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Showing papers in "Advances in Materials Science and Engineering in 2016"


Journal ArticleDOI
TL;DR: In this article, the most extensively studied nanomaterials, including zero-valent metal nanoparticles (Ag, Fe, and Zn), metal oxide nanoparticles(TiO2, ZnO, and iron oxides), carbon nanotubes (CNTs), and nanocomposites are discussed and highlighted in detail.
Abstract: Due to the exceptional characteristics which resulted from nanoscale size, such as improved catalysis and adsorption properties as well as high reactivity, nanomaterials have been the subject of active research and development worldwide in recent years. Numerous studies have shown that nanomaterials can effectively remove various pollutants in water and thus have been successfully applied in water and wastewater treatment. In this paper, the most extensively studied nanomaterials, zero-valent metal nanoparticles (Ag, Fe, and Zn), metal oxide nanoparticles (TiO2, ZnO, and iron oxides), carbon nanotubes (CNTs), and nanocomposites are discussed and highlighted in detail. Besides, future aspects of nanomaterials in water and wastewater treatment are discussed.

246 citations


Journal ArticleDOI
TL;DR: In this paper, the authors present a review of fatigue life prediction techniques for metallic materials, including linear damage rule (LDR)-based, multiaxial and variable amplitude loading, stochastic-based, energy-based and continuum damage mechanics methods.
Abstract: Metallic materials are extensively used in engineering structures and fatigue failure is one of the most common failure modes of metal structures. Fatigue phenomena occur when a material is subjected to fluctuating stresses and strains, which lead to failure due to damage accumulation. Different methods, including the Palmgren-Miner linear damage rule- (LDR-) based, multiaxial and variable amplitude loading, stochastic-based, energy-based, and continuum damage mechanics methods, forecast fatigue life. This paper reviews fatigue life prediction techniques for metallic materials. An ideal fatigue life prediction model should include the main features of those already established methods, and its implementation in simulation systems could help engineers and scientists in different applications. In conclusion, LDR-based, multiaxial and variable amplitude loading, stochastic-based, continuum damage mechanics, and energy-based methods are easy, realistic, microstructure dependent, well timed, and damage connected, respectively, for the ideal prediction model.

185 citations


Journal ArticleDOI
TL;DR: A comparison of the prediction results obtained using both the models is presented and it can be inferred that the ANN model with the training function Levenberg-Marquardt (LM) for the prediction of concrete compressive strength is the best prediction tool.
Abstract: An effort has been made to develop concrete compressive strength prediction models with the help of two emerging data mining techniques, namely, Artificial Neural Networks (ANNs) and Genetic Programming (GP). The data for analysis and model development was collected at 28-, 56-, and 91-day curing periods through experiments conducted in the laboratory under standard controlled conditions. The developed models have also been tested on in situ concrete data taken from literature. A comparison of the prediction results obtained using both the models is presented and it can be inferred that the ANN model with the training function Levenberg-Marquardt (LM) for the prediction of concrete compressive strength is the best prediction tool.

129 citations


Journal ArticleDOI
TL;DR: In this paper, apple extract was used as reducing agent and aqueous silver nitrate as the precursor for the formation of AgNPs, and the results showed that the AgNP formation was observed as a color change from colorless to dark-brownish.
Abstract: Silver nanoparticles (AgNPs) were synthesized using apple extract as a reducing agent and aqueous silver nitrate as the precursor. The AgNPs formation was observed as a color change of the mixture from colorless to dark-brownish. The X-ray diffraction pattern confirmed the presence of only Ag crystallites, and the dynamic light scattering estimates the average sizes of the AgNPs to be 30.25 ± 5.26 nm. Furthermore, Fourier Transform Infrared as well as UV-vis spectroscopy identifies ethylene groups as the reducing agent and capping agent for the formation of the AgNPs. This green synthesis provides an economic, eco-friendly, and clean synthesis route to AgNPs. AgNPs in suspension showed activity against Gram-negative and Gram-positive bacteria with minimum bactericidal concentrations (MBCs) to be in the range from 125 μg/mL to 1000 μg/mL.

104 citations


Journal ArticleDOI
TL;DR: In this article, the effects of different nanosilica dosages (0.5, 1, and 1.5% with respect to cement) on compressive strength and durability properties of concrete with water/binder ratios 0.65, 0.55, and 0.5 were investigated.
Abstract: The effects of the addition of different nanosilica dosages (0.5%, 1%, and 1.5% with respect to cement) on compressive strength and durability properties of concrete with water/binder ratios 0.65, 0.55, and 0.5 were investigated. Water sorptivity, apparent chloride diffusion coefficient, electrical resistivity, and carbonation coefficient of concrete were measured. The results showed that compressive strength significantly improved in case of water/binder = 0.65, while for water/binder = 0.5 no change was found. Increasing nanosilica content, the water sorptivity decreased only for water/binder = 0.55. The addition of 0.5% nanosilica decreased the apparent chloride diffusion coefficient for water/binder = 0.65 and 0.55; however, higher nanosilica dosages did not decrease it with respect to reference value. The resistivity was elevated by 0.5% nanosilica for all water/binder ratios and by 1.5% nanosilica only for water/binder = 0.5. The carbonation coefficient was not notably affected by increasing nanosilica dosages and even adverse effect was observed for water/binder = 0.65. Further information of microstructure was also provided through characterization techniques such as X-ray diffraction, thermal gravimetric analysis, mercury intrusion porosimetry, and scanning electron microscopy. The effectiveness of a certain nanosilica dosage addition into lower strength mixes was more noticeable, while, for the higher strength mix, the effectiveness was less.

95 citations


Journal ArticleDOI
TL;DR: An overview of recent research and development related to NiTi-based shape memory alloys is presented in this article, where applications and uses of NiTi based shape memory materials as biomaterials are discussed.
Abstract: Shape memory alloys remember their shape due to thermoelastic martensitic phase transformation. These alloys have advantages in terms of large recoverable strain and these alloys can exert continuous force during use. Equiatomic NiTi, also known as nitinol, has a great potential for use as a biomaterial as compared to other conventional materials due to its shape memory and superelastic properties. In this paper, an overview of recent research and development related to NiTi based shape memory alloys is presented. Applications and uses of NiTi based shape memory alloys as biomaterials are discussed. Biocompatibility issues of nitinol and researchers’ approach to overcome this problem are also briefly discussed.

90 citations


Journal ArticleDOI
TL;DR: In this article, the effect of Si/P molar ratio on the geopolymers properties was studied using XRD, IR spectroscopy, and SEM, and it was shown that when the Si/p molar ratios decreases, the amorphous phase content increases.
Abstract: New three-dimensional geopolymer materials based on illito-kaolinitic clay and phosphoric acid were synthesized. The effect of Si/P molar ratio on the geopolymers properties was studied. Raw, calcined clay, and geopolymers structures were investigated using XRD, IR spectroscopy, and SEM. The phosphoric acid-based geopolymers mechanical properties were evaluated by measuring the compressive strength. The Si/P molar ratio was found to increase with the increase of the compressive strength of the obtained geopolymers, which attained a maximum value at Si/P equal to 2.75. Beyond this ratio, the mechanical strength decreases. The XRD patterns of these geopolymers samples have proven that when the Si/P molar ratio decreases, the amorphous phase content increases. Besides, the structural analyses have revealed the presence of aluminum phosphate and Si-O-Al-O-P polymeric structure, whatever the Si/P molar ratio is (between 2.25 and 3.5). The obtained results have confirmed that the presence of the associated minerals such as hematite and quartz in the clay does not prevent the geopolymerization reaction, but the presence of illite mineral seems to have a modest contribution in the geopolymerization.

83 citations


Journal ArticleDOI
TL;DR: In this article, a reformulated Arrhenius equation was proposed from the smooth exponential behavior of DC conductivity versus dielectric constant at different temperatures, and the relaxation processes have been interpreted in terms of Argand plots.
Abstract: Solid and nanocomposite polymer electrolytes based on chitosan have been prepared by solution cast technique. The XRD results reveal the occurrence of complexation between chitosan (CS) and the LiTf salt. The deconvolution of the diffractogram of nanocomposite solid polymer electrolytes demonstrates the increase of amorphous domain with increasing alumina content up to 4 wt.%. Further incorporation of alumina nanoparticles (6 to 10 wt.% Al2O3) results in crystallinity increase (large crystallite size). The morphological (SEM and EDX) analysis well supported the XRD results. Similar trends of DC conductivity and dielectric constant with Al2O3 concentration were explained. The TEM images were used to explain the phenomena of space charge and blocking effects. The reformulated Arrhenius equation () was proposed from the smooth exponential behavior of DC conductivity versus dielectric constant at different temperatures. The more linear behavior of DC conductivity versus reveals the crucial role of dielectric constant in Arrhenius equation. The drawbacks of Arrhenius equation can be understood from the less linear behavior of DC conductivity versus . The relaxation processes have been interpreted in terms of Argand plots.

80 citations


Journal ArticleDOI
TL;DR: In this article, a magnetorheological material is prepared by dispersing soft magnetic particles into Silly Putty matrix with shear stiffening property, and the experimental results indicate that the external magnetic field exerts significant influence on the creep and relaxation behaviors.
Abstract: A novel magnetorheological material defined as magnetorheological Silly Putty (MRSP) is prepared by dispersing soft magnetic particles into Silly Putty matrix with shear stiffening property. Static mechanical properties including creep and stress relaxation and dynamic rheological properties of MRSPs are tested by rheometer. The experimental results indicate that the external magnetic field exerts significant influence on the creep and relaxation behaviors. Moreover, the storage modulus of MRSPs increases sharply in response to the external stimuli of increasing angular frequency automatically and can be enhanced by external magnetic field. Besides, temperature plays a key role in shear stiffening and magnetorheological effect of MRSPs. Furthermore, considering the obstruction to the particle chains formation induced by Silly Putty matrix, a nonperforative particle aggregated chains model is proposed. The model curve is in consistency with experimental data, which means it can describe magnetoinduced behavior of MRSPs well.

67 citations


Journal ArticleDOI
TL;DR: In this paper, the authors reviewed shrinkage prediction models for cementitious materials and presented analysis of selected published data utilizing the aforementioned models, including capillary pressure theory, Gibbs-Bangham shrinkage, and withdrawal of disjoining pressure in Portland and non-Portland cement.
Abstract: This paper reviews shrinkage prediction models for cementitious materials and presents analysis of selected published data utilizing the aforementioned models. The main objective of this review is to revisit and reexamine the primary shrinkage mechanisms, that is, capillary pressure theory, Gibbs-Bangham shrinkage, and withdrawal of disjoining pressure in Portland and non-Portland cement. In particular, the theoretical basis for current shrinkage models is elaborated on and its soundness and applicability to explain the published experimental data are discussed. Additionally, a specific comparison was made among high water-to-cement (w/c) ratio ordinary Portland cement (OPC), low w/c OPC, and alkaline activated slag.

64 citations


Journal ArticleDOI
TL;DR: In this article, the authors examined the workability, strength, and fracture properties of SCCs containing 0, 25, 50, 75, and 100% coarse RCA and found that at RCA utilisation levels of 25% to 50% little or no negative impact was observed for strength, workability or fracture properties, with the exception of a slight reduction in Young's modulus.
Abstract: The utilisation of recycled concrete aggregate (RCA) in Self-Compacting Concrete (SCC) has the potential to reduce both the environmental impact and financial cost associated with this increasingly popular concrete type. However, to date limited research exists exploring the use of coarse RCA in SCC. The work presented in this paper seeks to build on the existing knowledge in this area by examining the workability, strength, and fracture properties of SCCs containing 0%, 25%, 50%, 75%, and 100% coarse RCA. The experimental programme indicated that at RCA utilisation levels of 25% to 50% little or no negative impact was observed for strength, workability, or fracture properties, with the exception of a slight reduction in Young’s modulus.

Journal ArticleDOI
TL;DR: In this article, a theoretical model based on the same initial assumptions of the analytical models proposed by Hudak and Davidson and Ellyin is proposed to estimate the influence of the crack closure effects.
Abstract: Structural design taking into account fatigue damage requires a thorough knowledge of the behaviour of materials. In addition to the monotonic behaviour of the materials, it is also important to assess their cyclic response and fatigue crack propagation behaviour under constant and variable amplitude loading. Materials whenever subjected to fatigue cracking may exhibit mean stress effects as well as crack closure effects. In this paper, a theoretical model based on the same initial assumptions of the analytical models proposed by Hudak and Davidson and Ellyin is proposed to estimate the influence of the crack closure effects. This proposal based further on Walker’s propagation law was applied to the P355NL1 steel using an inverse analysis (back-extrapolation) of experimental fatigue crack propagation results. Based on this proposed model it is possible to estimate the crack opening stress intensity factor, , the relationship between quantity and the stress intensity factor, the crack length, and the stress ratio. This allows the evaluation of the influence of the crack closure effects for different stress ratio levels, in the fatigue crack propagation rates. Finally, a good agreement is found between the proposed theoretical model and the analytical models presented in the literature.

Journal ArticleDOI
Xinrong Liu, Zijuan Wang, Yan Fu, Wen Yuan, Luli Miao 
TL;DR: In this paper, the degradation of mechanical parameters of rock mass in the hydrofluctuation belt of a reservoir bank slope arising from rainfall and the reservoir level fluctuation is studied.
Abstract: In terms of the degradation of mechanical parameters of rock mass in the hydrofluctuation belt of a reservoir bank slope arising from rainfall and the reservoir level fluctuation, the moderately weathered sandstone in a side slope of the Three Gorges Reservoir Region is selected as a research object to carry out “drying-saturation-drying” tests for disks with two thicknesses ( mm, mm) in different cycles; a spiral CT machine, an ultrasonic velocity meter, and a light Schmidt hammer are utilzed to conduct nondestructive testing on dry-wet cycles; through the Brazilian splitting test, the uniaxial tensile strength of “dry” and “saturated” sandstones under different dry-wet cycles is obtained. The research shows that, with the increase of the dry-wet circles (), the longitudinal wave velocity and the rebound strength of sandstones are linearly decreased with ; the uniaxial tensile strength of sandstones and the mean CT number of cross sections are logarithmically decreased with ; the fitting equation of macro/micromechanical parameters and dry-wet cycles () of sandstones is raised, which is provided as a reference basis for the weathering process of sandstones under dry-wet cycles.

Journal ArticleDOI
TL;DR: In this paper, a novel vision-based cable force measurement method using smartphone camera is proposed, and, then, its feasibility and practicality is initially validated through cable model test.
Abstract: In the recent years, with the development and popularization of smartphone, the utilization of smartphone in the Structural Health Monitoring (SHM) has attracted increasing attention owing to its unique feature. Since bridges are of great importance to society and economy, bridge health monitoring has very practical significance during its service life. Furthermore, rapid damage assessment of bridge after an extreme event such as earthquake is very important in the recovery work. Smartphone-based bridge health monitoring and postevent damage evaluation have advantages over the conventional monitoring techniques, such as low cost, ease of installation, and convenience. Therefore, this study investigates the implementation feasibility of the quick bridge health monitoring technique using smartphone. A novel vision-based cable force measurement method using smartphone camera is proposed, and, then, its feasibility and practicality is initially validated through cable model test. An experiment regarding multiple parameters monitoring of one bridge scale model is carried out. Parameters, such as acceleration, displacement, and angle, are monitored using smartphone. The experiment results show that there is a good agreement between the reference sensor and smartphone measurements in both time and frequency domains.

Journal ArticleDOI
TL;DR: In this paper, various damage mechanisms to porous building materials induced by salt action are analyzed and the importance of pretreatment investigations is discussed as well; in combination with the knowledge of salt and moisture transport mechanisms they can give useful indications regarding treatment options.
Abstract: Salt damage can affect the service life of numerous building structures, both historical and contemporary, in a significant way. In this review, various damage mechanisms to porous building materials induced by salt action are analyzed. The importance of pretreatment investigations is discussed as well; in combination with the knowledge of salt and moisture transport mechanisms they can give useful indications regarding treatment options. The methods of salt damage treatment are assessed then, including both passive techniques based on environmental control, reduction of water transport, or conversion to less soluble salts and active procedures resulting in the removal of salts from deterioration zones. It is concluded that cellulose can still be considered as the favorite material presently used in desalination poultices but hydrophilic mineral wool can serve as its prospective alternative in future applications. Another important cause of building pathologies is the rising damp and, in this phenomenon, it is particularly severe considering the presence of salts in water. The treatment of rising damp in historic building walls is a very complex procedure and at Laboratory of Building Physics (LFC-FEUP) a wall base hygroregulated ventilation system was developed and patented.

Journal ArticleDOI
TL;DR: In this article, the effect of the water-cement ratio on the relative viscosity of the cement paste, as well as pore structure and strength of the hardened foam concrete is discussed.
Abstract: Foam concrete with different dry densities (400, 500, 600, 700, and 800 kg/m3) was prepared from ordinary Portland cement (P.O.42.5R) and vegetable protein foaming agent by adjusting the water-cement ratio through the physical foaming method. The performance of the cement paste adopted, as well as the structure and distribution of air pores, was characterized by a rheometer, scanning electron microscope, vacuum water saturation instrument, and image analysis software. Effects of the water-cement ratio on the relative viscosity of the cement paste, as well as pore structure and strength of the hardened foam concrete, were discussed. Results showed that water-cement ratio can influence the size, distribution, and connectivity of pores in foam concrete. The compressive strength of the foam concrete showed an inverted V-shaped variation law with the increase in water-cement ratio.

Journal ArticleDOI
TL;DR: In this article, the wear rate of Al6061 hybrid metal matrix composite reinforced with the hard ceramic alumina and soft solid lubricant of molybdenum disulphide is investigated.
Abstract: Aluminum Hybrid Reinforcement Technology is a response to the dynamic ever-increasing service requirement of industries such as transportation, aerospace, automobile, and marine, due to its attractive properties like high ductility, highly conductivity, light weight, and high strength to weight ratio. In this evolution, an attempt has been made to investigate the wear rate of Al6061 hybrid metal matrix composite reinforced with the hard ceramic alumina (4, 8, and 12 wt.% of Al2O3) and soft solid lubricant of molybdenum disulphide (2, 4, and 6 wt.% of MoS2) is fabricated by using stir casting method. The unlubricated pins on disc wear tests were conducted to examine the wear behaviour of Al6061/12 wt.% of Al2O3/MoS2 composites. The sliding wear tests were carried out at various loads of 15, 30, and 45 N, sliding velocity (1.25, 2.50, and 3.25 m/sec), and different MoS2 wt.% (2, 4, and 6 wt.%). In addition, the CNC turning experiments were conducted on Al6061/12 wt.% Al2O3/6 wt.% MoS2 using CNMG 120408 uncoated carbide cutting tool under cutting of 100, 150, and 200 m/min, feed of 0.1, 0.2, and 0.3 mm/rev, and depth of cut of 1, 1.5, and 2 mm.

Journal ArticleDOI
TL;DR: In this paper, the axial compression of short concrete columns in steel (Q235) tubes was investigated and it was found that the peak nominal stress decreases with increasing specimen size and that axial bearing capacity is determined by three separate components: the cylinder compressive strength of the concrete, the improvement in strength due to the confining effect of the steel tube, and the longitudinal strength of a steel tube.
Abstract: The bearing capacities of concrete-filled steel tubes are normally derived through experiments with small-scale specimens, but it is uncertain whether such derivations are appropriate for the much larger components used in practical engineering. This study therefore investigates the effect of different diameters (219, 426, 630, and 820 mm) on the axial compression of short concrete columns in steel (Q235) tubes. It is found that the peak nominal stress decreases with increasing specimen size and that the axial bearing capacity is determined by three separate components: the cylinder compressive strength of the concrete, the improvement in strength due to the confining effect of the steel tube, and the longitudinal strength of the steel tube. At peak load, increases in the specimen diameter reduce the hoop stresses in the steel tube, thereby reducing the strengthening effect of confinement. Vertical stress in the steel tube is increased with diameter; therefore, the axial bearing capacity of the steel tube is directly related to the specimen size. Size effect coefficients for these three aspects of bearing capacity are defined and used to develop a size-dependent model for predicting the axial bearing capacity of large, concrete-filled steel tubes. The model is then validated against experimental data.

Journal ArticleDOI
TL;DR: In this paper, the effect of coarse aggregate morphological properties on the high-temperature performance of asphalt mixtures was investigated by applying abrasion cycles of 0, 200, 400, 600, 800, 1000 and 1200 on crushed angular aggregates.
Abstract: The morphological properties of coarse aggregates, such as shape, angularity, and surface texture, have a great influence on the mechanical performance of asphalt mixtures. This study aims to investigate the effect of coarse aggregate morphological properties on the high-temperature performance of asphalt mixtures. A modified Los Angeles (LA) abrasion test was employed to produce aggregates with various morphological properties by applying abrasion cycles of 0, 200, 400, 600, 800, 1000, and 1200 on crushed angular aggregates. Based on a laboratory-developed Morphology Analysis System for Coarse Aggregates (MASCA), the morphological properties of the coarse aggregate particles were quantified using the index of fractal dimension. The high-temperature performances of the dense-graded asphalt mixture (AC-16), gap-graded stone asphalt mixture (SAC-16), and stone mastic asphalt (SMA-16) mixtures containing aggregates with different fractal dimensions were evaluated through the dynamic stability (DS) test and the penetration shear test in laboratory. Good linear correlations between the fractal dimension and high-temperature indexes were obtained for all three types of mixtures. Moreover, the results also indicated that higher coarse aggregate angularity leads to stronger high-temperature shear resistance of asphalt mixtures.

Journal ArticleDOI
TL;DR: In this paper, the authors investigated the solidification/stabilization of fly ash containing heavy metals using the Portland cement as a binder and found that both the cement/fly ash ratio and curing time have significant effects on the mechanical (i.e., compressive strength) and leaching behaviors of the stabilized fly ash mixtures.
Abstract: This study investigated the solidification/stabilization of fly ash containing heavy metals using the Portland cement as a binder. It is found that both the cement/fly ash ratio and curing time have significant effects on the mechanical (i.e., compressive strength) and leaching behaviors of the stabilized fly ash mixtures. When the cement/fly ash ratio increases from 4 : 6 to 8 : 2, the increase of compressive strength ratio raises from 42.24% to 80.36%; meanwhile, the leaching amount of heavy metals decreases by 2.33% to 85.23%. When the curing time increases from 3 days to 56 days, the compressive strength ratio of mixtures raises from 240.00% to 414.29%; meanwhile, the leaching amount of heavy metals decreases by 16.49% to 88.70%. The decrease of compressive strength with the lower cement/fly ash ratios and less curing time can be attributed to the increase of fly ash loading, which hinders the formation of ettringite and destroys the structure of hydration products, thereby resulting in the pozzolanic reaction and fixation of water molecules. Furthermore, the presence of cement causes the decrease of leaching, which results from the formation of ettringite and the restriction of heavy metal ion migration in many forms, such as C-S-H gel and adsorption.

Journal ArticleDOI
TL;DR: In this article, the authors used extended digital image correlation to measure the displacement field near the tip of the crack when the cracks grow in different directions in directional polymethyl methacrylate and tested the critical load for different specimens and analyzed the fracture morphology of the different specimens.
Abstract: The main purpose of this work is to investigate the fracture mechanical properties of aeronautical polymethyl methacrylate, which has been treated with directional tensile technology. Because of the special processing of directional polymethyl methacrylate, the molecular chain structures are different in different directions. The mechanical properties depend on the specific molecular chain structures. We use extended digital image correlation to measure the displacement field near the tip of the crack when the cracks grow in different directions in directional polymethyl methacrylate. We then tested the critical load for different specimens and analyzed the fracture morphology of the different specimens. Thanks to the experimental results, a molecular chain model of directional polymethyl methacrylate could be established. The analysis results using the molecular chain model are consistent with the experiments, which confirms the reliability of the molecular chain model.

Journal ArticleDOI
TL;DR: In this article, the conductivity and dielectric constant were measured in the normal frequency range and the behaviors of measured EM property were investigated with carbonation velocity and strength, which shows an attempt of application to durability evaluation through EM measurement.
Abstract: Dielectric constant and conductivity, the so-called EM properties (electromagnetic), are widely adopted for NDT (Nondestructive Technique) in order to detect damage or evaluate performance of concrete without damage to existing RC (reinforced concrete). Among deteriorating agents, chloride ion is considered as one of the most critical threats due to rapid penetration and direct effect on steel corrosion. In the work, cement mortar samples with 3 w/c (water-to-cement) ratios and 4 levels of chloride addition are considered. Conductivity and dielectric constant are measured in the normal frequency range. They increase with strength of mortar and more chloride ions due to denser pore formation. Furthermore, the behaviors of measured EM property are investigated with carbonation velocity and strength, which shows an attempt of application to durability evaluation through EM measurement.

Journal ArticleDOI
TL;DR: In this article, the authors investigated the possibility of utilizing iron ore tailings (IOT) to replace clay as alumina-silicate raw material for the production of Portland cement clinker.
Abstract: The cement industry has for some time been seeking alternative raw material for the Portland cement clinker production. The aim of this research was to investigate the possibility of utilizing iron ore tailings (IOT) to replace clay as alumina-silicate raw material for the production of Portland cement clinker. For this purpose, two kinds of clinkers were prepared: one was prepared by IOT; the other was prepared by clay as a reference. The reactivity and burnability of raw meal, mineralogical composition and physical properties of clinker, and hydration characteristic of cement were studied by burnability analysis, differential thermal analysis, X-ray diffraction, and hydration analysis. The results showed that the raw meal containing IOT had higher reactivity and burnability than the raw meal containing clay, and the use of IOT did not affect the formation of characteristic mineralogical phases of Portland cement clinker. Furthermore, the physical and mechanical performance of two cement clinkers were similar. In addition, the use of IOT was found to improve the grindability of clinker and lower the hydration heat of Portland cement. These findings suggest that IOT can replace the clay as alumina-silicate raw material for the preparation of Portland cement clinker.

Journal ArticleDOI
TL;DR: In this paper, the improved reactivity of a geopolymer based on a combination of fly ash and blast furnace slag (BFS) by the addition of silica fume was investigated.
Abstract: This study investigates the improved reactivity of a geopolymer based on a combination of fly ash and blast furnace slag (BFS) by the addition of silica fume. The geopolymer was synthesized by activating a mixture of fly ash, BFS, and three different types of silica fume with alkali activator. X-ray diffraction (XRD) and inductively coupled plasma-optical emission spectroscopy (ICP-OES) were utilized to characterize the reaction. The silicate structure was also analyzed by nuclear magnetic resonance (NMR) spectroscopy. From these results, it was found that the replacement of fly ash with the silica fume led to a significant decrease in the (1Al) and an increase in the (2Al), (3Al), and (4Al). The Si/Al ratio of the aluminosilicate gel was relatively constant, ranging from 2.0 to 2.6, while the Si/Al ratio of the C-S-H gel increased with the addition of silica fume. Therefore, some of the Al dissolved from the slag contributed to the formation of aluminosilicate gel, and the remnant slag particles mostly participated in the formation of the C-(A)-S-H gel with a decrease in the (1Al). The increase in the reactivity of slag caused by the addition of silica fume was attributed to the reaction of the Al in the slag with the silica fume.

Journal ArticleDOI
TL;DR: Based on the actual data, the authors constructs an international supply chain model using system dynamics method and simulates the reconstruction trend of the supply chain after 3D printing application, and concludes that the universal application of 3D printers will lead to the worldwide transport volume shrinking dramatically.
Abstract: In recent years 3D printing technology is developing rapidly. In the foreseeable future, when 3D printing is widely used, the world’s industrial structure will be greatly changed. Based on the actual data, this paper constructs an international supply chain model using system dynamics method. And it simulates the reconstruction trend of the supply chain after 3D printing application. The conclusion shows that the universal application of 3D printing will lead to the worldwide transport volume shrinking dramatically. The manufacturing activities will gradually outflow to the countries which are closer to the final customers. The relevant countries should carry out feasible measures to face this opportunity and challenge. The measures include the reform of logistics facilities, the logistics cooperation with the origin of 3D printing materials, and the matched transportation of 3D printing materials and traditional processing ones.

Journal ArticleDOI
TL;DR: In this article, several recent developments in material science and deposition methods for flexible organic light-emitting devices (OLEDs) are surveyed and compared, according to their mechanical, optical, thermal, and chemical properties.
Abstract: Several recent developments in material science and deposition methods for flexible organic light-emitting devices (OLEDs) are surveyed. The commonly used plastic substrates are compared, according to their mechanical, optical, thermal, and chemical properties. Multilayer electrode structures, used as transparent electrodes, replacing conventional indium tin oxide (ITO) are presented and data about their conductivity, transparency, and bending ability are provided. Attention is paid to some of the most popular industrial processes for flexible OLEDs manufacturing, such as roll-to-roll printing, inkjet printing, and screen printing. Main specifics and challenges, related to the foils reliability, mechanical stability of the transparent electrodes, and deposition and patterning of organic emissive films, are discussed.

Journal ArticleDOI
TL;DR: In this paper, the role of microstructure on mechanical and fatigue properties of thin-section Ti6Al4V sheets was investigated with the aim of reviewing the effects of microstructures on fatigue properties where suboptimal microstures might result following heat treatment of assemblies that may not be suited to further annealing, for example, following laser welding.
Abstract: The microstructures of Ti6Al4V are complex and strongly affect its mechanical properties and fatigue behavior. This paper investigates the role of microstructure on mechanical and fatigue properties of thin-section Ti6Al4V sheets, with the aim of reviewing the effects of microstructure on fatigue properties where suboptimal microstructures might result following heat treatment of assemblies that may not be suited to further annealing, for example, following laser welding. Samples of Ti6Al4V sheet were subjected to a range of heat treatments, including annealing and water quenching from temperatures ranging from 650°C to 1050°C. Micrographs of these samples were inspected for microstructure, and hardness, 0.2% proof stress, elongation, and fracture strength were measured and attributed back to microstructure. Fractography was used to support the findings from microstructure and mechanical analyses. The strength ranking from high to low for the microstructures of thin Ti6Al4V sheets observed in this study is as follows: acicular martensite, Widmanstatten, bimodal, and equiaxed microstructure. The fatigue strength ranking from high to low is as follows: equiaxed, bimodal, Widmanstatten, and acicular martensite microstructure.

Journal ArticleDOI
TL;DR: In this paper, the authors put forward the idea of taking the silane silica (nanosilica modified with silane coupling agent) as filler to develop one kind of modified asphalt concrete which has excellent comprehensive performance based on the idea to enhance the whole performance of asphalt concrete and interface consolidation strength between aggregate and asphalt at the same time.
Abstract: At present there are many kinds of fillers and modifier used for modified asphalt, but the effect of modifier differs in thousands of ways; most of them can increase the high temperature performance of asphalt, but the modified effect of low-temperature crack resistance, water stability, and antifatigue performance is different. Aiming at the subsistent problems, this paper innovatively puts forward the idea of taking the silane silica (nanosilica modified with silane coupling agent) as filler to develop one kind of modified asphalt concrete which has excellent comprehensive performance based on the idea of enhance the whole performance of asphalt concrete and interface consolidation strength between aggregate and asphalt at the same time. The best mixing amount of silane silica and the production process of modified asphalt were conducted by contrasting the test date as penetration, viscosity, and softening point; the aging of asphalt and modified asphalt was analyzed by TG test, the superiority of silane silica modified asphalt is more clearly understandable by chemical analysis results. Meanwhile it is proved that silane silica has positive effect to improve the mixture of high and low temperature performance, water stability, and aging resistance through a series of road performance tests.

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TL;DR: In this article, the setting time and compressive and bond strengths of MPC mortar were measured to assess the applicability, and hydration product was detected by the X-ray diffraction.
Abstract: Fundamental properties of magnesium phosphate cement (MPC) were investigated in this paper. The setting time and compressive and bond (i.e., flexural and tensile bond) strengths were measured to assess the applicability, and hydration product was detected by the X-ray diffraction. The specimens were manufactured with magnesia and potassium dihydrogen phosphate (K2HPO4) was added to activate hydration process. The Borax (Na2B4O7·10H2O) was used as a retarder to mitigate overwhelming rapid hardening. Mercury intrusion porosimetry was used to examine the pore structure of MPC mortar, and simultaneously rapid chloride penetration test was performed. As a result, the compressive strength of MPC mortar was mostly achieved within 12 hours; in particular, the MPC mortar at 4.0 of M/P ranked the highest value accounting for 30.0 MPa. When it comes to tensile and flexural bond to old substrate in mortar patching, the MPS had the higher tensile and flexural strengths, accounting for 1.9 and 1.7 MPa, respectively, compared to OPC mortar patching. Unlike Portland cement mortar, the MPC mortar contained mainly air void rather than capillary pores in the pore distribution. Presumably due to reduced capillary pore in the MPC, the MPC indicated lower penetrability in the chloride penetration test.

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TL;DR: In this paper, the authors used Remote Sensing (RS) and Geographic Information Systems (GIS) techniques for the assessment of the data, applying the Revised Universal Soil Loss Equation (RUSLE) for the calculation of the risk of erosion.
Abstract: Soil erosion is one of the major environmental problems in terms of soil degradation in Saudi Arabia. Soil erosion leads to significant on- and off-site impacts such as significant decrease in the productive capacity of the land and sedimentation. The key aspects influencing the quantity of soil erosion mainly rely on the vegetation cover, topography, soil type, and climate. This research studies the quantification of soil erosion under different levels of data availability in Wadi Yalamlam. Remote Sensing (RS) and Geographic Information Systems (GIS) techniques have been implemented for the assessment of the data, applying the Revised Universal Soil Loss Equation (RUSLE) for the calculation of the risk of erosion. Thirty-four soil samples were randomly selected for the calculation of the erodibility factor, based on calculating the -factor values derived from soil property surfaces after interpolating soil sampling points. Soil erosion risk map was reclassified into five erosion risk classes and 19.3% of the Wadi Yalamlam is under very severe risk (37,740 ha). GIS and RS proved to be powerful instruments for mapping soil erosion risk, providing sufficient tools for the analytical part of this research. The mapping results certified the role of RUSLE as a decision support tool.