Journal ArticleDOI
1D, 2D and 3D luminescent zinc(II) coordination polymers assembled from varying flexible thioether ligands.
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TLDR
Using a series flexible thioether ligands, a 1D infinite chain, a 2D interpenetrating sheet, and a chiral 3D framework were obtained and Luminescent properties of these compounds were studied.Abstract:
Using a series flexible thioether ligands, 4-(2-pyridylmethylthio)benzoic acid (HL1), 4-(4-pyridylmethylthio)benzoic acid (HL2) and 4-(3-pyridylmethylthio)benzoic acid (HL3), a 1D infinite chain [Zn3(L1)6]n (1), a 2D interpenetrating sheet [Zn(L2)2]n (2), and a chiral 3D framework [Zn(L3)2H2O]n (3) were obtained Luminescent properties of these compounds were also studiedread more
Citations
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Engineering Metal Organic Frameworks for Heterogeneous Catalysis
TL;DR: In conclusion, MOFs as Host Matrices or Nanometric Reaction Cavities should not be considered as a source of concern in the determination of MOFs’ properties in relation to other materials.
Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
TL;DR: In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.
Journal ArticleDOI
Lanthanide metal-organic frameworks for luminescent sensing and light-emitting applications
TL;DR: In this paper, the authors summarize the research progress on the design and construction of luminescent lanthanide MOFs, as well as their potential functions and applications on luminecent sensing and light-emitting.
Journal ArticleDOI
Recent advances in crystal engineering
TL;DR: The 10th edition of CrystEngComm as mentioned in this paper highlighted the state-of-the-art of crystal engineering and new trends and developing areas in crystal engineering, such as intermolecular interactions, metal-organic frameworks or coordination polymers; polymorphism and solvates.
Journal ArticleDOI
Syntheses, Structures, and Photoluminescence of Five New Metal−Organic Frameworks Based on Flexible Tetrapyridines and Aromatic Polycarboxylate Acids
Jin-Song Hu,Yongjia Shang,Xiao-Qiang Yao,Ling Qin,Yi-Zhi Li,Zijian Guo,He-Gen Zheng,He-Gen Zheng,Zi-Ling Xue +8 more
TL;DR: In this article, tetrakis(4-pyridyloxymethylene)methane (TPOM) with deprotonated 1,4-benzenedicarboxylate (H2BDc) or 5-hydroxyisophthalic acid (5-OH-H2bdc) were characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction.
References
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Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.
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Hydrogen Storage in Microporous Metal-Organic Frameworks
Nathaniel L. Rosi,Juergen Eckert,Mohamed Eddaoudi,David T. Vodak,Jaheon Kim,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Inelastic neutron scattering spectroscopy of the rotational transitions of the adsorbed hydrogen molecules indicates the presence of two well-defined binding sites (termed I and II), which are associated with hydrogen binding to zinc and the BDC linker, respectively.
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A homochiral metal-organic porous material for enantioselective separation and catalysis
TL;DR: The synthesis of a homochiral metal–organic porous material that allows the enantioselective inclusion of metal complexes in its pores and catalyses a transesterification reaction in an enantiOSElective manner is reported.
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CH/π hydrogen bonds in crystals
TL;DR: The CH/π interaction is a kind of hydrogen bond operating between a soft acid CH and a soft base π-system (double and triple bonds, C6 and C5 aromatic rings, heteroaromatics, convex surfaces of fullerenes and nanotubes) as discussed by the authors.