Showing papers on "Semiclassical physics published in 2021"

Bra-ket wormholes in gravitationally prepared states

Abstract: We consider two dimensional CFT states that are produced by a gravitational path integral. As a first case, we consider a state produced by Euclidean AdS2 evolution followed by flat space evolution. We use the fine grained entropy formula to explore the nature of the state. We find that the naive hyperbolic space geometry leads to a paradox. This is solved if we include a geometry that connects the bra with the ket, a bra-ket wormhole. The semiclassical Lorentzian interpretation leads to CFT state entangled with an expanding and collapsing Friedmann cosmology. As a second case, we consider a state produced by Lorentzian dS2 evolution, again followed by flat space evolution. The most naive geometry also leads to a similar paradox. We explore several possible bra-ket wormholes. The most obvious one leads to a badly divergent temperature. The most promising one also leads to a divergent temperature but by making a projection onto low energy states we find that it has features that look similar to the previous Euclidean case. In particular, the maximum entropy of an interval in the future is set by the de Sitter entropy.

BCFT entanglement entropy at large central charge and the black hole interior

Abstract: In this note, we consider entanglement and Renyi entropies for spatial subsystems of a boundary conformal field theory (BCFT) or of a CFT in a state constructed using a Euclidean BCFT path integral. Holographic calculations suggest that these entropies undergo phase transitions as a function of time or parameters describing the subsystem; these arise from a change in topology of the RT surface. In recent applications to black hole physics, such transitions have been seen to govern whether or not the bulk entanglement wedge of a (B)CFT region includes a portion of the black hole interior and have played a crucial role in understanding the semiclassical origin of the Page curve for evaporating black holes. In this paper, we reproduce these holographic results via direct (B)CFT calculations. Using the replica method, the entropies are related to correlation functions of twist operators in a Euclidean BCFT. These correlations functions can be expanded in various channels involving intermediate bulk or boundary operators. Under certain sparseness conditions on the spectrum and OPE coefficients of bulk and boundary operators, we show that the twist correlators are dominated by the vacuum block in a single channel, with the relevant channel depending on the position of the twists. These transitions between channels lead to the holographically observed phase transitions in entropies.

Information paradox and its resolution in de Sitter holography

Abstract: We formulate a version of the information paradox in de Sitter spacetime and show that it is solved by the emergence of entanglement islands in the context of the De Sitter/de Sitter correspondence; in particular, the entanglement entropy of a subregion obeys a time-dependent Page curve. Our construction works in general spacetime dimensions and keeps the graviton massless. We interpret the resulting behavior of the entanglement entropy using double holography. It suggests that the spatial distribution of microscopic degrees of freedom depends on descriptions, as in the case of a black hole. In the static (distant) description of de Sitter (black hole) spacetime, these degrees of freedom represent microstates associated with the Gibbons-Hawking (Bekenstein-Hawking) entropy and are localized toward the horizon. On the other hand, in a global (effective two-sided) description, which is obtained by the quantum analog of analytic extension and is intrinsically semiclassical, they are distributed uniformly and in a unique semiclassical de Sitter (black hole) vacuum state.

Quasiparticle dynamics of symmetry-resolved entanglement after a quench: Examples of conformal field theories and free fermions

Abstract: The time evolution of the entanglement entropy is a key concept to understand the structure of a nonequilibrium quantum state. In a large class of models, such evolution can be understood in terms of a semiclassical picture of moving quasiparticles spreading the entanglement throughout the system. However, it is not yet known how the entanglement splits between the sectors of an internal local symmetry of a quantum many-body system. Here, guided by the examples of conformal field theories and free-fermion chains, we show that the quasiparticle picture can be adapted to this goal, leading to a general conjecture for the charged entropies whose Fourier transform gives the desired symmetry-resolved entanglement ${S}_{n}(q)$. We point out two physically relevant effects that should be easily observed in atomic experiments: a delay time for the onset of ${S}_{n}(q)$ which grows linearly with $|\mathrm{\ensuremath{\Delta}}q|$ (the difference between the charge $q$ and its mean value) and an effective equipartition when $|\mathrm{\ensuremath{\Delta}}q|$ is much smaller than the subsystem size.

Cosmological singularities, entanglement and quantum extremal surfaces

Abstract: We study aspects of entanglement and extremal surfaces in various families of spacetimes exhibiting cosmological, Big-Crunch, singularities, in particular isotropic AdS Kasner. The classical extremal surface dips into the bulk radial and time directions. Explicitly analysing the extremization equations in the semiclassical region far from the singularity, we find the surface bends in the direction away from the singularity. In the 2-dim cosmologies obtained by dimensional reduction of these and other singularities, we have studied quantum extremal surfaces by extremizing the generalized entropy. The resulting extremization shows the quantum extremal surfaces to always be driven to the semiclassical region far from the singularity. We give some comments and speculations on our analysis.

Path integral optimization from Hartle-Hawking wave function

Abstract: We propose a gravity dual description of the path integral optimization in conformal field theories [Caputa et al., Phys. Rev. Lett. 119, 071602 (2017)], using Hartle-Hawking wave functions in anti--de Sitter spacetime. We show that the maximization of the Hartle-Hawking wave function is equivalent to the path integral optimization procedure. Namely, the variation of the wave function leads to a constraint, equivalent to the Neumann boundary condition on a bulk slice, whose classical solutions reproduce metrics from the path integral optimization in conformal field theories. After taking the boundary limit of the semiclassical Hartle-Hawking wave function, we reproduce the path integral complexity action in two dimensions, as well as its higher- and lower-dimensional generalizations. We also discuss an emergence of holographic time from conformal field theory path integrals.

WKB Estimate of Bilayer Graphene's Magic Twist Angles

Abstract: Graphene bilayers exhibit zero-energy flatbands at a discrete series of magic twist angles In the absence of intrasublattice interlayer hopping, zero-energy states satisfy a Dirac equation with a non-Abelian SU(2) gauge potential that cannot be diagonalized globally We develop a semiclassical WKB approximation scheme for this Dirac equation by introducing a dimensionless Planck's constant proportional to the twist angle, solving the linearized Dirac equation around AB and BA turning points, and connecting Airy function solutions via bulk WKB wave functions We find zero-energy solutions at a discrete set of values of the dimensionless Planck's constant, which we obtain analytically Our analytic flatband twist angles correspond closely to those determined numerically in previous work

Quantum simulation of open quantum systems in heavy-ion collisions

Abstract: We present a framework to simulate the dynamics of hard probes such as heavy quarks or jets in a hot, strongly coupled quark-gluon plasma (QGP) on a quantum computer. Hard probes in the QGP can be treated as open quantum systems governed in the Markovian limit by the Lindblad equation. However, due to large computational costs, most current phenomenological calculations of hard probes evolving in the QGP use semiclassical approximations of the quantum evolution. Quantum computation can mitigate these costs and offers the potential for a fully quantum treatment with exponential speed-up over classical techniques. We report a simplified demonstration of our framework on IBM Q quantum devices and apply the random identity insertion method to account for cnot depolarization noise, in addition to measurement error mitigation. Our work demonstrates the feasibility of simulating open quantum systems on current and near-term quantum devices, which is of broad relevance to applications in nuclear physics, quantum information, and other fields.

Introduction to Quantum Field Theory with Applications to Quantum Gravity

Abstract: Applications of quantum field theoretical methods to gravitational physics, both in the semiclassical and the full quantum frameworks, require a careful formulation of the fundamental basis of quantum theory, with special attention to such important issues as renormalization, quantum theory of gauge theories, and especially effective action formalism. The first part of this graduate textbook provides both a conceptual and technical introduction to the theory of quantum fields. The presentation is consistent, starting from elements of group theory, classical fields, and moving on to the effective action formalism in general gauge theories. Compared to other existing books, the general formalism of renormalization in described in more detail, and special attention paid to gauge theories. This part can serve as a textbook for a one-semester introductory course in quantum field theory. In the second part, we discuss basic aspects of quantum field theory in curved space, and perturbative quantum gravity. More than half of Part II is written with a full exposition of details, and includes elaborated examples of simplest calculations. All chapters include exercises ranging from very simple ones to those requiring small original investigations. The selection of material of the second part is done using the “must-know” principle. This means we included detailed expositions of relatively simple techniques and calculations, expecting that the interested reader will be able to learn more advanced issues independently after working through the basic material, and completing the exercises.

Introduction to theory of high-harmonic generation in solids: tutorial

Abstract: High-harmonic generation (HHG) in solids has emerged in recent years as a rapidly expanding and interdisciplinary field, attracting attention from both the condensed-matter and the atomic, molecular, and optics communities. It has exciting prospects for the engineering of new light sources and the probing of ultrafast carrier dynamics in solids, and the theoretical understanding of this process is of fundamental importance. This tutorial provides a hands-on introduction to the theoretical description of the strong-field laser-matter interactions in a condensed-phase system that give rise to HHG. We provide an overview ranging from a detailed description of different approaches to calculating the microscopic dynamics and how these are intricately connected to the description of the crystal structure, through the conceptual understanding of HHG in solids as supported by the semiclassical recollision model, and finally a brief description of how to calculate the macroscopic response. We also give a general introduction to the Berry phase, and we discuss important subtleties in the modelling of HHG, such as the choice of structure and laser gauges, and the construction of a smooth and periodic structure gauge for both nondegenerate and degenerate bands. The advantages and drawback of different structure and laser-gauge choices are discussed, both in terms of their ability to address specific questions and in terms of their numerical feasibility.

Modeling nonadiabatic dynamics with degenerate electronic states, intersystem crossing, and spin separation: A key goal for chemical physics

Abstract: We examine the many open questions that arise for nonadiabatic dynamics in the presence of degenerate electronic states, e.g., for singlet-to-triplet intersystem crossing where a minimal Hamiltonian must include four states (two of which are always degenerate). In such circumstances, the standard surface hopping approach is not sufficient as the algorithm does not include Berry force. Yet, we hypothesize that such a Berry force may be crucial as far as creating chiral induced spin separation, which is now a burgeoning field of study. Thus, this Perspective highlights the fact that if one can generate a robust and accurate semiclassical approach for the case of degenerate states, one will take a big step forward toward merging chemical physics with spintronics.

Semiclassical regime for dark matter self-interactions

Abstract: Many particle physics models for dark matter self-interactions---motivated to address long-standing challenges to the collisionless cold dark matter paradigm---fall within the semiclassical regime, with interaction potentials that are long range compared to the de Broglie wavelength for dark matter particles. In this work, we present a quantum-mechanical derivation and new analytic formulas for the semiclassical momentum transfer and viscosity cross sections for self-interactions mediated by a Yukawa potential. Our results include the leading quantum corrections beyond the classical limit and allow for both distinguishable and identical dark matter particles. Our formulas supersede the well-known formulas for the momentum transfer cross section obtained from the classical scattering problem, which are often used in phenomenological studies of self-interacting dark matter. Together with previous approximation formulas for the cross section in the quantum regime, our new results allow for nearly complete analytic coverage of the parameter space for self-interactions with a Yukawa potential. We also discuss the phenomenological implications of our results and provide a new velocity-averaging procedure for constraining velocity-dependent self-interactions. Our results have been implemented in the newly released code CLASSICS.

Quantum operator growth bounds for kicked tops and semiclassical spin chains

Abstract: We present a framework for understanding the dynamics of operator size, and bounding the growth of out-of-time-ordered correlators, in models of large-$S$ spins. Focusing on the dynamics of a single spin, we show the finiteness of the Lyapunov exponent in the large-$S$ limit; our bounds are tighter than the best known Lieb-Robinson-type bounds on these systems. We numerically find our upper bound on Lyapunov exponents is within an order of magnitude of numerically computed values in classical and quantum kicked top models. Generalizing our results to coupled large-$S$ spins on lattices, we show that the butterfly velocity, which characterizes the spatial speed of quantum information scrambling, is finite as $S\ensuremath{\rightarrow}\ensuremath{\infty}$. We emphasize qualitative differences between operator growth in semiclassical large-spin models and quantum holographic systems including the Sachdev-Ye-Kitaev model.

Entanglement View of Dynamical Quantum Phase Transitions.

Abstract: The analogy between an equilibrium partition function and the return probability in many-body unitary dynamics has led to the concept of dynamical quantum phase transition (DQPT). DQPTs are defined by nonanalyticities in the return amplitude and are present in many models. In some cases, DQPTs can be related to equilibrium concepts, such as order parameters, yet their universal description is an open question. In this Letter, we provide first steps toward a classification of DQPTs by using a matrix product state description of unitary dynamics in the thermodynamic limit. This allows us to distinguish the two limiting cases of "precession" and "entanglement" DQPTs, which are illustrated using an analytical description in the quantum Ising model. While precession DQPTs are characterized by a large entanglement gap and are semiclassical in their nature, entanglement DQPTs occur near avoided crossings in the entanglement spectrum and can be distinguished by a complex pattern of nonlocal correlations. We demonstrate the existence of precession and entanglement DQPTs beyond Ising models, discuss observables that can distinguish them, and relate their interplay to complex DQPT phenomenology.

Microlocal Analysis of the Bulk-Edge Correspondence

Abstract: The bulk-edge correspondence predicts that interfaces between topological insulators support robust currents. We prove this principle for PDEs that are periodic away from an interface. Our approach relies on semiclassical methods. It suggests novel perspectives for the analysis of topologically protected transport.

Black hole interior in unitary gauge construction

Abstract: A quantum system with a black hole accommodates two widely different, though physically equivalent, descriptions. In one description, based on global spacetime of general relativity, the existence of the interior region is manifest, while understanding unitarity requires nonperturbative quantum gravity effects such as replica wormholes. The other description adopts a manifestly unitary, or holographic, description, in which the interior emerges effectively as a collective phenomenon of fundamental degrees of freedom. In this paper we study the latter approach, which we refer to as the unitary gauge construction. In this picture, the formation of a black hole is signaled by the emergence of a surface (stretched horizon) possessing special dynamical properties: quantum chaos, fast scrambling, and low energy universality. These properties allow for constructing interior operators, as we do explicitly, without relying on details of microscopic physics. A key role is played by certain coarse modes in the zone region (hard modes), which determine the degrees of freedom relevant for the emergence of the interior. We study how the interior operators can or cannot be extended in the space of microstates and analyze irreducible errors associated with such extension. This reveals an intrinsic ambiguity of semiclassical theory formulated with a finite number of degrees of freedom. We provide an explicit prescription of calculating interior correlators in the effective theory, which describes only a finite region of spacetime. We study the issue of state dependence of interior operators in detail and discuss a connection of the resulting picture with the quantum error correction interpretation of holography.

Quarkonium Semiclassical Transport in Quark-Gluon Plasma: Factorization and Quantum Correction

Abstract: We study quarkonium transport in the quark-gluon plasma by using the potential nonrelativistic QCD (pNRQCD) effective field theory and the framework of open quantum systems. We argue that the coupling between quarkonium and the thermal bath is weak using separation of scales, so the initial density matrix of the total system factorizes and the time evolution of the subsystem is Markovian. We derive the semiclassical Boltzmann equation for quarkonium by applying a Wigner transform to the Lindblad equation and carrying out a semiclassical expansion. We resum relevant interactions to all orders in the coupling constant at leading power of the nonrelativistic and multipole expansions. The derivation is valid for both weakly coupled and strongly coupled quark-gluon plasmas. We find reaction rates in the transport equation factorize into a quarkonium dipole transition function and a chromoelectric gluon distribution function. For the differential reaction rate, the definition of the momentum dependent chromoelectric gluon distribution function involves staple-shaped Wilson lines. For the inclusive reaction rate, the Wilson lines collapse into a straight line along the real time axis and the distribution becomes momentum independent. The relation between the two Wilson lines is analogous to the relation between the Wilson lines appearing in the gluon parton distribution function (PDF) and the gluon transverse momentum dependent parton distribution function (TMDPDF). The centrality dependence of the quarkonium nuclear modification factor measured by experiments probes the momentum independent distribution while the transverse momentum dependence and measurements of the azimuthal angular anisotropy may be able to probe the momentum dependent one. We discuss one way to indirectly constrain the quarkonium in-medium real potential by using the factorization formula and lattice calculations. The leading quantum correction to the semiclassical transport equation of quarkonium is also worked out. The study can be easily generalized to quarkonium transport in cold nuclear matter, which is relevant for quarkonium production in eA collisions in the future Electron-Ion Collider.

Driven-dissipative phase transition in a Kerr oscillator: From semiclassical PT symmetry to quantum fluctuations

Abstract: We study a minimal model that has a driven-dissipative quantum phase transition, namely, a Kerr nonlinear oscillator subject to driving and dissipation. Using mean-field theory, exact diagonalization, and the Keldysh formalism, we analyze the critical phenomena in this system, showing which aspects can be captured by each approach and how the approaches complement each other. Then critical scaling and finite-size scaling are calculated analytically using the quantum Langevin equation. The physics contained in this simple model is surprisingly rich: it includes a continuous phase transition, ${Z}_{2}$ symmetry breaking, $\mathcal{PT}$ symmetry, state squeezing, and critical fluctuations. Due to its simplicity and solvability, this model can serve as a paradigm for exploration of open quantum many-body physics.

Gauge invariance of transverse momentum dependent distributions at small x

Abstract: The interplay between the small-$x$ limit of QCD amplitudes and QCD factorization at moderate $x$ has been studied extensively in recent years. It was finally shown that semiclassical formulations of small-$x$ physics can have the form of an infinite twist framework involving transverse momentum dependent distributions in the eikonal limit. In this work, we demonstrate that small-$x$ distributions can be formulated in terms of transverse gauge links. This allows, in particular, for direct and efficient decompositions of observables into subamplitudes involving gauge-invariant suboperators which span parton distributions.

The two-sphere partition function in two-dimensional quantum gravity

Abstract: We study the Euclidean path integral of two-dimensional quantum gravity with positive cosmological constant coupled to conformal matter with large and positive central charge. The problem is considered in a semiclassical expansion about a round two-sphere saddle. We work in the Weyl gauge whereby the computation reduces to that for a (timelike) Liouville theory. We present results up to two-loops, including a discussion of contributions stemming from the gauge fixing procedure. We exhibit cancelations of ultraviolet divergences and provide a path integral computation of the central charge for timelike Liouville theory. Combining our analysis with insights from the DOZZ formula we are led to a proposal for an all orders result for the two-dimensional gravitational partition function on the two-sphere.

Quantum Optimal Transport with Quantum Channels

Abstract: We propose a new generalization to quantum states of the Wasserstein distance, which is a fundamental distance between probability distributions given by the minimization of a transport cost. Our proposal is the first where the transport plans between quantum states are in natural correspondence with quantum channels, such that the transport can be interpreted as a physical operation on the system. Our main result is the proof of a modified triangle inequality for our transport distance. We also prove that the distance between a quantum state and itself is intimately connected with the Wigner-Yanase metric on the manifold of quantum states. We then specialize to quantum Gaussian systems, which provide the mathematical model for the electromagnetic radiation in the quantum regime. We prove that the noiseless quantum Gaussian attenuators and amplifiers are the optimal transport plans between thermal quantum Gaussian states, and that our distance recovers the classical Wasserstein distance in the semiclassical limit.

The mixed $0$-form/$1$-form anomaly in Hilbert space: pouring new wine into old bottles

Abstract: We study four-dimensional gauge theories with arbitrary simple gauge group with $1$-form global center symmetry and $0$-form parity or discrete chiral symmetry. We canonically quantize on $\mathbb{T}^3$, in a fixed background field gauging the $1$-form symmetry. We show that the mixed $0$-form/$1$-form 't Hooft anomaly results in a central extension of the global-symmetry operator algebra. We determine this algebra in each case and show that the anomaly implies degeneracies in the spectrum of the Hamiltonian at any finite-size torus. We discuss the consistency of these constraints with both older and recent semiclassical calculations in $SU(N)$ theories, with or without adjoint fermions, as well as with their conjectured infrared phases.

Intrinsic Anomalous Hall Conductivity in a Nonuniform Electric Field.

Abstract: We study how the intrinsic anomalous Hall conductivity is modified in two-dimensional crystals with broken time-reversal symmetry due to weak inhomogeneity of the applied electric field. Focusing on a clean noninteracting two-band system without band crossings, we derive the general expression for the Hall conductivity at small finite wave vector q to order q^{2}, which governs the Hall response to the second gradient of the electric field. Using the Kubo formula, we show that the answer can be expressed through the Berry curvature, Fubini-Study quantum metric, and the rank-3 symmetric tensor which is related to the quantum geometric connection and physically corresponds to the gauge-invariant part of the third cumulant of the position operator. We further compare our results with the predictions made within the semiclassical approach. By deriving the semiclassical equations of motion, we reproduce the result obtained from the Kubo formula in some limits. We also find, however, that the conventional semiclassical description in terms of the definite position and momentum of the electron is not fully consistent because of singular terms originating from the Heisenberg uncertainty principle. We thus present a clear example of a case when the semiclassical approach inherently suffers from the uncertainty principle, implying that it should be applied to systems in nonuniform fields with extra care.

Dissipative phase transitions in the fully connected Ising model with p -spin interaction

Abstract: In this paper, we study the driven-dissipative $p$-spin models for $p\ensuremath{\ge}2$. In thermodynamic limit, the equation of motion is derived by using a semiclassical approach. The long-time asymptotic states are obtained analytically, which exhibit multistability in some regions of the parameter space. The steady state is unique as the number of spins is finite. But the thermodynamic limit of the steady-state magnetization displays nonanalytic behavior somewhere inside the semiclassical multistable region. We find both the first-order and continuous dissipative phase transitions. As the number of spins increases, both the Liouvillian gap and magnetization variance vanish according to a power law at the continuous transition. At the first-order transition, the gap vanishes exponentially accompanied by a jump of magnetization in thermodynamic limit. The properties of transitions depend on the symmetry and semiclassical multistability, being qualitatively different among $p=2$, odd $p$ $(p\ensuremath{\ge}3)$, and even $p$ $(p\ensuremath{\ge}4)$.

Cosmological consequences of a principle of finite amplitudes

Abstract: Over 30 years ago, Barrow and Tipler proposed the principle according to which the action integrated over the entire four-manifold describing the universe should be finite. Here we explore the cosmological consequences of a related criterion, namely, that semiclassical transition amplitudes from the early universe up to current field values should be well defined. On a classical level, our criterion is weaker than the Barrow-Tipler principle, but it has the advantage of being sensitive to quantum effects. We find significant consequences for early universe models, in particular, eternal inflation and strictly cyclic universes are ruled out. Within general relativity, the first phase of evolution cannot be inflationary, and it can be ekpyrotic only if the scalar field potential is trustworthy over an infinite field range. Quadratic gravity eliminates all nonaccelerating backgrounds near a putative big bang (thus imposing favorable initial conditions for inflation), while the expected infinite series of higher-curvature quantum corrections eliminates Lorentzian big bang spacetimes altogether. The scenarios that work best with the principle of finite amplitudes are the no-boundary proposal, which gives finite amplitudes in all dynamical theories that we have studied, and string-inspired loitering phases. We also comment on the relationship of our proposal to the swampland conjectures.

Linking the Singularities of Cosmological Correlators

Abstract: Much of the structure of cosmological correlators is controlled by their singularities, which in turn are fixed in terms of flat-space scattering amplitudes. An important challenge is to interpolate between the singular limits to determine the full correlators at arbitrary kinematics. This is particularly relevant because the singularities of correlators are not directly observable, but can only be accessed by analytic continuation. In this paper, we study rational correlators, including those of gauge fields, gravitons, and the inflaton, whose only singularities at tree level are poles and whose behavior away from these poles is strongly constrained by unitarity and locality. We describe how unitarity translates into a set of cutting rules that consistent correlators must satisfy, and explain how this can be used to bootstrap correlators given information about their singularities. We also derive recursion relations that allow the iterative construction of more complicated correlators from simpler building blocks. In flat space, all energy singularities are simple poles, so that the combination of unitarity constraints and recursion relations provides an efficient way to bootstrap the full correlators. In many cases, these flat-space correlators can then be transformed into their more complex de Sitter counterparts. As an example of this procedure, we derive the correlator associated to graviton Compton scattering in de Sitter space, though the methods are much more widely applicable.

On the assumptions leading to the information loss paradox

Abstract: The information loss paradox is usually stated as an incompatibility between general relativity and quantum mechanics. However, the assumptions leading to the problem are often overlooked and, in fact, a careful inspection of the main hypothesises suggests a radical reformulation of the problem. Indeed, we present a thought experiment involving a black hole that emits radiation and, independently of the nature of the radiation, we show the existence of an incompatibility between (i) the validity of the laws of general relativity to describe infalling matter far from the Planckian regime, and (ii) the so-called central dogma which states that as seen from an outside observer a black hole behaves like a quantum system whose number of degrees of freedom is proportional to the horizon area. We critically revise the standard arguments in support of the central dogma, and argue that they cannot hold true unless some new physics is invoked even before reaching Planck scales. This suggests that the information loss problem, in its current formulation, is not necessarily related to any loss of information or lack of unitarity. Therefore, in principle, semiclassical general relativity and quantum mechanics can be perfectly compatible before reaching the final stage of the black hole evaporation where, instead, a consistent theory of quantum gravity is needed to make any prediction.

Ab initio semiclassical evaluation of vibrationally resolved electronic spectra with thawed Gaussians

Abstract: Vibrationally resolved electronic spectra of polyatomic molecules provide valuable information about the quantum properties of both electrons and nuclei. This chapter reviews the recent progress in ab initio semiclassical calculations of such spectra, based on the thawed Gaussian approximation and its extensions. After reviewing molecular quantum dynamics induced by the interaction with electromagnetic field and the most common semiclassical approximations to quantum dynamics, we explain details of the thawed Gaussian approximation and its variants. Next, we discuss the time-dependent approach to steady-state and time-resolved electronic spectroscopy, and review several standard models that facilitate interpreting vibrationally resolved electronic spectra. Finally, we present the on-the-fly ab initio implementation of the thawed Gaussian approximation and provide several examples of both linear and pump–probe spectra computed with this methodology, which, at a low additional cost and without sacrificing the ease of interpretation, outperforms the standard global harmonic approaches.

Fermi's Golden Rule for Spontaneous Emission in Absorptive and Amplifying Media.

Abstract: We demonstrate a fundamental breakdown of the photonic spontaneous emission (SE) formula derived from Fermi's golden rule, in absorptive and amplifying media, where one assumes the SE rate scales with the local photon density of states, an approach often used in more complex, semiclassical nanophotonics simulations. Using a rigorous quantization of the macroscopic Maxwell equations in the presence of arbitrary linear media, we derive a corrected Fermi's golden rule and master equation for a quantum two-level system (TLS) that yields a quantum pumping term and a modified decay rate that is net positive. We show rigorous numerical results of the temporal dynamics of the TLS for an example of two coupled microdisk resonators, forming a gain-loss medium, and demonstrate the clear failure of the commonly adopted formulas based solely on the local density of states.