Institution
Jan Długosz University
Education•Częstochowa, Poland•
About: Jan Długosz University is a education organization based out in Częstochowa, Poland. It is known for research contribution in the topics: Crystal structure & Luminescence. The organization has 749 authors who have published 2311 publications receiving 19395 citations. The organization is also known as: Higher Teacher Education School.
Papers published on a yearly basis
Papers
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TL;DR: The observed increase of malondialdehyde (MDA) concentration and changes in the H2O2 level indicated presence of oxidative stress in spring barley and common radish, which usually led to the increase of superoxide dismutase (SOD), catalase (CAT) and peroxidase (POD) activity.
22 citations
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TL;DR: In this paper, the authors performed band structure calculations in generalized gradient and local density approximations and allowed to determine the composition and structure of the valence and conduction bands of Na 2 Mo 2 O 7 single crystals.
22 citations
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TL;DR: In this paper, the energy levels of the Mn4+ ion (3d3 configuration) were calculated for all available sites in the lattice and the results compared with the experimental spectroscopic data.
22 citations
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TL;DR: The examined ILs demonstrated low toxicity to higher plants, and the compound that exhibited higher phytotoxicity to these plant species was [BenzTMA][Cl], whereas the plant that was more resistant to such ILs was common radish.
Abstract: The harmful effect of ionic liquids (ILs) on the environment is one of the important elements of scientific research conducted around the world. This study presents the effect of ionic liquids, containing the asymmetric cations benzyltrimethylammonium chloride [BenzTMA][Cl] and benzyltriethylammonium chloride [BenzTEA][Cl], on physiological and biochemical changes in common radish plants and spring barley seedlings. The examined ILs demonstrated low toxicity to higher plants. The compound that exhibited higher phytotoxicity to these plant species was [BenzTMA][Cl], whereas the plant that was more resistant to such ILs was common radish. Both the ionic liquids, particularly at higher concentrations, led to changes in the metabolism of plants, which resulted in a decrease of chlorophyll a, chlorophyll b, total chlorophyll, and carotenoids content. The observed changes were positively correlated with increasing concentrations of the examined ILs in the soil. In the case of spring barley, a decrease in the fr...
22 citations
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TL;DR: The theoretical calculations reveal an indirect band gap for Tl3PbI5, which indicates a strong influence of the electron-phonon interaction on the observed optoelectronic features.
Abstract: A novel Tl3PbI5 crystal has been studied both experimentally and theoretically. Complex measurements of the X-ray photoelectron core-level and valence-band spectra for the pristine and Ar+-ion irradiated surfaces of a Tl3PbI5 single crystal grown by the Bridgman–Stockbarger method were performed in order to clarify their principal properties (charge carriers mobility, effective inter-band distances, effective absorption etc.) relevant for optoelectronic applications. The principal role of two heavy cations – Tl and Pb – is explored. The X-ray photoelectron spectroscopy results reveal a high chemical stability of the Tl3PbI5 single crystal surface which makes it very promising for technological applications. Theoretical band-structure calculations for the Tl3PbI5 compound reveal that the I 5p states dominate in the top of the valence band and play a crucial role in the formation of the optical features and charge carrier mobility. The bottom of the Tl3PbI5 valence band is formed mainly by the admixture of Tl 6s and Pb 6s states, while the unoccupied Pb 6p and Tl 6p states dominate at the bottom of the conduction band. The band energy dispersion related to effective masses and the charge carrier mobility is studied in detail. Crucially, the theoretical calculations reveal an indirect band gap for Tl3PbI5, which indicates a strong influence of the electron–phonon interaction on the observed optoelectronic features. The temperature measurements of the fundamental absorption have shown that the band energy gap of Tl3PbI5 increases from 2.29 to 2.39 eV when the temperature changes from 300 to 100 K.
22 citations
Authors
Showing all 755 results
Name | H-index | Papers | Citations |
---|---|---|---|
Mikhail G. Brik | 48 | 408 | 9470 |
I.V. Kityk | 37 | 288 | 5211 |
I.V. Kityk | 37 | 287 | 5579 |
Marek Kowalczuk | 36 | 191 | 4128 |
Joanna Wietrzyk | 35 | 367 | 4804 |
Aleksander Sieroń | 33 | 292 | 4462 |
Lesław Juszczak | 33 | 104 | 2947 |
Józef Drabowicz | 31 | 277 | 3416 |
Keshra Sangwal | 30 | 177 | 4053 |
Oleh Shpotyuk | 29 | 295 | 3471 |
Adam Opolski | 29 | 92 | 2278 |
Piotr Dobrzyński | 27 | 129 | 2286 |
Piotr Kurcok | 25 | 76 | 1794 |
Jaroslaw Krzywanski | 25 | 77 | 1229 |
Malgorzata Makowska-Janusik | 24 | 105 | 1786 |