A New Method of Analyzing Thermogravimetric Data
TLDR
In this paper, a new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed, which is simple and applicable to reactions which can not be analyzed by other methods.Abstract:
A new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed. The method is simple and applicable to reactions which can not be analyzed by other methods. The effect of the heating rate on thermogravimetric curves has been elucidated, and the master curve of the experimental curves at different heating rates has been derived. The applications of the method to the pyrolyses of calcium oxalate and nylon 6 have been shown ; the results are in good agreement with the reported values. The applicability of the method to other types of thermal analyses has been discussed, and the method of the conversion of the data to other conditions of temperature change has been suggested. From these discussions, the definition of the thermal stability of materials has been criticized.read more
Citations
More filters
Journal ArticleDOI
Chemical kinetics on thermal decompositions of di-tert-butyl peroxide studied by calorimetry
TL;DR: In this article, an overview of chemical kinetics on the thermal decomposition of di-tert-butyl peroxide (DTBP) has been performed in this study.
Journal ArticleDOI
Pyrolysis of ficus nitida wood: Determination of kinetic and thermodynamic parameters
TL;DR: In this paper, the kinetic and thermodynamic analysis of ficus wood was carried out using the thermogravimetric analysis (TGA) and integral master-plots method to estimate the kinetic triplets.
Journal ArticleDOI
Kinetic thermal behaviour and evaluation of physical structure of sugar cane bagasse char during non-isothermal steam gasification
Elbager M.A. Edreis,Hong Yao +1 more
TL;DR: In this paper, the physical structures of sugar cane bagasse (SCB) chars as a function of pyrolysis temperature have been studied by using Brunauer-Emmett-Teller (BET) surface area technique.
Journal ArticleDOI
Impact of atmospheric water vapor on the thermal decomposition of calcium hydroxide: a universal kinetic approach to a physico-geometrical consecutive reaction in solid-gas systems under different partial pressures of product gas.
TL;DR: The challenge in this study was to universally describe the kinetics of thermal decomposition under various p(H2O) conditions by introducing an accommodation function in the fundamental kinetic equation.
Journal ArticleDOI
Quantitative evaluation of softened regions in weld heat-affected zones of 6061-T6 aluminum alloy : Characterizing of the laser beam welding process
TL;DR: In this article, a kinetic equation describing the dissolution of age precipitates has been established and has been applied to 6061-T6 aluminum weldments and the hardness profiles and the width of softened zones have been successfully predicted in both welding processes.
References
More filters
Journal ArticleDOI
Kinetic Parameters from Thermogravimetric Data
A. W. Coats,J. P. Redfern +1 more
TL;DR: In this article, a thermocouple is used to measure the sample temperature in a Stanton HT-D thermobalance, the bead of which is positioned in or near the sample, depending on crucible design.
Journal ArticleDOI
A New Analysis of Thermogravimetric Traces.
H. H. Horowitz,Gershon. Metzger +1 more
Journal ArticleDOI
The Application of Thermoanalytical Techniques to Reaction Kinetics: The Thermogravimetric Evaluation of the Kinetics of the Decomposition of Calcium Oxalate Monohydrate
Eli S. Freeman,Benjamin Carroll +1 more
Journal ArticleDOI
Kinetic analysis of thermogravimetric data
TL;DR: The kinetic analysis of the thermogram, by use of either its exact equation or a more convenient approximation formula, is straightforward in cases of volatilization via simple kinetics as mentioned in this paper.
Journal ArticleDOI
Estimating isothermal life from thermogravimetric data
TL;DR: In this paper, the authors presented a method for estimating equivalent isothermal life from thermogravimetric data and for estimating the apparent activation energy for volatilization even though the nature of the kinetic process is unknown.
Related Papers (5)
A quick, direct method for the determination of activation energy from thermogravimetric data
Joseph H. Flynn,Leo A. Wall +1 more