SRI International

About: SRI International is a nonprofit organization based out in Menlo Park, California, United States. It is known for research contribution in the topics: Ionosphere & Laser. The organization has 7222 authors who have published 13102 publications receiving 660724 citations. The organization is also known as: Stanford Research Institute & SRI.

Steady‐State Passive Films Interfacial Kinetic Effects and Diagnostic Criteria

Abstract: This paper reports that the point defect model for steady-state passive films formed anodically on metal s in aqueous environments has been extended to include irreversible dissolution of the film and the irreversible generation and annihilation of cation and oxygen vacancies at the metal/film and film/solution interfaces. THe model yields a number of diagnostic criteria that can be used to identify the majority (vacancy) charge carrier and to characterize the kinetic nature of the interfacial vacancy generation and annihilation processes. We use these criteria to show that the steady-state passive film that forms on nickel in acidic phosphate buffer solutions is a cation conductor and that cation transport from the metal to the solution involves irreversible ejection of cations from the film. On the other hand, the passive film that forms on tungsten in the same environment under steady-state conditions is found to be an oxygen ion conductor with the passive current being determined by kinetically controlled film dissolution at the film/solution interface. These different behaviors are rationalized in terms of the relative energies for generation of cation and anion vacancies in the passive films.

Discrete Dynamic Programming and Capital Allocation

Abstract: Dynamic programming algorithms are developed for optimal capital allocation subject to budget constraints. We extend the work of Weingartner [Weingartner, H. M. 1966. Capital budgeting of interrelated projects: Survey and synthesis. Management Sci.127, March 485--516.] and Weingartner and Ness [Weingartner, H. M., D. N. Ness. 1967. Methods for the solution of the multi-dimensional 0/1 knapsack problem. Oper. Res.151, January--February 83--108.] by including multilevel projects, reinvesting returns, borrowing and lending, capital deferrals, and project interactions. We are able to handle dynamic programming models with several state variables because the optimal returns are monotone non-decreasing step functions. Computational experience with a variety of problems is reported.