A New Method of Analyzing Thermogravimetric Data
TLDR
In this paper, a new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed, which is simple and applicable to reactions which can not be analyzed by other methods.Abstract:
A new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed. The method is simple and applicable to reactions which can not be analyzed by other methods. The effect of the heating rate on thermogravimetric curves has been elucidated, and the master curve of the experimental curves at different heating rates has been derived. The applications of the method to the pyrolyses of calcium oxalate and nylon 6 have been shown ; the results are in good agreement with the reported values. The applicability of the method to other types of thermal analyses has been discussed, and the method of the conversion of the data to other conditions of temperature change has been suggested. From these discussions, the definition of the thermal stability of materials has been criticized.read more
Citations
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Cure behaviors and mechanical properties of carbon fiber-reinforced nylon6/epoxy blended matrix composites
Kwan-Woo Kim,Dong-Kyu Kim,Byoung-Suhk Kim,Kay-Hyeok An,Soo-Jin Park,Kyong Yop Rhee,Byung Joo Kim +6 more
TL;DR: In this paper, the composition effects of a nylon6 and epoxy blend system on the cure behaviors and mechanical properties of carbon fiber-reinforced nylon6/epoxy composites were investigated.
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Kinetics of thermal degradation and thermal oxidative degradation of poly(p-dioxanone)
TL;DR: In this article, the kinetics of the thermal degradation and thermal oxidative degradation of poly(p-dioxanone) (PPDO) were investigated by thermogravimetric analysis Kissinger method, Friedman method, Flynn-Wall-Ozawa method and Coats-Redfern method.
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Study of the thermooxidative degradation kinetics of poly(tetrafluoroethene) using iso-conversional calculation procedure
TL;DR: In this article, the authors compared six calculation procedures based on single TG curves and iso-conversional method, as well as 27 mechanism functions for the PTFE degradation process.
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Improved thermo-mechanical properties by the addition of natural fibres in starch-based sustainable biocomposites
TL;DR: In this article, sustainable biocomposites based on thermoplastic starch copolymers (Mater-Bi KE03B1) and biofibres (cotton, hemp and kenaf) were prepared and characterised in terms of their thermo-mechanical and morphological properties.
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Fuel production from waste polystyrene via pyrolysis: Kinetics and products distribution.
Jan Nisar,Ghulam Ali,Afzal Shah,Munawar Iqbal,Rafaqat Ali Khan,Sirajuddin,Farooq Anwar,Raqeeb Ullah,Mohammad Salim Akhter +8 more
TL;DR: Temperature of 410 °C and exposure time of 70 min are the best conditions for maximum fuel oil production and a comparison of the composition of pyrolysis oil with standard parameters of diesel, gasoline and kerosene oil suggested that pyrofullysis oil from polystyrene waste holds great promise for replacing fuel oil.
References
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Journal ArticleDOI
Kinetic Parameters from Thermogravimetric Data
A. W. Coats,J. P. Redfern +1 more
TL;DR: In this article, a thermocouple is used to measure the sample temperature in a Stanton HT-D thermobalance, the bead of which is positioned in or near the sample, depending on crucible design.
Journal ArticleDOI
A New Analysis of Thermogravimetric Traces.
H. H. Horowitz,Gershon. Metzger +1 more
Journal ArticleDOI
The Application of Thermoanalytical Techniques to Reaction Kinetics: The Thermogravimetric Evaluation of the Kinetics of the Decomposition of Calcium Oxalate Monohydrate
Eli S. Freeman,Benjamin Carroll +1 more
Journal ArticleDOI
Kinetic analysis of thermogravimetric data
TL;DR: The kinetic analysis of the thermogram, by use of either its exact equation or a more convenient approximation formula, is straightforward in cases of volatilization via simple kinetics as mentioned in this paper.
Journal ArticleDOI
Estimating isothermal life from thermogravimetric data
TL;DR: In this paper, the authors presented a method for estimating equivalent isothermal life from thermogravimetric data and for estimating the apparent activation energy for volatilization even though the nature of the kinetic process is unknown.
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