stagnation premixed flames. On the other hand, the subgrid model in the new formulation provides enough fine-scale resolution to accurately capture the flamelet nature of undisturbed laminar flame propagation and small scale wrinkling of the flame surface. As a result, the intermittency associated ...

Journal ArticleDOI
TL;DR: In this paper, the authors compare the burning rate determined by two widely used experimental methods: flow-velocity measurements and scalar measurements of the flame-surface density, Σ.

Journal ArticleDOI
TL;DR: In this article, a radical-molecule reaction mechanism was used to predict the size distribution of aromatic structures formed in rich premixed flames of ethylene at atmospheric pressure with C/O ratios across the soot threshold limit.


Journal ArticleDOI
TL;DR: In this paper, experimental measurements of the adiabatic burning velocity in methane-oxygen-nitrogen mixtures were presented, where non-stretched flames were stabilized on a perforated plate burner at 1' atm.
Abstract: Experimental measurements of the adiabatic burning velocity in methane-oxygen-nitrogen mixtures are presented. Non-stretched flames were stabilized on a perforated plate burner at 1 atm. The oxygen content in the artificial air was varied from 16 percent to 21 percent. The Heat Flux method was used to determine burning velocities under conditions when the net heat loss of the flame is zero. Major attention in this work has been paid to the identification of possible uncertainties and errors of the measurements. The overall error of the burning velocities is estimated to be smaller than ± 0.8 cm/s. Experimental results are in very good agreement with recent literature data for methane-air mixtures. They also agree well with detailed chemical model predictions.

Journal ArticleDOI
TL;DR: In this paper, the evolution of flame-made titania particles from spherical to weakly agglomerated ones has been studied in a premixed flame of methane and oxygen by oxidizing titanium tetraisopropoxide vapor at various concentrations.

Journal ArticleDOI
A. Makino1
TL;DR: In this article, a review of fundamental mechanisms governing the Self-propagating High-temperature Synthesis (SHS) process, which is characterized by the flame propagation through a matrix of compacted reactive particles and is recognized to hold the practical significance in producing novel solid materials, is reviewed.


Journal ArticleDOI
TL;DR: In this paper, the effect of strain rate and scalar dissipation rate on the instantaneous local displacement speed at the triple flame edge was determined by performing direct numerical simulations of a hydrogen-air triple flame subjected to an unsteady strain field induced by a pair of counterrotating vortices.

Journal ArticleDOI
TL;DR: In this article, the authors used a particle image velocimetry system with a high-resolution video camera to clarify the mechanisms of laminar dust flame propagation in a vertical duct.
Abstract: Following our earlier study on the behavior of lycopodium dust flames, further experiments using a particle image velocimetry system with a high-resolution video camera have been conducted to clarify the mechanisms of laminar dust flame propagation in a vertical duct. Lycopodium, a nearly equal-sized particle, has been recognized as being monodispersed, but it was found that an actual lycopodium dust cloud consisted of individual and agglomerated particles. Corresponding to the particle forms, the reaction zone showed a double flame structure, consisting of enveloped diffusion flames (spot flame) of individual particles and diffusion flames (independent flame) surrounding some particles. Due to the convective flow caused by a flame, part of the gravitational settling particles was shifted to the surrounding sides and the rest of the particles changed their movements to upwards in front of the flame. Such particle movement causes a dynamic variation in dust concentration ahead of the flame, which propagates at lower dust concentration rather than the mean concentration. Although the flame moved discontinuously on a micro scale, an overall constant flame velocity was found, presumably due to the dynamic variation in dust concentration and induced flow ahead of the flame. Judging from the above-mentioned movement of single particles in front of the flame, a residence time of the unburnt particle in the preheating zone is needed to form combustible gases close to the particle. This residence time depends on the preheating zone thickness, the particle velocity and the flame propagation velocity. The observation of the movement of a single particle suggested a flame propagation mechanism where an enveloped and diffusion lycopodium dust flame discontinuously propagates from one particle to those adjacent in a laminar suspension.

Journal ArticleDOI
TL;DR: In this article, an investigation of the inhibition properties of Phosphorus-Containing Compounds (PCCs) in moderately strained (global strain rate of 300 s−1) non-premixed methane-N2/O2/Ar flames is presented.

Journal ArticleDOI
TL;DR: In this work, two numerical techniques have been applied for numerical simulation of soot formation in a laminar premixed acetylene/oxygen/argon flame and some evidence for the particle inception model employing coalescence of PAH molecules has been found.

Journal ArticleDOI
TL;DR: In this article, a simulation and comparison with standard experimental data of turbulent premixed combustion occurring at large Reynolds and moderately large Damkohler numbers (a situation which is typical in industrial burners) have been presented.
Abstract: Numerical simulation and comparison with standard experimental data of turbulent premixed combustion occurring at large Reynolds and moderately large Damkohler numbers (a situation which is typical in industrial burners) have been presented. The simulation has been performed in the framework of the Turbulent Flame-speed Closure (TFC) combustion model, developed in [1-4], which makes use of a theoretical expression for the turbulent combustion velocity for the closure of the progress variable transport equation. This model is based on the concept of the Intermediate Steady Propagation (ISP) regime of combustion in real combustors, i.e. when the turbulent flame propagates with equilibrium turbulent flame speed but has flame brush thickness growing according to the turbulent dispersion law. These ISP flames precede usually analysed 1D stationary flames, and from the theoretical point of view they are in fact intermediate asymptotic of the combustion process between the period of formation of developed turbulent flames and 1D stationary flames. Numerical results of turbulent premixed combustion in a two-dimensional planar channel at parameters that correspond to real industrial combustors have been compared with corresponding standard experimental data on a high speed turbulent premixed flame [9]. Finally, it has been explained in the framework of the TFC combustion model that "countergradient transport", i.e. the necessity to use a negative effective diffusion coefficient to describe experimental heat and progress variable fluxes inside the flame, is an inherent feature of turbulent premixed flames, and is connected with direct dependence of the second order velocity-scalars correlation on combustion. It has been shown that the existence of the countergradient transport phenomenon is not in contradiction with the actual increasing of the flame brush width.

Journal ArticleDOI
TL;DR: In this article, a focused beam from a tungsten/halogen lamp was used to ignite the center of the fuel sample while an external air flow was varied from 0 to 10 cm/s.

Journal ArticleDOI
TL;DR: In this paper, a heat flux method was used for stabilization of nonstretched flames on a perforated plate burner at 1 atm, and radial and axial profiles of the concentrations of stable species and NO in the postflame zone were used to evaluate the influence of the ambient air en-trainment.
Abstract: Probe sampling measurements of the concentrations of O2, CO2, CO, and NO in the postflame zone of the methane-air flames are reported. A heat flux method was used for stabilization of nonstretched flames on a perforated plate burner at 1 atm. Major attention in this work has been paid to the identification of possible uncertainties and errors of the measurements. Radial and axial profiles of the concentrations of stable species and NO in the postflame zone were used to evaluate the influence of the ambient air en-trainment. flame expansion, and downstream heat losses. In the core region of the flames, the radial profiles of the major species and NO are flat from moderately lean to moderately rich mixtures. In the very lean mixtures an ambient air dilutes the burnt gases, while in the very rich mixtures it causes oxidation of the combustion products. The buoyancy and radial flame expansion can significantly modify observed concentration gradients in the postflame region. In the methane-air mixtures, the NO...

Journal ArticleDOI
TL;DR: In this paper, the results of a theoretical study of the interactions between a laminar, premixed flame front and a plane acoustic wave are presented. But the results are limited to the case of planar flames.
Abstract: This paper presents the results of a theoretical study of the interactions between a laminar, premixed flame front and a plane acoustic wave. Its objective is to elucidate the processes that damp or drive acoustic waves as they interact with flames. Using linear analysis, the characteristics of the acoustic field, the flame's movement and wrinkling in response to acoustic perturbations, and the acoustic energy that is produced or dissipated at the flame are calculated. These calculations show that the net acoustic energy flux out of the flame is controlled by competing acoustic energy production and dissipation processes. Energy is added to the acoustic field by unsteady heat release processes resulting from the unsteady flux of unburned reactants through the flame by fluctuations in the flame speed or density of the unburned reactants. Energy is dissipated by the transfer of acoustic energy into fluctuations in vorticity that are generated at the flame front because of the misaligned fluctuating pressure and mean density gradients (i.e. the baroclinic vorticity production mechanism). The paper concludes by showing how these results can be generalized to determine the response of planar flames to an arbitrarily complex acoustic field. The principal contribution of this work is its demonstration that the excitation of vorticity and fluctuations in the flame speed have significant qualitative and quantitative affects on the interactions between flames and acoustic waves.

Journal ArticleDOI
TL;DR: In this paper, a non-premixed lifted jet flame is studied dynamically in the hysteresis zone and the role of streamwise vortices in the stabilization mechanism of the lifted flame is confirmed by measurements obtained with a disordered jet from a straight tube burner.
Abstract: A nonpremixed lifted jet flame is studied dynamically in the hysteresis zone. High-speed laser tomography images show clearly that, in the case of an organized jet, the flame is located on streamwise counter-rotating vortex filaments generated to secondary instabilities and ejected towards ambient air. Particle image velocimetry is used to evaluate the amplitude of the translational and rotational velocity of these filaments. The use of an acoustic field to force jet instabilities shows that the flame, following large filament ejections, moves back upstream very close to the nozzle without anchoring at it. The role of streamwise vortices in the stabilization mechanism of the lifted flame is confirmed by measurements obtained with a disordered jet, from a straight tube burner. From these results, it is proposed that secondary vortices at the flame base are sufficiently strong to create a premixed zone and to oppose flame propagation.

Journal ArticleDOI
TL;DR: In this article, a detailed kinetic reaction mechanism was proposed for the oxidation of benzene in a jet-stirred reactor at high temperature (950-1350 K) at atmospheric pressure and variable equivalence ratio (0·3≤ 0 ≤ 1·5).
Abstract: New experimental results have been obtained for the oxidation of benzene in a jet-stirred reactor at high temperature (950–1350 K) at atmospheric pressure and variable equivalence ratio (0·3≤ 0 ≤1·5). Molecular species concentration profiles of reactants, stable intermediates and final products were obtained by probe sampling followed by on-line and off-line GC analyses. The oxidation of benzene in these conditions was modeled using a detailed kinetic reaction mechanism (120 species and 921 reactions, most of them reversible). The proposed mechanism was also used to simulate the oxidation of benzene at low pressure (0·46 atm) and high pressure in stirred reactor conditions. The burning velocities of benzene-air mixtures were well-predicted by the proposed kinetic scheme that was also used to simulate the MBMS results of Bittner and Howard obtained for a fuel-rich benzene-oxygen-argon premixed flame. The ignition delays of benzene-oxygen-argon mixtures measured by Burcat over the range of equivalence ratio...